Citation: Tiantian Wang, Man Liu, Jiayi Mao, Yimeng Liang, Lichang Wang, Dongzhi Liu, Tianyang Wang, Wenping Hu. Recent advances in long-persistent luminescence materials based on host–guest architecture[J]. Chinese Chemical Letters, ;2024, 35(1): 108385. doi: 10.1016/j.cclet.2023.108385 shu

Recent advances in long-persistent luminescence materials based on host–guest architecture

Tiantian Wang ^a ,
Man Liu ^a ,
Jiayi Mao ^a ,
Yimeng Liang ^a ,
Lichang Wang ^b ,
Dongzhi Liu ^c ,
Tianyang Wang ^{a, *,} ,
Wenping Hu ^{a, d, e}

a.
Tianjin Key Laboratory of Molecular Optoelectronic Science (TJ-MOS), Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China
b.
Department of Chemistry and Biochemistry and the Materials Technology Center, Southern Illinois University, Carbondale, IL 62901, United States
c.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
d.
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China
e.
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207, China

tianyangwang@tju.edu.cn

Received Date: 20 February 2023
Revised Date: 23 March 2023
Accepted Date: 26 March 2023
Available Online: 28 March 2023

Figures(7)

Organic long-persistent luminescence (LPL) materials, featuring low preparation cost, eco-friendly synthesis, and easy modification of functional groups, have exhibited extensive applications in information encryption, anti-counterfeiting, and biological imaging. Several design strategies including crystallization-inducement, H-aggregation, and host–guest doping to enhance persistent-room-temperature phosphorescence (RTP) effect by precisely controlling intersystem crossing (ISC) constant and suppressing nonradiative decay rates, those are important strategies to enable LPL performance. Among the strategies, researchers have made several efforts to enhance persistent-RTP effect by host–guest interaction, in which the host matrices provide a rigid environment for phosphor guest molecules. The interaction of the luminescent guest molecules with the host matrix can effectively reduce the vibration and rotation of the luminescent molecules, and suppress the non-radiative inactivation, thereby improving the phosphorescence quantum yield. This review aims to summarize several design strategies of pure organic LPL materials based on persistent-RTP effect through host–guest interaction, and describe some applications of pure organic LPL materials in different fields.
- Organic long-persistent luminescence,
- Host–guest interaction,
- Small molecule,
- Macrocyclic,
- Polymer
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沈阳化工大学材料科学与工程学院沈阳 110142