Citation: Mao-Fan Li, Ming‐Yu Guo, De-Xuan Liu, Xiao-Xian Chen, Wei-Jian Xu, Wei-Xiong Zhang. Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)][J]. Chinese Chemical Letters, ;2024, 35(12): 109507. doi: 10.1016/j.cclet.2024.109507 shu

Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]

Mao-Fan Li ^a ,
Ming‐Yu Guo ^a ,
De-Xuan Liu ^a ,
Xiao-Xian Chen ^a ,
Wei-Jian Xu ^{b, *,} ,
Wei-Xiong Zhang ^{a, *,}

a.
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou 510275, China
b.
Department of Chemistry & CICECO-Aveiro Institute of Materials, University of Aveiro, Aveiro 3810-193, Portugal

weijxu@ua.pt

zhangwx6@mail.sysu.edu.cn

Received Date: 30 November 2023
Revised Date: 24 December 2023
Accepted Date: 11 January 2024
Available Online: 14 January 2024

Figures(4)

Multi-stimuli responsive materials controlled and coupled by two or more channels have a broad range of applications in the field of switches, memories, and molecular machines. The exploration of the material is currently focused on the pure organic system, which limits the development of such materials greatly. In this work, we present a new chiral organic-inorganic hybrid salt, (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)] (1), which exhibits rare multi-stimuli responsive behaviors in thermal, mechanical and optical channels. In detail, 1 undergoes a C2-P2₁22₁ phase transition deriving from the thermal motion of organic cations with the increase of temperature, but the reverse transition can only be induced by mechanical pressure. Moreover, polycrystalline hybrid salt showed photo-responsive performance, i.e., the ground-state N-bound nitrosyl ligand adopts two configurations in excited states caused by light in 532 nm irradiation, accompanying with a photo-induced structural transformation of the anionic framework. Namely, the thermal motion characteristics of organic cations, the photoresponse characteristics of anionic inorganic skeleton and the pressure characteristics from hydrogen bonds are simultaneously integrated in 1. This unprecedented coupling mechanism of multi-stimuli responses makes 1 a potential candidate for future multichannel data storage applications.
- Phase transition,
- Organic and inorganic hybrids,
- Multi-stimuli responsive materials,
- Nitroprusside,
- Photoisomerization
1. [1]
  Y. Dong, J. Wang, X. Guo, et al., Nat. Commun. 10 (2019) 4087–4096. doi: 10.1038/s41467-019-12044-5
2. [2]
  B. Ma, Y. Zhang, J. Li, et al., Chem. Eng. J. 466 (2023) 143420–143427. doi: 10.1016/j.cej.2023.143420
3. [3]
  D.X. Liu, Z.H. Yu, X.X. Chen, W.X. Zhang, X.M. Chen, Chin. Chem. Lett. 34 (2023) 107310. doi: 10.1016/j.cclet.2022.03.033
4. [4]
  M. Mączka, S. Sobczak, P. Ratajczyk, et al., Chem. Mater. 34 (2022) 7867–7877. doi: 10.1021/acs.chemmater.2c01533
5. [5]
  D.X. Liu, X.X. Chen, Z.M. Ye, W.X. Zhang, X.M. Chen, Sci. China Mater. 65 (2022) 263–267. doi: 10.1007/s40843-021-1794-1
6. [6]
  Y.P. Gong, X.X. Chen, B.Q. Zhao, et al., Chin. Chem. Lett. 34 (2023) 108282. doi: 10.1016/j.cclet.2023.108282
7. [7]
  A. Meeks, M.M. Lerch, T.B.H. Schroeder, A. Shastri, J. Aizenberg, J. Am. Chem. Soc. 144 (2021) 219–227.
8. [8]
  H. Huang, C. Xu, K. Lin, et al., Chin. Chem. Lett. 34 (2023) 107850. doi: 10.1016/j.cclet.2022.107850
9. [9]
  R. Toyoda, N.V. Hoang, K.G. Moghaddam, et al., Nat. Commun. 13 (2022) 5765–5770. doi: 10.1038/s41467-022-33177-0
10. [10]
  Z. Jiang, H. Zhao, W. Wu, et al., J. Mate. Chem. C 11 (2023) 4375–4383. doi: 10.1039/d3tc00271c
11. [11]
  M. Gao, J. Li, N. Peng, et al., J. Mol. Liq. 368 (2022) 120681–120691. doi: 10.1016/j.molliq.2022.120681
12. [12]
  F. Joy, K.P. Chaithra, A. Nizam, et al., Chem. Eng. J. 453 (2023) 139798–139812. doi: 10.1016/j.cej.2022.139798
13. [13]
  A.A. Beharry, G.A. Woolley, Chem. Soc. Rev. 40 (2011) 4422–4437. doi: 10.1039/c1cs15023e
14. [14]
  S. Kumar, J.T. Herpt, R.Y.N. Gengler, et al., J. Am. Chem. Soc. 138 (2016) 12519–12526. doi: 10.1021/jacs.6b06806
15. [15]
  P. Tavadze, G. Avendaño Franco, P. Ren, et al., J. Am. Chem. Soc. 140 (2017) 285–290.
16. [16]
  M.A. Kochman, T. Gryber, B. Durbeej, A. Kubas, Phys. Chem. Chem. Phys. 24 (2022) 18103–18118. doi: 10.1039/d2cp02143a
17. [17]
  S. Hasebe, Y. Hagiwara, K. Takechi, et al., Chem. Mater. 34 (2022) 1315–1324. doi: 10.1021/acs.chemmater.1c04007
18. [18]
  W.Q. Liao, Y.L. Zeng, Y.Y. Tang, et al., J. Am. Chem. Soc. 143 (2021) 21685–21693. doi: 10.1021/jacs.1c11000
19. [19]
  S. Ohkoshi, K. Nakagawa, K. Imoto, et al., Nat. Chem. 12 (2020) 338–344. doi: 10.1038/s41557-020-0427-2
20. [20]
  M. Komine, K. Imoto, A. Namai, M. Yoshikiyo, S. Ohkoshi, Inorg. Chem. 60 (2021) 2097–2104. doi: 10.1021/acs.inorgchem.0c03493
21. [21]
  W.J. Xu, K. Romanyuk, J.M.G. Martinho, et al., J. Am. Chem. Soc. 142 (2020) 16990–16998. doi: 10.1021/jacs.0c06048
22. [22]
  R.G. Qiu, X.X. Chen, R.K. Huang, et al., Chem. Commun. 56 (2020) 5488–5491. doi: 10.1039/d0cc01877e
23. [23]
  W.H. Hu, W.J. Xu, Q.R. Meng, et al., Chem. Commun. 55 (2019) 11555–11558. doi: 10.1039/c9cc05967a
24. [24]
  H. Ye, W.H. Hu, X.X. Chen, et al., Chem. Asian J. 18 (2023) e202300608. doi: 10.1002/asia.202300608
25. [25]
  A.W. Crawford, R.H. Groeneman, D.K. Unruh, K.M. Hutchins, Chem. Commun. 55 (2019) 3258–3261. doi: 10.1039/c9cc00836e
26. [26]
  T. Yang, Y. Liu, L. Hua, et al., Chin. Chem. Lett. 35 (2024) 108707. doi: 10.1016/j.cclet.2023.108707
27. [27]
  R. Shang, S. Chen, B.W. Wang, Z.M. Wang, S. Gao, Angew. Chem. Int. Ed. 55 (2016) 2097–2100. doi: 10.1002/anie.201510024
28. [28]
  D. Schaniel, B. Cormary, I. Malfant, et al., Phys. Chem. Chem. Phys. 9 (2007) 3717–3724. doi: 10.1039/B704778A
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2. [2]
  Kai Ye , Zhicheng Ye , Chuantao Wang , Zhilai Luo , Cheng Lian , Chunyan Bao . Artificial signal transduction triggered by molecular photoisomerization in lipid membranes. Chinese Chemical Letters, 2025, 36(4): 110033-. doi: 10.1016/j.cclet.2024.110033
3. [3]
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4. [4]
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5. [5]
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7. [7]
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8. [8]
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9. [9]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
10. [10]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
11. [11]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
12. [12]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
13. [13]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
14. [14]
  Mengjia Luo , Yi Qiu , Zhengyang Zhou . Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4. Chinese Journal of Structural Chemistry, 2025, 44(1): 100446-100446. doi: 10.1016/j.cjsc.2024.100446
15. [15]
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16. [16]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
17. [17]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
18. [18]
  Yan Cheng , Hai-Quan Yao , Ya-Di Zhang , Chao Shi , Heng-Yun Ye , Na Wang . Nitrate-bridged hybrid organic-inorganic perovskites. Chinese Journal of Structural Chemistry, 2024, 43(9): 100358-100358. doi: 10.1016/j.cjsc.2024.100358
19. [19]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
20. [20]
  Ning Zhang , Mengjie Qin , Jiawen Zhu , Xuejing Lou , Xiao Tian , Wende Ma , Youmei Wang , Minghua Lu , Zongwei Cai . Thickness-controllable synthesis of metal-organic framework based hollow nanoflowers with magnetic core via liquid phase epitaxy for phosphopeptides enrichment. Chinese Chemical Letters, 2025, 36(4): 110177-. doi: 10.1016/j.cclet.2024.110177

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Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)2[Fe(CN)5(NO)]

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通讯作者: 陈斌, bchen63@163.com

Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]