Citation: Xingyi Zhang, Modeste Venin Mendieev Nitou, Wenjun Li, Zhao Wan, Longfei Liu, Zhaohui Luo, Sohail Muhammad, Wu Qin, Liang An, Yinghua Niu, Weiqiang Lv. Enhanced Li⁺ migration in solid polymer electrolyte driven by anion-containing polymer-chains[J]. Chinese Chemical Letters, ;2023, 34(11): 108245. doi: 10.1016/j.cclet.2023.108245 shu

Enhanced Li⁺ migration in solid polymer electrolyte driven by anion-containing polymer-chains

Xingyi Zhang ^{a, b, 1} ,
Modeste Venin Mendieev Nitou ^{a, b, 1} ,
Wenjun Li ^{a, b} ,
Zhao Wan ^b ,
Longfei Liu ^b ,
Zhaohui Luo ^c ,
Sohail Muhammad ^{a, b} ,
Wu Qin ^d ,
Liang An ^e ,
Yinghua Niu ^{a, b, f, *,} ,
Weiqiang Lv ^{a, b, *,}

a.
Yangtze Delta Region Institute (Huzhou), University of Electronic Science and Technology of China, Huzhou 313001, China
b.
School of physics, University of electronic Science and Technology of China, Chengdu 611731, China
c.
X-Energy Systems Co., Ltd., Jiaxing 314000, China
d.
National Engineering Laboratory for Biomass Power Generation Equipment, School of Renewable Energy Engineering, North China Electric Power University, Beijing 102206, China
e.
Department of Mechanical Engineering, the Hong Kong Polytechnic University, Hong Kong, China
f.
Zhejiang Humo Polishing Grinder Manufacture Co., Ltd., Huzhou 313012, China

yh_niu@aliyun.com

eselwq@uestc.edu.cn

Received Date: 12 December 2022
Revised Date: 17 January 2023
Accepted Date: 16 February 2023
Available Online: 19 February 2023

Figures(4)

