Citation: Xueyang Zhao, Bangwei Deng, Hongtao Xie, Yizhao Li, Qingqing Ye, Fan Dong. Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction[J]. Chinese Chemical Letters, ;2024, 35(7): 109139. doi: 10.1016/j.cclet.2023.109139 shu

Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction

Xueyang Zhao ^{a, b} ,
Bangwei Deng ^a ,
Hongtao Xie ^a ,
Yizhao Li ^a ,
Qingqing Ye ^c ,
Fan Dong ^{a, b, *,}

a.
Yangtze Delta Region Institute (Huzhou), University of Electronic Science and Technology of China, Huzhou 313001, China
b.
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 611731, China
c.
Suzhou Industrial Technology Research Institute of Zhejiang University, Zhejiang University, Suzhou 215159, China

dongfan@uestc.edu.cn

Received Date: 31 May 2023
Revised Date: 4 September 2023
Accepted Date: 21 September 2023
Available Online: 23 September 2023

Figures(5)

Diatomic-site catalysts (DASCs) have emerged as a kind of promising heterogeneous candidate catalysts for electrochemical CO₂ reduction (ECR), which is considered to retain the advantage of single-atom catalysts (SACs) but also introduce opportunities to exceed the limit of single-atom catalysts. In the past few years, tremendous progress has been achieved in this field. Herein, the recent progress in ECR on DASCs has been summarized. It will start with the classification of DASCs. Then the challenges in the precise fabrication and characterization of DASCs have been emphasized. By introducing the advanced ECR performance on DASCs, superior to that on SACs, the synergistic effects of the dual metal atoms are highlighted, as this origin of the advanced ECR performance on DASCs is comprehensively summarized. Finally, the major challenges and perspectives of DASCs have been proposed to shed light on the development of DASCs for ECR application.
- Diatomic-site metal catalyst,
- Electrochemical CO₂ reduction,
- Classification,
- CO₂ activation,
- Synergistic effects
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO2 reduction

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通讯作者: 陈斌, bchen63@163.com

Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction