Citation: Kexin Ma, Jing Li, Huiyan Ma, Yan Yang, Hua Yang, Jing Lu, Yunwu Li, Jianmin Dou, Suna Wang, Suijun Liu. 2D Cd-MOF and its mixed-matrix membranes for luminescence sensing antibiotics in various aqueous systems and visible fingerprint identifying[J]. Chinese Chemical Letters, ;2023, 34(11): 108227. doi: 10.1016/j.cclet.2023.108227 shu

2D Cd-MOF and its mixed-matrix membranes for luminescence sensing antibiotics in various aqueous systems and visible fingerprint identifying

Kexin Ma ^a ,
Jing Li ^a ,
Huiyan Ma ^a ,
Yan Yang ^a ,
Hua Yang ^a ,
Jing Lu ^a ,
Yunwu Li ^{a, *,} ,
Jianmin Dou ^a ,
Suna Wang ^{a, *,} ,
Suijun Liu ^{b, *,}

a.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China
b.
School of Chemistry and Chemical Engineering, Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

liyunwu@lcu.edu.cn

wangsuna@lcu.edu.cn

sjliu@jxust.edu.cn

Received Date: 2 January 2023
Revised Date: 30 January 2023
Accepted Date: 14 February 2023
Available Online: 16 February 2023

Figures(5)

