Citation: Yujie Dong, Jun Liu, Xing Gao, Ting Pan, Biming Mao, Songcheng Yu, Yongjun Wu, Cheng Zhang, Hongchao Guo. Pd-catalyzed cascade cyclization of allenylethylene carbonates and indandiones: Synthesis of tetracyclic dihydrocyclopentaindenofuranone derivatives^☆[J]. Chinese Chemical Letters, ;2023, 34(10): 108297. doi: 10.1016/j.cclet.2023.108297 shu

Pd-catalyzed cascade cyclization of allenylethylene carbonates and indandiones: Synthesis of tetracyclic dihydrocyclopentaindenofuranone derivatives^☆

Yujie Dong ^a ,
Jun Liu ^a ,
Xing Gao ^a ,
Ting Pan ^a ,
Biming Mao ^a ,
Songcheng Yu ^b ,
Yongjun Wu ^b ,
Cheng Zhang ^{a, *,} ,
Hongchao Guo ^{a, *,}

a.
Department of Chemistry and Innovation Center of Pesticide Research, China Agricultural University, Beijing 100193, China
b.
College of Public Health, Zhengzhou University, Zhengzhou 450001, China

^☆

zhangc9711@cau.edu.cn

hchguo@cau.edu.cn

Received Date: 5 December 2022
Revised Date: 24 February 2023
Accepted Date: 1 March 2023
Available Online: 6 March 2023

Figures(5)

A palladium-catalyzed cascade cyclization of allenylethylene carbonates with 1,3-indandiones was developed, providing biologically interesting tetracyclic dihydrocyclopentaindenofuranone derivatives having three contiguous quaternary carbon centers in moderate to high yields with excellent diastereoselectivities. In this reaction, the allene moiety was fully fused into the cyclopentene ring.
- Palladium,
- Allenylethylene carbonates,
- Indandiones,
- Cascade cyclization,
- Decarboxylation
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沈阳化工大学材料科学与工程学院沈阳 110142

Pd-catalyzed cascade cyclization of allenylethylene carbonates and indandiones: Synthesis of tetracyclic dihydrocyclopentaindenofuranone derivatives☆

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通讯作者: 陈斌, bchen63@163.com

Pd-catalyzed cascade cyclization of allenylethylene carbonates and indandiones: Synthesis of tetracyclic dihydrocyclopentaindenofuranone derivatives^☆