Citation: Xiyang Wang, Keke Huang, Xiaofeng Wu, Long Yuan, Liping Li, Guangshe Li, Shouhua Feng. Manipulation and observation of atomic-scale superlattices in perovskite manganate[J]. Chinese Chemical Letters, ;2023, 34(12): 108267. doi: 10.1016/j.cclet.2023.108267 shu

Manipulation and observation of atomic-scale superlattices in perovskite manganate

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin Provincial International Cooperation Key Laboratory of Advanced Inorganic Solid Functional Materials, Jilin University, Changchun 130012, China

shfeng@jlu.edu.cn

Received Date: 20 October 2022
Revised Date: 23 February 2023
Accepted Date: 23 February 2023
Available Online: 27 February 2023

Figures(4)

Superlattices in crystals, particularly in perovskite oxides with strong correlation effects, can create new states of matter and produce peculiar physicochemical phenomena. However, the newfangled perovskite superlattices depend on physical deposition with unit-cell precision. It has been challenging to explore a new suitable chemical method to tailor perovskite superlattices. Herein, we present a new bottom-up strategy to precisely prepare atomic-scale oxide superlattices of (LaMnO₃)₁-(La_1-x-yCa_xK_yMnO₃)₂ in a monodispersed perovskite La_0.66Ca_0.29K_0.05MnO₃ (LCKMO). The special atomic-scale perovskite superlattices are demonstrated using SAED, HAADF-STEM, XRD, and atomic-resolution elemental mapping. Our experiments reveal that the perovskite superlattices can be fabricated under extreme hydrothermal conditions utilizing ultra-high concentrations of KOH. An approximate molten salt system in the hydrothermal process can induce the disproportionation reaction of MnO₂ solids, which is vital to the growth of ordered perovskite superlattices. This work not only clarifies the hydrothermal growth process of perovskite oxides in extreme conditions, but also proposes a novel engineering route toward perovskite superlattices.
- Perovskite oxides,
- Hydrothermal,
- Ordered superstructure,
- Perovskite superlattice,
- Disproportionation reaction
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