Citation: Ruonan Yang, Jiajia Li, Dongmei Zhang, Xiuqi Zhang, Xia Li, Han Yu, Zhanhu Guo, Chuanxin Hou, Gang Lian, Feng Dang. Grain-refining Co_0.85Se@CNT cathode catalyst with promoted Li₂O₂ growth kinetics for lithium-oxygen batteries[J]. Chinese Chemical Letters, ;2024, 35(12): 109595. doi: 10.1016/j.cclet.2024.109595 shu

Grain-refining Co_0.85Se@CNT cathode catalyst with promoted Li₂O₂ growth kinetics for lithium-oxygen batteries

Ruonan Yang ^a ,
Jiajia Li ^a ,
Dongmei Zhang ^a ,
Xiuqi Zhang ^a ,
Xia Li ^a ,
Han Yu ^a ,
Zhanhu Guo ^b ,
Chuanxin Hou ^{c, *,} ,
Gang Lian ^{a, *,} ,
Feng Dang ^{a, *,}

a.
School of Materials Science & Engineering, State Key Laboratory of Crystal Materials, Shandong University, Ji’nan 250061, China
b.
Integrated Composites Lab, Department of Mechanical and Construction Engineering, Northumbria University, Newcastle Upon Tyne, NE1 8ST, United Kingdom
c.
School of Environmental and Material Engineering, Yantai University, Yantai 264005, China

chuanxin210@ytu.edu.cn

liangang@sdu.edu.cn

dangfeng@sdu.edu.cn

Received Date: 7 December 2023
Revised Date: 2 January 2024
Accepted Date: 29 January 2024
Available Online: 6 February 2024

Figures(5)

