Citation: Guorong Li, Yijing Wu, Chao Zhong, Yixin Yang, Zian Lin. Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ)[J]. Chinese Chemical Letters, ;2024, 35(5): 108904. doi: 10.1016/j.cclet.2023.108904 shu

Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ)

Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou 350108, China

zianlin@fzu.edu.cn

Received Date: 21 December 2022
Revised Date: 31 July 2023
Accepted Date: 6 August 2023
Available Online: 8 August 2023

Figures(5)

Targeted construction of new covalent organic frameworks (COFs) with specific purposes and rationalities to build colorimetric assay platform for environmental pollutant monitoring have attracted increasing interest. However, it is still challenging due to lack of available coordination sites inside COFs pores and only a slight bonding ability for anchoring metal. In this work, a two-dimensional (2D) COFs (termed as Tz-COF) with high crystallinity, excellent chemical stability, and abundant sulfur coordination in its skeletons was synthesized and used for the confined growth of Au NPs. It was found that the Au NPs showed significant dispersibility for the support of Tz-COF. The proposed Tz-COF@Au NPs possessed outstanding Hg²⁺-activated peroxidase-like activity benefited from physicochemical properties of gold amalgam and synergistic effect between COFs and Au NPs to oxidize chromogenic substrate. Based on highly efficient activity and distinctive color evolution, the strategy for detecting Hg²⁺ was developed and successfully applied to determine the content of Hg²⁺ in real environmental samples. This work manifests that a potential strategy to establish a colorimetric assay platform for environmental pollutant monitoring based on the targeted manufacturing of novel COFs with specific functions.
- Covalent organic frameworks,
- Thiazole,
- Sulfur coordination,
- Au nanoparticles,
- Hg²⁺-activated peroxidase-like activity
1. [1]
  C. Chen, D. Zhao, Y. Jiang, et al., Anal. Chem. 91 (2019) 15017–15024. doi: 10.1021/acs.analchem.9b03629
2. [2]
  Y. Huang, M. Zhao, S. Han, et al., Adv. Mater. 29 (2017) 1700102. doi: 10.1002/adma.201700102
3. [3]
  R. Xu, Z. Wang, S. Liu, H. Li, Chin. Chem. Lett. 33 (2022) 4683–4686. doi: 10.1016/j.cclet.2021.12.062
4. [4]
  X.K. Wan, H.B. Wu, B.Y. Guan, D. Luan, X.W.D. Lou, Adv. Mater. 32 (2020) 1901349. doi: 10.1002/adma.201901349
5. [5]
  L. Shang, T. Bian, B. Zhang, et al., Angew. Chem. Int. Ed. 53 (2014) 250–254. doi: 10.1002/anie.201306863
6. [6]
  W. Yuan, B. Zhu, K. Fang, et al., Science 371 (2021) 517–521. doi: 10.1126/science.abe3558
7. [7]
  L. Duan, C.T. Hung, J. Wang, et al., Angew. Chem. Int. Ed. 61 (2022) e202211307. doi: 10.1002/anie.202211307
8. [8]
  F. Jin, E. Lin, T. Wang, et al., Chemistry 8 (2022) 3064–3080. doi: 10.1016/j.chempr.2022.07.016
9. [9]
  Z. Li, Z. Zhang, R. Nie, et al., Adv. Funct. Mater. 32 (2022) 2112553. doi: 10.1002/adfm.202112553
10. [10]
  L. Chen, M. Huang, B. Chen, et al., Chin. Chem. Lett. 33 (2022) 2867–2882. doi: 10.1016/j.cclet.2021.10.060
11. [11]
  Q. Guan, L.L. Zhou, Y.B. Dong, Chem. Soc. Rev. 51 (2022) 6307–6416. doi: 10.1039/D1CS00983D
12. [12]
  Y. Zhang, G. Li, Y. Hu, Chin. Chem. Lett. 32 (2021) 2529–2533. doi: 10.1016/j.cclet.2021.01.031
13. [13]
  H.C. Ma, J.L. Kan, G.J. Chen, C.X. Chen, Y.B. Dong, Chem. Mater. 29 (2017) 6518–6524. doi: 10.1021/acs.chemmater.7b02131
14. [14]
  Y. Deng, Z. Zhang, P. Du, et al., Angew. Chem. Int. Ed. 59 (2020) 6082–6089. doi: 10.1002/anie.201916154
15. [15]
  M. Yu, Y. Chen, M. Gao, et al., Small 19 (2022) 2206407.
16. [16]
  Y. Tian, Q. Lu, X. Guo, et al., Nanoscale 12 (2020) 7776–7781. doi: 10.1039/C9NR08220D
17. [17]
  R. Tao, X. Shen, Y. Hu, et al., Small 16 (2020) 1906005. doi: 10.1002/smll.201906005
18. [18]
  L. Niu, X. Zhao, Z. Tang, et al., Sci. Total Environ. 835 (2022) 155423. doi: 10.1016/j.scitotenv.2022.155423
19. [19]
  X. Shi, Y. Yao, Y. Xu, et al., ACS Appl. Mater. Interfaces 9 (2017) 7481–7488. doi: 10.1021/acsami.6b16267
20. [20]
  W. Ma, G. Li, C. Zhong, et al., Chem. Commun. 57 (2021) 7362–7365. doi: 10.1039/D1CC02646A
21. [21]
  K. Wang, Z. Jia, Y. Bai, et al., J. Am. Chem. Soc. 142 (2020) 11131–11138. doi: 10.1021/jacs.0c03418
22. [22]
  A.C. Jakowetz, T.F. Hinrichsen, L. Ascherl, et al., J. Am. Chem. Soc. 141 (2019) 11565–11571. doi: 10.1021/jacs.9b03956
23. [23]
  Y. Xie, Y. Chen, X. Sun, Y. Wang, Y. Wang, Chin. Chem. Lett. 32 (2021) 2061–2065. doi: 10.1016/j.cclet.2020.10.001
24. [24]
  S.B. Ren, X.L. Chen, P.X. Li, et al., J. Power Sources 461 (2020) 228145. doi: 10.1016/j.jpowsour.2020.228145
25. [25]
  J. Dong, X. Li, S.B. Peh, et al., Chem. Mater. 31 (2018) 146–160.
26. [26]
  N. Liu, L. Shi, X. Han, et al., Chin. Chem. Lett. 31 (2020) 386–390. doi: 10.1016/j.cclet.2019.06.050
27. [27]
  Z. Zhang, C. Kang, S.B. Peh, et al., J. Am. Chem. Soc. 144 (2022) 14992–14996. doi: 10.1021/jacs.2c05309
28. [28]
  F. Haase, E. Troschke, G. Savasci, et al., Nat. Commun. 9 (2018) 2600. doi: 10.1038/s41467-018-04979-y
29. [29]
  Q. Peng, Z.Y. Wang, B.S. Sa, B. Wu, Z.M. Sun, ACS Appl. Mater. Interfaces 8 (2016) 13449–13457. doi: 10.1021/acsami.6b03368
30. [30]
  W.R. Cui, C.R. Zhang, W. Jiang, et al., ACS Sustain. Chem. Eng. 7 (2019) 9408–9415. doi: 10.1021/acssuschemeng.9b00613
31. [31]
  L. Tan, Y. Zhang, H. Qiang, et al., Sens. Actuat. B: Chem. 229 (2016) 686–691. doi: 10.1016/j.snb.2016.02.037
32. [32]
  L. Chen, J. Li, L. Chen, ACS Appl. Mater. Interfaces 6 (2014) 15897–15904. doi: 10.1021/am503531c
33. [33]
  J. Xu, F. Sun, Q. Li, et al., Small 18 (2022) 2200525. doi: 10.1002/smll.202200525
34. [34]
  L. Wang, F. Gao, A. Wang, et al., Adv. Mater. 32 (2020) 2005423. doi: 10.1002/adma.202005423
35. [35]
  Y. Guo, Y. Tao, X. Ma, et al., Chem. Eng. J. 350 (2018) 120–130. doi: 10.1016/j.cej.2018.05.135
36. [36]
  S. Zhang, D. Zhang, X. Zhang, et al., Anal. Chem. 89 (2017) 3538–3544. doi: 10.1021/acs.analchem.6b04805
1. [1]
  Jiaqi Ma , Lan Li , Yiming Zhang , Jinjie Qian , Xusheng Wang . Covalent organic frameworks: Synthesis, structures, characterizations and progress of photocatalytic reduction of CO2. Chinese Journal of Structural Chemistry, 2024, 43(12): 100466-100466. doi: 10.1016/j.cjsc.2024.100466
2. [2]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
3. [3]
