Citation: Yan Wang, Si-Meng Zhai, Peng Luo, Xi-Yan Dong, Jia-Yin Wang, Zhen Han, Shuang-Quan Zang. Vapor- and temperature-triggered reversible optical switching for multi-response Cu₈ cluster supercrystals[J]. Chinese Chemical Letters, ;2024, 35(11): 109493. doi: 10.1016/j.cclet.2024.109493 shu

Vapor- and temperature-triggered reversible optical switching for multi-response Cu₈ cluster supercrystals

Yan Wang ^a ,
Si-Meng Zhai ^a ,
Peng Luo ^{b, c} ,
Xi-Yan Dong ^{a, b, c} ,
Jia-Yin Wang ^{b, *,} ,
Zhen Han ^{a, *,} ,
Shuang-Quan Zang ^{a, *,}

a.
Henan Key Laboratory of Crystalline Molecular Functional Materials, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
b.
Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, China
c.
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China

wangjiayin@henu.edu.cn

hanzhen77@zzu.edu.cn

zangsqzg@zzu.edu.cn

Received Date: 27 November 2023
Revised Date: 19 December 2023
Accepted Date: 4 January 2024
Available Online: 15 January 2024

Figures(5)

Multi-response metal cluster supercrystal materials, which can simultaneously display various such as color, photoluminescence, changes by bearing only one stimulus, have huge potential as stimuli-responsive intelligent material, but are rarely reported. Here, we report three Cu₈ cluster supercrystals, Cu₈-1, Cu₈-2, and Cu₈-3, with homologous cluster molecule units [Cu₈(PNP)₃(EPPTA)₆](PF₆)₂ but distinct packing. These supercrystals display bright µs-long photoluminescence with a high quantum yield of up to 26.6% in solid-state at room temperature and aggregation-induced emission (AIE) characteristic. Superior thermal stability and blue-excitable bright yellow emission make Cu8-3 serve as a yellow phosphor for white light-emitting diode. Furthermore, upon being stimulated by solvent vapor and temperature, reversible supercrystal-to-supercrystal transformations can be witnessed accompanied by remarkable color and luminescence switching. This work not only provides a kind of Cu cluster supercrystal model but also motivates the further development of metal clusters in multi-response materials.
- Copper cluster,
- Supercrystal,
- Photoluminescence,
- Stimuli-response,
- Reversible switching
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Vapor- and temperature-triggered reversible optical switching for multi-response Cu8 cluster supercrystals

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通讯作者: 陈斌, bchen63@163.com

Vapor- and temperature-triggered reversible optical switching for multi-response Cu₈ cluster supercrystals