Li-ion batteries with solid polymer electrolytes (SPEs) are safer than conventional liquid electrolytes due to the absence of highly flammable liquid electrolytes. However, their performance is limited by the poor Li⁺ transport in SPEs at room temperature. Anion-containing polymer-chains incorporated SPEs (ASPEs) are therefore developed to enhance Li⁺ diffusion kinetics. Herein, we propose a novel and feasible strategy to incorporate the anion-containing polymer-chains, such as lithiated perfluorinated sulfonic acid (PFSA), into polyvinylidene fluoride (PVDF) polymer-based SPEs. The immobile anion groups from the PFSA-chains impede the migration of mobile anion groups dissociated from the Li salt. The transference number is thus raised from ~0.3 to 0.52 with the introduction of anion-containing polymer-chains into SPEs. The electrostatic repulsion among anion-containing chains also reduces the close chain stacking and brings 159% increase in the ionic conductivity to 0.83 × 10⁻³ S/cm at 30 ℃ in contrast with the pure PVDF-based SPE. In addition, LiFeO₄/Li batteries with ASPEs exhibit 55% capacity boost at 0.5 C in contrast to the capacity of batteries with pure-PVDF SPEs, and also offer more than 1000 charge/discharge cycles. Our research findings potentially offer a facile strategy to design thermal stable SPEs with superior Li⁺ transport behaviors towards developing high-performance SPEs-based batteries.
- Solid polymer electrolyte,
- Lithiated perfluorinated sulfonic acid,
- Polyvinylidene fluoride,
- Solid-state battery,
- Anion containing polymer
1. [1]
  L. Lu, X. Han, J. Li, J. Hua, M. Ouyang, J. Power Source 226 (2013) 272–288. doi: 10.1016/j.jpowsour.2012.10.060
2. [2]
  R. Chen, Q. Li, X. Yu, L. Chen, H. Li, Chem. Rev. 120 (2020) 6820–6877. doi: 10.1021/acs.chemrev.9b00268
3. [3]
  R.P. Doyle, X. Chen, M. Macrae, et al., Macromolecules 47 (2014) 3401–3408. doi: 10.1021/ma402325a
4. [4]
  C.L. Yan, Rare Metal 39 (2020) 458–459. doi: 10.1007/s12598-020-01417-1
5. [5]
  N. Meng, F. Lian, G. Cui, Small 17 (2021) e2005762. doi: 10.1002/smll.202005762
6. [6]
  W. Kou, Y. Zhang, W. Wu, et al., Green Energy Environ. (2022), doi: 10.1016/j.gee.2022.05.002. doi: 10.1016/j.gee.2022.05.002
7. [7]
  T.K.L. Nguyen, G. Lopez, C. Iojoiu, R. Bouchet, B. Ameduri, J. Power Source 498 (2021) 229920. doi: 10.1016/j.jpowsour.2021.229920
8. [8]
  J. Zhang, J. Zhao, L. Yue, et al., Adv. Energy Mater. 5 (2015) 1501082. doi: 10.1002/aenm.201501082
9. [9]
  C. Yang, K. Fu, Y. Zhang, E. Hitz, L. Hu, Adv. Mater. 29 (2017) 1701169. doi: 10.1002/adma.201701169
10. [10]
  Z. Xue, D. He, X. Xie, J. Mater. Chem. A 3 (2015) 19218–19253. doi: 10.1039/C5TA03471J
11. [11]
  Y.N. Liu, Z. Xiao, W.K. Zhang, et al., Rare Metal 41 (2022) 3762–3773. doi: 10.1007/s12598-022-02065-3
12. [12]
  A.L. Chen, N. Shang, Y. Ouyang, et al., eScience 2 (2022) 192–200. doi: 10.1016/j.esci.2022.02.003
13. [13]
  P.Y. Ji, J. Fang, Y.Y. Zhang, P. Zhang, J.B. Zhao, ChemElectroChem 4 (2017) 2352–2358. doi: 10.1002/celc.201700256
14. [14]
  W. Pu, X. He, L. Wang, C. Jiang, C. Wan, J. Membr. Sci. 272 (2006) 11–14. doi: 10.1016/j.memsci.2005.12.038
15. [15]
  W. Xu, X.G. Sun, C.A. Angell, Electrochim. Acta 48 (2003) 2255–2266. doi: 10.1016/S0013-4686(03)00212-3
16. [16]
  W. Wieczorek, D. Raducha, A. Zalewska, J.R. Stevens, J. Phys. Chem. B 102 (1998) 8725–8731. doi: 10.1021/jp982403f
17. [17]
  Q. Ma, H. Zhang, C. Zhou, et al., Angew. Chem. Int. Ed. 55 (2016) 2521–2525. doi: 10.1002/anie.201509299
18. [18]
  P. Lightfoot, M.A. Mehta, P.G. Bruce, Science 262 (1993) 883–885. doi: 10.1126/science.262.5135.883
19. [19]
  J. Cao, D. Zhang, R. Chanajaree, et al., Adv. Powder Mater. 1 (2022) 100007. doi: 10.1016/j.apmate.2021.09.007
20. [20]
  Z. Cai, Y. Liu, S. Liu, L. Li, Y. Zhang, Energy Environ. Sci. 5 (2012) 5690–5693. doi: 10.1039/C1EE02708E
21. [21]
  Q. Liu, G. Yang, X. Li, et al., Energy Storage Mater. 51 (2022) 443–452. doi: 10.1016/j.ensm.2022.06.040
22. [22]
  H. Huo, B. Wu, T. Zhang, et al., Energy Storage Mater. 18 (2019) 59–67. doi: 10.1016/j.ensm.2019.01.007
23. [23]
  C. Ma, Y. Feng, F. Xing, et al., J. Mater. Chem. A 7 (2019) 19970–19976. doi: 10.1039/C9TA07551H
24. [24]
  C. Niu, J. Liu, G. Chen, et al., J. Power Source 417 (2019) 70–75. doi: 10.1016/j.jpowsour.2019.02.004
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  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
14. [14]
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16. [16]
  Yang Deng , Yitao Ouyang , Chao Han . Constriction-susceptible makes fast cycling of lithium metal in solid-state batteries: Silicon as an example. Chinese Journal of Structural Chemistry, 2024, 43(7): 100276-100276. doi: 10.1016/j.cjsc.2024.100276
17. [17]
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18. [18]
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Enhanced Li⁺ migration in solid polymer electrolyte driven by anion-containing polymer-chains