Highly active cathode catalysts for efficient formation/decomposition of Li₂O₂ are essential for the performance improvement of lithium-oxygen batteries (LOBs). In this study, a grain-refining Co_0.85Se catalyst with a lattice spacing of 2.69 Å of (101) plane closely matching with the (100) plane (2.72 Å) of Li₂O₂ was applied for high-performance LOBs. Highly (101) plane exposed Co_0.85Se@CNT was synthesized by a simple one-pot hydrothermal method. The Co_0.85Se with the lattice matching effect not only led to the efficient conversion and polarized growth of Li₂O₂, but also prevented the formation of byproducts. Density functional theory (DFT) calculations reveal that Co_0.85Se (101) plane has the intrinsic catalytic ability to generate/decompose Li₂O₂ during ORR/OER process, due to its homogeneous electron distribution, suitable adsorption energy, and promoted Li₂O₂ growth kinetics. As a consequence, the (101) plane highly exposed Co_0.85Se@CNT-80 electrode exhibited remarkable cycle stability over 2400 h at 100 mA/g and 290 cycles at 500 mA/g, which is about 2 times longer than other electrodes.
- Lithium-oxygen batteries,
- Co_0.85Se@CNT,
- Cathode catalysts,
- Grain-refiner,
- DFT calculation
1. [1]
  M. Armand, J.M. Tarascon, Nature 451 (2008) 652–657. doi: 10.1038/451652a
2. [2]
  D. Aurbach, B.D. McCloskey, L.F. Nazar, P.G. Bruce, Nat. Energy 1 (2016) 16128. doi: 10.1038/nenergy.2016.128
3. [3]
  P.G. Bruce, S.A. Freunberger, L.J. Hardwick, J.M. Tarascon, Nat. Mater. 11 (2012) 19–29. doi: 10.1038/nmat3191
4. [4]
  Q. Xiong, G. Huang, X.B. Zhang, Angew. Chem. Int. Ed. 59 (2020) 19311–19319. doi: 10.1002/anie.202009064
5. [5]
  T. Ogasawara, A. Débart, M. Holzapfel, P. Novak, P.G. Bruce, J. Am. Chem. Soc. 128 (2006) 1390–1393. doi: 10.1021/ja056811q
6. [6]
  L. Grande, E. Paillard, J. Hassoun, et al., Adv. Mater. 27 (2015) 784–800. doi: 10.1002/adma.201403064
7. [7]
  W.J. Kwak, D. Sharon Rosy, et al., Chem. Rev. 120 (2020) 6626–6683. doi: 10.1021/acs.chemrev.9b00609
8. [8]
  F.J. Li, J. Chen, Adv. Energy Mater. 7 (2017) 1602934. doi: 10.1002/aenm.201602934
9. [9]
  C.Z. Shu, J.Z. Wang, J.P. Long, H.K. Liu, S.X. Dou, Adv. Mater. 31 (2019) 1804587. doi: 10.1002/adma.201804587
10. [10]
  J.M. Tarascon, M. Armand, Nature 414 (2001) 359–367. doi: 10.1038/35104644
11. [11]
  C. Xia, C.Y. Kwok, L.F. Nazar, Science 361 (2018) 777–781. doi: 10.1126/science.aas9343
12. [12]
  G.L. Zhang, C.Y. Liu, L. Guo, et al., Adv. Energy Mater. 12 (2022) 2200791. doi: 10.1002/aenm.202200791
13. [13]
  J. Xie, X.H. Yao, Q.M. Cheng, et al., Angew. Chem. Int. Ed. 54 (2015) 4299–4303. doi: 10.1002/anie.201410786
14. [14]
  F.J. Li, T. Zhang, H.S. Zhou, Energy Environ. Sci. 6 (2013) 1125–1141. doi: 10.1039/c3ee00053b
15. [15]
  M.D. Bhatt, H. Geaney, M. Nolan, C. O’Dwyer, Phys. Chem. Chem. Phys. 16 (2014) 12093–12130. doi: 10.1039/c4cp01309c
16. [16]
  Y. Dou, Z. Xie, Y. Wei, Z. Peng, Z. Zhou, Natl. Sci. Rev. 9 (2022) nwac040. doi: 10.1093/nsr/nwac040
17. [17]
  S.M. Zhang, M.H. Chen, X. Zhao, et al., Electrochem. Energy Rev. 4 (2021) 336–381. doi: 10.1007/s41918-020-00085-0
18. [18]
  F.Y. Cheng, J. Chen, Chem. Soc. Rev. 41 (2012) 2172–2192. doi: 10.1039/c1cs15228a
19. [19]
  Y.Y. Shao, F. Ding, J. Xiao, et al., Adv. Funct. Mater. 23 (2013) 987–1004. doi: 10.1002/adfm.201200688
20. [20]
  B. He, G. Li, J. Li, et al., Adv. Energy Mater. (2021) 2003263.
21. [21]
  L. Johnson, C.M. Li, Z. Liu, et al., Nat. Chem. 6 (2014) 1091–1099. doi: 10.1038/nchem.2101
22. [22]
  X. Liu, X. Song, Q. Zhang, et al., J. Energy Chem. 69 (2022) 516–523. doi: 10.1016/j.jechem.2022.01.007
23. [23]
  B.M. Gallant, R.R. Mitchell, D.G. Kwabi, et al., J. Phys. Chem. C 116 (2012) 20800–20805. doi: 10.1021/jp308093b
24. [24]
  M.M.O. Thotiyl, S.A. Freunberger, Z.Q. Peng, P.G. Bruce, J. Am. Chem. Soc. 135 (2013) 494–500. doi: 10.1021/ja310258x
25. [25]
  M. Balaish, A. Kraytsberg, Y. Ein-Eli, Phys. Chem. Chem. Phys. 16 (2014) 2801–2822. doi: 10.1039/c3cp54165g
26. [26]
  H.G. Jung, J. Hassoun, J.B. Park, Y.K. Sun, B. Scrosati, Nat. Chem. 4 (2012) 579–585. doi: 10.1038/nchem.1376
27. [27]
  Y. Wang, J. Wang, Z. Mohamed, et al., Appl. Mater. Today 19 (2020) 100603. doi: 10.1016/j.apmt.2020.100603
28. [28]
  Z.L. Li, S. Ganapathy, Y.L. Xu, et al., Adv. Energy Mater. 8 (2018) 1703513. doi: 10.1002/aenm.201703513
29. [29]
  J. Lu, L. Cheng, K.C. Lau, et al., Nat. Commun. 5 (2014) 4895. doi: 10.1038/ncomms5895
30. [30]
  S.T. Plunkett, A. Kondori, D.Y. Chung, et al., ACS Energy Lett. 7 (2022) 2619–2626. doi: 10.1021/acsenergylett.2c01191
31. [31]
  Z.C. Wu, J.J. Li, Z.X. Zou, X. Wang, J. Solid State Electrochem. 22 (2018) 1785–1794. doi: 10.1007/s10008-018-3885-3
32. [32]
  Y.X. Huang, Z.H. Wang, Y. Jiang, et al., Nano Energy 53 (2018) 524–535. doi: 10.1016/j.nanoen.2018.09.010
33. [33]
  S.J. Shen, Z.P. Lin, K. Song, et al., Angew. Chem. Int. Ed. 60 (2021) 12360–12365. doi: 10.1002/anie.202102961
34. [34]
  Y. Han, X. Chen, C. Qian, et al., Chem. Eng. J. 420 (2021) 130461. doi: 10.1016/j.cej.2021.130461
35. [35]
  H. Zhou, L. Guo, R. Zhang, et al., Adv. Funct. Mater. (2023) 2304154.
36. [36]
  R. Liu, Y. Fu, G. Zhang, et al., J. Mater. Chem. A 10 (2022) 18078–18086. doi: 10.1039/D2TA05411F
37. [37]
  D. Li, L. Zhao, Q. Xia, et al., Adv. Funct. Mater. 32 (2022) 2108153. doi: 10.1002/adfm.202108153
38. [38]
  G. Li, N. Li, S. Peng, et al., Adv. Energy Mater. 11 (2021) 2002721. doi: 10.1002/aenm.202002721
39. [39]
  L. Guo, L. Tan, A. Xu, et al., Energy Storage Mater. 50 (2022) 96–104. doi: 10.1016/j.ensm.2022.05.014
40. [40]
  H. Huang, C. Cheng, G. Zhang, et al., Adv. Funct. Mater. 32 (2022) 2111546. doi: 10.1002/adfm.202111546
41. [41]
  G. Zhang, G. Li, J. Wang, et al., Adv. Energy Mater. 12 (2022) 2103910. doi: 10.1002/aenm.202103910
42. [42]
  A.D. Becke, K.E. Edgecombe, J. Chem. Phys. 92 (1990) 5397–5403. doi: 10.1063/1.458517
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Grain-refining Co0.85Se@CNT cathode catalyst with promoted Li2O2 growth kinetics for lithium-oxygen batteries

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通讯作者: 陈斌, bchen63@163.com

Grain-refining Co_0.85Se@CNT cathode catalyst with promoted Li₂O₂ growth kinetics for lithium-oxygen batteries