Citation: Baijie Xu, Ruikun Zhao, Zhen Jing, Xinyi Ma, Hui Zhao, Pengtao Ma, Jingping Wang, Jingyang Niu. Ln-substituted polytungstates as efficient hetergeneous catalysts for Knoevenagel condensation reaction[J]. Chinese Chemical Letters, ;2023, 34(12): 108249. doi: 10.1016/j.cclet.2023.108249 shu

Ln-substituted polytungstates as efficient hetergeneous catalysts for Knoevenagel condensation reaction

Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

jpwang@henu.edu.cn

jyniu@henu.edu.cn

Received Date: 19 October 2022
Revised Date: 6 January 2023
Accepted Date: 20 February 2023
Available Online: 24 February 2023

Figures(1)

Three isomorphic polytungstates, Cs₉K₁₈H₁₀{[Sm₂(H₂O)₄W₄O₁₀(AsW₉O₃₃)₃]₂(N(CH₂PO₃)₂)}·46.5H₂O (1), Cs₁₀K₉H₁₈{[Eu₂(H₂O)₄W₄O₁₀(AsW₉O₃₃)₃]₂(N(CH₂PO₃)₂)}·41.5H₂O (2), Cs₁₀K₉H₁₈{[Gd₂(H₂O)₄W₄O₁₀ (AsW₉O₃₃)₃]₂(N(CH₂PO₃)₂)}·46H₂O (3), have been successfully synthesized and characterized by routine methods, and demonstrated excellent catalytic activities in Knoevenagel condensation reaction as heterogeneous catalysts. Notably, catalyst 1 achieved higher reaction activity than catalysts 2 and 3, where a satisfactory reaction yield (95%) and high TON value (6380) could be obtained at moderate reaction condition. In addition, in the scale-up experiment, with the help of catalyst 1, 7.8 g benzaldehyde and 5.7 g ethyl cyanoacetate could transform into corresponding condensation product with a satisfactory yield (83%) and impressive TON value (13,883).
- Polyoxometalates,
- Polytungstates,
- Lanthanide,
- Lewis acid and base sites,
- Knoevenagel condensation reaction
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