  Yuting Wu , Haifeng Lv , Xiaojun Wu . Design of two-dimensional porous covalent organic framework semiconductors for visible-light-driven overall water splitting: A theoretical perspective. Chinese Journal of Structural Chemistry, 2024, 43(11): 100375-100375. doi: 10.1016/j.cjsc.2024.100375
4. [4]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
5. [5]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
6. [6]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
7. [7]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
8. [8]
  Chang LIU , Chao ZHANG , Tongbu LU . Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N₂ electroreduction. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305
9. [9]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
10. [10]
  Shaobin He , Xiaoyun Guo , Qionghua Zheng , Huanran Shen , Yuan Xu , Fenglin Lin , Jincheng Chen , Haohua Deng , Yiming Zeng , Wei Chen . Engineering nickel-supported osmium bimetallic nanozymes with specifically improved peroxidase-like activity for immunoassay. Chinese Chemical Letters, 2025, 36(4): 110096-. doi: 10.1016/j.cclet.2024.110096
11. [11]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174
12. [12]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
13. [13]
  Shuang Liang , Jianjun Yao , Dan Liu , Mengli Zhou , Yong Cui , Zhaohui Wang . Tumor-responsive covalent organic polymeric nanoparticles enhancing STING activation for cancer immunotherapy. Chinese Chemical Letters, 2025, 36(3): 109856-. doi: 10.1016/j.cclet.2024.109856
14. [14]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
15. [15]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
16. [16]
  Xinyi Cao , Yucheng Jin , Hailong Wang , Xu Ding , Xiaolin Liu , Baoqiu Yu , Xiaoning Zhan , Jianzhuang Jiang . A tetraaldehyde-derived porous organic cage and covalent organic frameworks: Syntheses, structures, and iodine vapor capture. Chinese Chemical Letters, 2024, 35(9): 109201-. doi: 10.1016/j.cclet.2023.109201
17. [17]
  Junhua Wang , Xin Lian , Xichuan Cao , Qiao Zhao , Baiyan Li , Xian-He Bu . Dual polarization strategy to enhance CH₄ uptake in covalent organic frameworks for coal-bed methane purification. Chinese Chemical Letters, 2024, 35(8): 109180-. doi: 10.1016/j.cclet.2023.109180
18. [18]
  Jiahao Li , Guinan Chen , Chunhong Chen , Yuanyuan Lou , Zhihao Xing , Tao Zhang , Chengtao Gong , Yongwu Peng . Modulated synthesis of stoichiometric and sub-stoichiometric two-dimensional covalent organic frameworks for enhanced ethylene purification. Chinese Chemical Letters, 2025, 36(1): 109760-. doi: 10.1016/j.cclet.2024.109760
19. [19]
  Xi Zhou , Shengyao Wang . Dynamic two-dimensional covalent organic frameworks via ‘wine rack' design. Chinese Journal of Structural Chemistry, 2025, 44(4): 100464-100464. doi: 10.1016/j.cjsc.2024.100464
20. [20]
  Xue Xin , Qiming Qu , Islam E. Khalil , Yuting Huang , Mo Wei , Jie Chen , Weina Zhang , Fengwei Huo , Wenjing Liu . Hetero-phase zirconia encapsulated with Au nanoparticles for boosting electrocatalytic nitrogen reduction. Chinese Chemical Letters, 2024, 35(5): 108654-. doi: 10.1016/j.cclet.2023.108654

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(299)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142