Citation: Kexin Yin, Jingren Yang, Yanwei Li, Qian Li, Xing Xu. Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation[J]. Chinese Chemical Letters, ;2024, 35(12): 109847. doi: 10.1016/j.cclet.2024.109847 shu

Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation

Kexin Yin ^a ,
Jingren Yang ^{c, *,} ,
Yanwei Li ^b ,
Qian Li ^a ,
Xing Xu ^{a, *,}

a.
Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Qingdao 266237, China
b.
Environment Research Institute, Shandong University, Qingdao 266237, China
c.
State Environmental Protection Key Laboratory of Environmental Health Impact Assessment of Emerging Contaminants, Shanghai Academy of Environmental Sciences, Shanghai 200233, China

yangjr@saes.sh.cn

xuxing@sdu.edu.cn

Received Date: 13 December 2023
Revised Date: 12 March 2024
Accepted Date: 1 April 2024
Available Online: 3 April 2024

Figures(7)

Herein, a diatomite biomorphic Si-O doped carbon-based catalyst (DB-SiOC) was prepared using natural mineral diatomite as the silicon source and porous template. The results showed that the metal-free DB-SiOC catalyst exhibited ultrafast oxidation towards chlorophenol (CP) via peroxymonosulfate (PMS) activation, which was almost one order of magnitudes than most of carbon-based catalysts. The DB-SiOC/PMS system also showed the high ability to resist the interference of environmental matrix. The radicals (^•OH and SO₄^•‒) exhibited a very small contribution to the CP oxidation while the electron transfer processes (ETP) played the major role in the DB-SiOC/PMS system. The electron shuttles from the electron-donating CP molecules to the adjacent DB-SiOC/PMS* could be efficiently triggered via Si-O bonds as bridges, making it possible for ultrafast oxidation of CP. In addition, the hollow-disc shaped DB-SiOC provided the biomorphic DE structures with abundant pores for enriching the PMS and pollutants, thus further accelerating the oxidation reaction. This work provided a new routine for the fabrication of Si-O doped carbon-based catalysts with excellent Fenton-like catalytic activity, which would greatly promote their application prospects in Fenton-like systems.
- Peroxymonosulfate,
- Diatomite,
- Si-O doping,
- Fenton-like reaction,
- Electron transfer process (ETP)
1. [1]
  J. Lee, U. von Gunten, J.H. Kim, Environ. Sci. Technol. 54 (2020) 3064–3081. doi: 10.1021/acs.est.9b07082
2. [2]
  X. Wu, J.H. Kim, ACS ES&T Eng. 2 (2022) 1776–1796.
3. [3]
  Y. Jiang, D. Baimanov, S. Jin, et al., Proc. Natl. Acad. Sci. U. S. A. 120 (2023) e2210211120. doi: 10.1073/pnas.2210211120
4. [4]
  J. Zhang, B. Jing, Z. Tang, et al., Appl. Catal. B: Environ. 289 (2021) 120023. doi: 10.1016/j.apcatb.2021.120023
5. [5]
  Y. Su, M. Lu, R. Su, et al., Chin. Chem. Lett. 33 (2022) 2573–2578. doi: 10.1016/j.cclet.2021.08.078
6. [6]
  Q. Zhao, C.C. Wang, P. Wang, Chin. Chem. Lett. 33 (2022) 4828–4833. doi: 10.1016/j.cclet.2022.01.033
7. [7]
  J. Chen, C. Fang, W. Xia, et al., Environ. Sci. Technol. 52 (2018) 1461–1470. doi: 10.1021/acs.est.7b05543
8. [8]
  L. Peng, X. Duan, Y. Shang, et al., Appl. Catal. B: Environ. 287 (2021) 119963. doi: 10.1016/j.apcatb.2021.119963
9. [9]
  Y.N. Shang, X. Xu, B.Y. Gao, et al., Chem. Soc. Rev. 50 (2021) 5281–5322. doi: 10.1039/D0CS01032D
10. [10]
  P.J. Duan, X. Xu, K.Y. Guo, et al., Appl. Catal. B: Environ. 316 (2022) 121695. doi: 10.1016/j.apcatb.2022.121695
11. [11]
  Z.Y. Guo, R. Sun, Z. Huang, et al., Proc. Natl. Acad. Sci. U. S. A. 120 (2023) e2220608120. doi: 10.1073/pnas.2220608120
