Citation: Hui Li, Yanxing Qi, Jia Chen, Juanjuan Wang, Min Yang, Hongdeng Qiu. Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄[J]. Chinese Chemical Letters, ;2024, 35(11): 109659. doi: 10.1016/j.cclet.2024.109659 shu

Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄

Hui Li ^{a, b, c} ,
Yanxing Qi ^{b, c, *,} ,
Jia Chen ^a ,
Juanjuan Wang ^a ,
Min Yang ^b ,
Hongdeng Qiu ^{a, c, *,}

a.
CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

qiyx@licp.cas.cn

hdqiu@licp.cas.cn

Received Date: 16 October 2023
Revised Date: 23 January 2024
Accepted Date: 13 February 2024
Available Online: 18 February 2024

Figures(5)

A novel amine-modified pillar[5]arene bonded porous silica adsorbent (DETA-P5S) was designed to be applied to dynamic CO₂ adsorption and selective separation of CO₂ over N₂ and CH₄ gases mixture. The results demonstrated that reasonable introduction of DETA into the BE-P5 bonded silica support has significantly increased the adsorption capacity of CO₂. The DETA-P5S has the optimal adsorption capacity of 9.1 mmol/g with 5 vol% CO₂ at 40 ℃. The main reason of this increased capacity could be attributed to the enhanced CO₂ diffusion into porous adsorbent for its better dispersion in the pores of amine-pillar[5]arene cavity and active site of DETA. Furthermore, the dynamic saturation adsorption capacities of DETA-P5S were 7.11 (0.37) and 6.18 (0.44) mmol/g for CO₂/N₂ and CO₂/CH₄, respectively, both the gas mixtures showed high separation selectivity. Simultaneously, the DETA-P5S can maintain outstanding CO₂ adsorption capacity after fifteen regeneration cycles. Consequently, the designed DETA-P5S could serve as a promising adsorbent for CO₂ capture and storage.
- CO₂ adsorption,
- Selective separation,
- Porous silica,
- Solid amine adsorbents,
- Amine-pillar[5]arene
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO2 and selectivity over N2 and CH4

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通讯作者: 陈斌, bchen63@163.com

Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