Citation: Yujing Li, Xiaojun Zhang, Zicheng Wang, Lina Zhao, Yuxin Li. Highly sensitive Fe³⁺ luminescence detection via single-ion adsorption[J]. Chinese Chemical Letters, ;2024, 35(1): 108532. doi: 10.1016/j.cclet.2023.108532 shu

Highly sensitive Fe³⁺ luminescence detection via single-ion adsorption

Yujing Li ^a ,
Xiaojun Zhang ^a ,
Zicheng Wang ^a ,
Lina Zhao ^{a, b} ,
Yuxin Li ^{a, *,}

a.
Key Laboratory of Function Inorganic Material Chemistry (MOE), School of Chemistry and Material Science, and School of Civil Engineering, Heilongjiang University, Harbin 150080, China
b.
Department of Food & Environmental Engineering, East University of Heilongjiang, Harbin 150066, China

liyuxin@hlju.edu.cn

Received Date: 27 March 2023
Revised Date: 13 April 2023
Accepted Date: 29 April 2023
Available Online: 2 May 2023

Figures(3)

To achieve a lower detection limit has always been a goal of analytical chemists. Herein, we demonstrate the first picomolar level detection capability for Fe³⁺ ion via luminescence detection technology. The results of structural analysis and theoretical calculation show that Fe³⁺ ions are adsorbed on the central node of Eu-DBM (DBM = dibenzoylmethane) sensor in the form of single ion at ultralow concentration. Subsequently, the pathways of photo-induced charge and energy transfer of the obtained Eu-DBM@Fe³⁺ material have been changed, from the initial DBM-to-Eu³⁺ before Fe³⁺ adsorption to the ultimate DBM-to-Fe³⁺ after adsorption process, which quenches the luminescence of Eu³⁺ ion. This work not only obtains the highly sensitive luminescence detection ability, but also innovatively proposes the single-ion adsorption mechanism, both of which have important scientific and application values for the development of more efficient detection agents in the future.
- Luminescence detection,
- Lanthanide complex,
- High sensitivity,
- Fe³⁺ ion,
- Single-ion adsorption
1. [1]
  S. Bolisetty, M. Peydayesh, R. Mezzenga, Chem. Soc. Rev. 48 (2019) 463–487. doi: 10.1039/c8cs00493e
2. [2]
  Z. Bai, X. Ren, Z. Gong, et al., Chin. Chem. Lett. 28 (2017) 1901–1904. doi: 10.1016/j.cclet.2017.05.005
3. [3]
  J.J. Pang, R.H. Du, X. Lian, et al., Chin. Chem. Lett. 32 (2021) 2443–2447. doi: 10.1016/j.cclet.2021.01.040
4. [4]
  H. Wang, X. Wang, R.M. Kong, L. Xia, F. Qu, Chin. Chem. Lett. 32 (2021) 198–202. doi: 10.1016/j.cclet.2020.10.017
5. [5]
  C. Fan, X. Huang, L. Han, et al., Sens. Actuators B: Chem. 224 (2016) 592–599. doi: 10.1016/j.snb.2015.10.104
6. [6]
  J. Qian, N. Cao, J. Zhang, et al., Chin. Chem. Lett. 31 (2020) 2925–2928. doi: 10.1016/j.cclet.2020.05.004
7. [7]
  M. Li, B. Gurram, S. Lei, et al., Chin. Chem. Lett. 32 (2021) 1316–1330. doi: 10.1016/j.cclet.2020.09.004
8. [8]
  Y.M. Zhang, J.X. He, W. Zhu, et al., Mater. Sci. Eng. C 100 (2019) 62–69. doi: 10.3390/coatings9010062
9. [9]
  X. Guo, G. Yue, J. Huang, et al., ACS Appl. Mater. Interfaces 10 (2018) 26118–26127. doi: 10.1021/acsami.8b10529
10. [10]
  S. Wang, B. Sun, J. Sun, et al., Dyes Pigm. 202 (2022) 110256. doi: 10.1016/j.dyepig.2022.110256
11. [11]
  X. Zhang, X. Jin, Y. Li, Chin. Chem. Lett. 33 (2022) 2117–2120. doi: 10.1016/j.cclet.2021.08.080
12. [12]
  X. Zhang, L. Zhao, X. Jin, Z. Zhang, Y. Li, Anal. Chim. Acta 1181 (2021) 338905. doi: 10.1016/j.aca.2021.338905
13. [13]
  Y. Li, Y. Ban, R. Wang, et al., Chin. Chem. Lett. 31 (2020) 443–446. doi: 10.3390/biomedicines8100443
14. [14]
  Y. Shi, J. Liu, Y. Zhang, et al., Chin. Chem. Lett. 32 (2021) 3189–3194. doi: 10.1016/j.cclet.2021.03.022
15. [15]
  W.M. Chen, X.L. Meng, G.L. Zhuang, et al., J. Mater. Chem. A 5 (2017) 13079–13085. doi: 10.1039/C7TA01546A
16. [16]
  K. Sheng, H. Lu, A. Sun, et al., Chin. Chem. Lett. 30 (2019) 895–898. doi: 10.1016/j.cclet.2019.01.027
17. [17]
  Y. Li, X. Wang, C. Xing, et al., Chin. Chem. Lett. 30 (2019) 1440–1444. doi: 10.1016/j.cclet.2019.03.014
18. [18]
  M. Yu, Y. Xie, X. Wang, Y. Li, G. Li, ACS Appl. Mater. Interfaces 11 (2019) 21201–21210. doi: 10.1021/acsami.9b05815
19. [19]
  L.Y. Guo, H.F. Su, M. Kurmoo, et al., ACS Appl. Mater. Interfaces 9 (2017) 19980–19987. doi: 10.1021/acsami.7b05191
20. [20]
  X.P. Wang, L.L. Han, Z. Wang, L.Y. Guo, D. Sun, J. Mol. Struct. 1107 (2016) 1–6. doi: 10.1016/j.molstruc.2015.11.018
21. [21]
  X. Jin, L. Zhao, X. Zhang, et al., ACS Appl. Mater. Interfaces 14 (2022) 42267–42276. doi: 10.1021/acsami.2c14071
22. [22]
  X.L. Tao, M.C. Pan, X. Yang, R. Yuan, Y. Zhuo, Chin. Chem. Lett. 33 (2022) 4803–4807. doi: 10.1016/j.cclet.2022.01.010
23. [23]
  S. Prasad, I. Mandal, S. Singh, et al., Chem. Sci. 8 (2017) 5416–5433. doi: 10.1039/C7SC00880E
24. [24]
  M. Xie, C. Han, Q. Liang, et al., Sci. Adv. 5 (2019) eaav9857. doi: 10.1126/sciadv.aav9857
25. [25]
  R.D. Vecchio, N.V. Blough, Environ. Sci. Technol. 38 (2004) 3885–3891. doi: 10.1021/es049912h
26. [26]
  Q. Yan, Y. Yang, W. Chen, et al., Chem. Eng. J. 459 (2023) 141585. doi: 10.1016/j.cej.2023.141585
27. [27]
  Y. Hu, C. Zhao, L. Yin, et al., Chem. Eng. J. 349 (2018) 347–357. doi: 10.1016/j.cej.2018.05.070
28. [28]
  Y. Yang, T. Zou, Z. Wang, et al., Nanomaterials 9 (2019) 738. doi: 10.3390/nano9050738
29. [29]
  H.Q. Yin, X.Y. Wang, X.B. Yin, J. Am. Chem. Soc. 141 (2019) 15166–15173. doi: 10.1021/jacs.9b06755
1. [1]
  Yanqiong Wang , Yaqi Hou , Fengwei Huo , Xu Hou . Fe³⁺ ion quantification with reusable bioinspired nanopores. Chinese Chemical Letters, 2025, 36(2): 110428-. doi: 10.1016/j.cclet.2024.110428
2. [2]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
3. [3]
  Zhao-Bo Hu , Ling-Ao Gui , Long-He Li , Tong-Tong Xiao , Adam T. Hand , Pagnareach Tin , Mykhaylo Ozerov , Yan Peng , Zhongwen Ouyang , Zhenxing Wang , Zi-Ling Xue , You Song . Co^Ⅱ single-ion magnet and its multi-dimensional aggregations: Influence of the structural rigidity on magnetic relaxation process. Chinese Chemical Letters, 2025, 36(2): 109600-. doi: 10.1016/j.cclet.2024.109600
4. [4]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
5. [5]
  Chenghe Yang , Yi Lü , Rui Liu . The Rise to Fame of Digital PCR. University Chemistry, 2025, 40(4): 340-345. doi: 10.12461/PKU.DXHX202406111
6. [6]
  Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
7. [7]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
8. [8]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
9. [9]
  Huanyan Liu , Jiajun Long , Hua Yu , Shichao Zhang , Wenbo Liu . Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes. Chinese Chemical Letters, 2025, 36(3): 109712-. doi: 10.1016/j.cclet.2024.109712
10. [10]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
11. [11]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
12. [12]
  Yuan ZHU , Xiaoda ZHANG , Shasha WANG , Peng WEI , Tao YI . Conditionally restricted fluorescent probe for Fe³⁺ and Cu²⁺ based on the naphthalimide structure. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 183-192. doi: 10.11862/CJIC.20240232
13. [13]
  Shangda Qu , Yiming Yuan , Xu Ye , Wentao Xu . High sensitivity artificial synapses using printed high-transmittance ITO fibers for neuromorphic computing. Chinese Chemical Letters, 2024, 35(12): 110030-. doi: 10.1016/j.cclet.2024.110030
14. [14]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
15. [15]
  Xiaoning Li , Quanyu Shi , Meng Li , Ningxin Song , Yumeng Xiao , Huining Xiao , Tony D. James , Lei Feng . Functionalization of cellulose carbon dots with different elements (N, B and S) for mercury ion detection and anti-counterfeit applications. Chinese Chemical Letters, 2024, 35(7): 109021-. doi: 10.1016/j.cclet.2023.109021
16. [16]
  Jing Chen , Peisi Xie , Pengfei Wu , Yu He , Zian Lin , Zongwei Cai . MALDI coupled with laser-postionization and trapped ion mobility spectrometry contribute to the enhanced detection of lipids in cancer cell spheroids. Chinese Chemical Letters, 2024, 35(4): 108895-. doi: 10.1016/j.cclet.2023.108895
17. [17]
  Wenjie Jiang , Zhixiang Zhai , Xiaoyan Zhuo , Jia Wu , Boyao Feng , Tianqi Yu , Huan Wen , Shibin Yin . Revealing the reactant adsorption role of high-valence WO3 for boosting urea-assisted water splitting. Chinese Journal of Structural Chemistry, 2025, 44(3): 100519-100519. doi: 10.1016/j.cjsc.2025.100519
18. [18]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
19. [19]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
20. [20]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(442)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Highly sensitive Fe3+ luminescence detection via single-ion adsorption

Metrics

通讯作者: 陈斌, bchen63@163.com

Highly sensitive Fe³⁺ luminescence detection via single-ion adsorption