Citation: Yan-Kai Zhang, Yong-Zheng Zhang, Chun-Xiao Jia, Fang Wang, Xiuling Zhang, Yuhang Wu, Zhongmin Liu, Hui Hu, Da-Shuai Zhang, Longlong Geng, Jing Xu, Hongliang Huang. A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation[J]. Chinese Chemical Letters, ;2024, 35(12): 109756. doi: 10.1016/j.cclet.2024.109756 shu

A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation

Yan-Kai Zhang ^{a, b, 1} ,
Yong-Zheng Zhang ^{a, b, 1} ,
Chun-Xiao Jia ^a ,
Fang Wang ^a ,
Xiuling Zhang ^{a, b, *,} ,
Yuhang Wu ^a ,
Zhongmin Liu ^a ,
Hui Hu ^a ,
Da-Shuai Zhang ^{a, b} ,
Longlong Geng ^{a, b} ,
Jing Xu ^{a, *,} ,
Hongliang Huang ^{c, *,}

a.
Shandong Provincial Key Laboratory of Monocrystalline Silicon Semiconductor Materials and Technology, College of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, China
b.
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, China
c.
State Key Laboratory of Separation Membranes and Membrane Processes, School of Chemical Engineering and Technology, Tiangong University, Tianjin 300387, China

xlzhang99@126.com

xujing2306@163.com

huanghongliang@tiangong.edu.cn

Received Date: 16 November 2023
Revised Date: 16 February 2024
Accepted Date: 5 March 2024
Available Online: 8 March 2024

Figures(6)

The highly desired goal is to employ visible light for the photocatalytic reduction of toxic Cr(VI) to environmentally friendly Cr(III). Metal-organic frameworks (MOFs) are considered one of the most promising materials for the photoreduction of Cr(VI). Nevertheless, developing MOFs with high stability and activity is still challenging. Herein, we report a stable Zn-based MOF (named DZU-64) with an anthracene functionalized ligand, and its reduction of Cr(VI) under sunlight irradiation was investigated. DZU-64 exhibits excellent chemical stability in pH range of 2−14 aqueous solution, and remarkable thermal stability to 570 ℃. For the photoreduction of Cr(VI) under visible light irradiation, DZU-64 gives a record rate constant of 0.467 min⁻¹ and a high Cr(VI) reduction rate of 6.68 mg Cr_(VI) g_cata⁻¹ min⁻¹ at pH 2. Moreover, under real solar light, DZU-64 can also efficiently reduce Cr(VI) to Cr(III) while retaining its catalytic activity throughout 5 cycles without any notable decline, further demonstrating its great application prospect. By combining the photovoltaic performance tests and electron spin resonance test, the possible photoreduction of Cr(VI) mechanism in DZU-64 was analyzed.
- Metal-organic frameworks,
- Anthracene-based ligand,
- Cr(VI) reduction,
- Photocatalysis,
- Stability
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