12. [12]
  X. Wang, J. Jing, M. Zhou, R. Dewil, Chin. Chem. Lett. 34 (2023) 107621. doi: 10.1016/j.cclet.2022.06.044
13. [13]
  L. Chen, C. He, R. Wang, et al., Chin. Chem. Lett. 32 (2021) 53–56. doi: 10.1016/j.cclet.2020.11.013
14. [14]
  Y. Peng, G. Xie, P. Shao, et al., Appl. Catal. B: Environ. 310 (2022) 121345. doi: 10.1016/j.apcatb.2022.121345
15. [15]
  W. Ren, L. Xiong, G. Nie, et al., Environ. Sci. Technol. 54 (2020) 1267–1275. doi: 10.1021/acs.est.9b06208
16. [16]
  X. Duan, H. Sun, Y. Wang, et al., ACS Catal. 5 (2014) 553–559.
17. [17]
  Y. Wang, Z. Zhang, Z. Yin, et al., Appl. Catal. B: Environ. 319 (2022) 121891. doi: 10.1016/j.apcatb.2022.121891
18. [18]
  X. Duan, K. O'Donnell, H. Sun, et al., Small 11 (2015) 3036–3044. doi: 10.1002/smll.201403715
19. [19]
  W. Ren, P. Zhou, G. Nie, et al., Water Res. 186 (2020) 116361. doi: 10.1016/j.watres.2020.116361
20. [20]
  X. Dong, Z. Chen, A. Tang, et al., Adv. Funct. Mater. 32 (2022) 2111565. doi: 10.1002/adfm.202111565
21. [21]
  K. Li, X. Liu, T. Zheng, et al., Chem. Eng. J. 370 (2019) 136–147. doi: 10.1016/j.cej.2019.03.190
22. [22]
  K. Chen, C. Li, L. Shi, et al., Nat. Commun. 7 (2016) 13440. doi: 10.1038/ncomms13440
23. [23]
  X. Dong, B. Ren, X. Zhang, et al., Appl. Catal. B: Environ. 272 (2020) 118971. doi: 10.1016/j.apcatb.2020.118971
24. [24]
  J. Li, J. Xu, Z. Xie, et al., Adv. Mater. 30 (2018) e1800548. doi: 10.1002/adma.201800548
25. [25]
  P. Xu, R. Wei, P. Wang, Water Res. 235 (2023) 119843. doi: 10.1016/j.watres.2023.119843
26. [26]
  Y. Ding, Q. Cheng, J. Wu, et al., Adv. Mater. 34 (2022) e2202256. doi: 10.1002/adma.202202256
27. [27]
  X. Wen, W. Feng, X. Li, et al., Adv. Mater. 35 (2023) e2211690. doi: 10.1002/adma.202211690
28. [28]
  Z. Jia, T. Li, Z. Zheng, et al., Chem. Eng. J. 380 (2020) 122422. doi: 10.1016/j.cej.2019.122422
29. [29]
  M. Zhang, H. Li, J. Chen, et al., Small 18 (2022) e2202476. doi: 10.1002/smll.202202476
30. [30]
  X. Guo, Q. Zhang, H. He, et al., Appl. Catal. B: Environ. 335 (2023) 122886. doi: 10.1016/j.apcatb.2023.122886
31. [31]
  J. Murata, K. Hayama, M. Takizawa, Appl. Surf. Sci. 625 (2023) 157190. doi: 10.1016/j.apsusc.2023.157190
32. [32]
  Y. Chen, Z. Li, Y. Zhu, et al., Adv. Mater. 31 (2019) e1806312. doi: 10.1002/adma.201806312
33. [33]
  G. Chen, P. Liu, Z. Liao, et al., Adv. Mater. 32 (2020) e1907399. doi: 10.1002/adma.201907399
34. [34]
  A. Wang, J. Ni, W. Wang, et al., Appl. Catal. B: Environ. 319 (2022) 121926. doi: 10.1016/j.apcatb.2022.121926
35. [35]
  X. Duan, H. Sun, Z. Shao, et al., Appl. Catal. B: Environ. 224 (2018) 973–982. doi: 10.1016/j.apcatb.2017.11.051
36. [36]
  T. Liu, S. Xiao, N. Li, et al., Nat. Commun. 14 (2023) 2881. doi: 10.1038/s41467-023-38677-1
37. [37]
  Y. Yang, G. Banerjee, G.W. Brudvig, et al., Environ. Sci. Technol. 52 (2018) 5911–5919. doi: 10.1021/acs.est.8b00735
38. [38]
  B. Liu, W. Guo, W. Jia, et al., Water Res. 201 (2021) 117313. doi: 10.1016/j.watres.2021.117313
39. [39]
  A. Wang, B.Z. Zhu, C.H. Huang, et al., Water Res. 235 (2023) 119904. doi: 10.1016/j.watres.2023.119904
40. [40]
  J. Peng, P. Zhou, H. Zhou, et al., Environ. Sci. Technol. 55 (2021) 9189–9198. doi: 10.1021/acs.est.1c00020
41. [41]
  X. Zhou, M.K. Ke, G.X. Huang, et al., Proc. Natl. Acad. Sci. U. S. A. 119 (2022) e2119492119. doi: 10.1073/pnas.2119492119
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沈阳化工大学材料科学与工程学院沈阳 110142