The abuse of antibiotics has brought great harm to the human living environment and health, so it is extremely significant to develop an efficient and simple method to detect trace antibiotic residues in various wastewaters. Herein, a new two-dimensional (2D) Cd-based metal−organic framework (Cd-MOF, namely LCU-111) and its mixed matrix membranes (MMMs) is sifted as luminescence sensors for efficient monitoring antibiotic nitrofurazone (NFZ) in various aqueous systems and applied as visible fingerprint identifying. The LCU-111 has good selectivity, sensibility, reproducibility and anti-interference for luminescent quenching NFZ with low detection limits (LODs) of 0.4567, 0.3649 and 0.8071 ppm in aqueous solution, HEPES biological buffer, and real urban Tuhai River water, respectively. Interestingly, the luminescent test papers and MMMs allow the NFZ sensing easier and more rapid by naked eyes, only with a low LOD of 0.8117 ppm for MMMs sensor. Notably, by combining multiple experiments with density functional theory (DFT) calculations, the photo-induced electron transfer (PET) quenching mechanism is further elucidated. More importantly, potential practical applications of LCU-111 for latent fingerprint visualization provide lifelike evidences for effective identification of individuals, which can be applied in criminal investigation.
- MOF luminescence sensor,
- Mixed-matrix membranes,
- Real urban river water,
- Antibiotic nitrofurazone,
- Visible fingerprint identifying
1. [1]
  Y.Z. Tang, H.L. Huang, W.J. Xue, et al., Chem. Eng. J. 384 (2020) 123382. doi: 10.1016/j.cej.2019.123382
2. [2]
  H.K. Li, H.L. Ye, X.X. Zhao, et al., Chin. Chem. Lett. 32 (2021) 2851–2855. doi: 10.1016/j.cclet.2021.02.042
3. [3]
  Q.Q. Chu, B. Zhang, H.F. Zhou, et al., Inorg. Chem. 59 (2020) 2853–2860. doi: 10.1021/acs.inorgchem.9b03176
4. [4]
  S.L. Hou, J. Dong, X.L. Jiang, et al., Anal. Chem. 90 (2018) 1516–1519. doi: 10.1021/acs.analchem.7b05088
5. [5]
  H.T. Bai, H.X. Yuan, C.Y. Nie, et al., Angew. Chem. Int. Ed. 127 (2015) 13406–13411. doi: 10.1002/ange.201504566
6. [6]
  L. Ding, Y.Y. Zhao, H.H. Li, et al., J. Hazard. Mater. 416 (2021) 125759. doi: 10.1016/j.jhazmat.2021.125759
7. [7]
  Z.Z. Liang, H.B. Guo, H.T. Lei, et al., Chin. Chem. Lett. 33 (2022) 3999–4002. doi: 10.1016/j.cclet.2021.11.055
8. [8]
  X.P. Quan, B. Yan, ACS Appl. Mater. Interfaces 14 (2022) 49072–49081. doi: 10.1021/acsami.2c12822
9. [9]
  Z.J. Ke, K.X. Chen, Z.Z. Li, et al., Chin. Chem. Lett. 32 (2021) 3109–3112. doi: 10.1016/j.cclet.2021.03.043
10. [10]
  J.J. Hou, P. Jia, K.R. Yang, et al., ACS Appl. Mater. Interfaces 14 (2022) 13848–13857. doi: 10.1021/acsami.1c23199
11. [11]
  H.K. Li, Z.Y. Han, Q.Q. Zhu, et al., Chin. Chem. Lett. 32 (2021) 2865–2868. doi: 10.1016/j.cclet.2021.02.013
12. [12]
  L.L. Wang, P.L. Zheng, W.L. Zhang, et al., Mater. Today Commun. 16 (2018) 258–263. doi: 10.1016/j.mtcomm.2018.06.011
13. [13]
  H.H. Yu, Q. Liu, M.Y. Fan, et al., Dyes Pigm. 197 (2022) 109812. doi: 10.1016/j.dyepig.2021.109812
14. [14]
  S.J. Zhang, R.H. Liu, Q.L. Cui, et al., ACS Appl. Mater. Interfaces 9 (2017) 44134–44145. doi: 10.1021/acsami.7b15612
15. [15]
  N. Seal, M. Singh, S. Das, et al., Mater. Chem. Front. 5 (2021) 979–994. doi: 10.1039/D0QM00721H
16. [16]
  Y. Li, B.L. Chai, H. Xu, et al., Inorg. Chem. Front. 9 (2022) 1504–1513. doi: 10.1039/D2QI00023G
17. [17]
  W.P. Lustig, S. Mukherjee, N.D. Rudd, et al., Chem. Soc. Rev. 46 (2017) 3242–3285. doi: 10.1039/C6CS00930A
18. [18]
  H. Zheng, Y.K. Deng, M.Y. Ye, et al., Inorg. Chem. 59 (2020) 12404–12409. doi: 10.1021/acs.inorgchem.0c01494
1. [1]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
2. [2]
  Yubin Feng , Weihang Zhu , Xinting Yang , Zhe Yang , Chenke Wei , Yukai Guo , Andrew K. Whittaker , Chun Shen , Yue Zhao , Wenrui Qu , Bai Yang , Quan Lin . Amphibian-inspired conductive ionogel stabilizing in air/water as a wearable amphibious flexible sensor for drowning alarms. Chinese Chemical Letters, 2025, 36(4): 110554-. doi: 10.1016/j.cclet.2024.110554
3. [3]
  Yuxin Li , Chengbin Liu , Qiuju Li , Shun Mao . Fluorescence analysis of antibiotics and antibiotic-resistance genes in the environment: A mini review. Chinese Chemical Letters, 2024, 35(10): 109541-. doi: 10.1016/j.cclet.2024.109541
4. [4]
  Liang Dong , Jingkuo Qu , Tuo Zhang , Guanghui Zhu , Ningning Ma , Chang Zhao , Yi Yuan , Xiangjiu Guan , Liejin Guo . MOF-derived NiCo bimetallic cocatalyst for enhanced photocatalytic overall water splitting. Chinese Chemical Letters, 2025, 36(3): 110397-. doi: 10.1016/j.cclet.2024.110397
5. [5]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
6. [6]
  Lixian Fu , Yiyun Tan , Yue Ding , Weixia Qing , Yong Wang . Water–soluble and polarity–sensitive near–infrared fluorescent probe for long–time specific cancer cell membranes imaging and C. Elegans label. Chinese Chemical Letters, 2024, 35(4): 108886-. doi: 10.1016/j.cclet.2023.108886
7. [7]
  Yuting Wu , Haifeng Lv , Xiaojun Wu . Design of two-dimensional porous covalent organic framework semiconductors for visible-light-driven overall water splitting: A theoretical perspective. Chinese Journal of Structural Chemistry, 2024, 43(11): 100375-100375. doi: 10.1016/j.cjsc.2024.100375
8. [8]
  Tiantian Man , Fulin Zhu , Yaqi Huang , Yuhao Piao , Yan Su , Shengyuan Deng , Ying Wan . Mobile mini-fluorimeter for antibiotic aptasensing based on surface-plasmonic effect of burlike nanogolds enhanced by digitized imaging diagnosis. Chinese Chemical Letters, 2024, 35(5): 109036-. doi: 10.1016/j.cclet.2023.109036
9. [9]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
10. [10]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
11. [11]
  Xueling Yu , Lixing Fu , Tong Wang , Zhixin Liu , Na Niu , Ligang Chen . Multivariate chemical analysis: From sensors to sensor arrays. Chinese Chemical Letters, 2024, 35(7): 109167-. doi: 10.1016/j.cclet.2023.109167
12. [12]
  Lixian Cai , Yingxiang Ye . A flexible-robust MOF for efficient purification of perfluoropropane. Chinese Journal of Structural Chemistry, 2024, 43(11): 100368-100368. doi: 10.1016/j.cjsc.2024.100368
13. [13]
  Guangyao Wang , Zhitong Xu , Ye Qi , Yueguang Fang , Guiling Ning , Junwei Ye . Electrospun nanofibrous membranes with antimicrobial activity for air filtration. Chinese Chemical Letters, 2024, 35(10): 109503-. doi: 10.1016/j.cclet.2024.109503
14. [14]
  Shihong Wu , Ronghui Zhou , Hang Zhao , Peng Wu . Sonoafterglow luminescence for in vivo deep-tissue imaging. Chinese Chemical Letters, 2024, 35(10): 110026-. doi: 10.1016/j.cclet.2024.110026
15. [15]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
16. [16]
  Neng Shi , Haonan Jia , Jixiang Zhang , Pengyu Lu , Chenglong Cai , Yixin Zhang , Liqiang Zhang , Nongyue He , Weiran Zhu , Yan Cai , Zhangqi Feng , Ting Wang . Accurate expression of neck motion signal by piezoelectric sensor data analysis. Chinese Chemical Letters, 2024, 35(9): 109302-. doi: 10.1016/j.cclet.2023.109302
17. [17]
  Dian-Xue Ma , Yu-Wu Zhong . Achieving highly-efficient room-temperature phosphorescence with a nylon matrix. Chinese Journal of Structural Chemistry, 2024, 43(9): 100391-100391. doi: 10.1016/j.cjsc.2024.100391
18. [18]
  Ming-Yi Sun , Lu Zhang , Ya Li , Chong-Chen Wang , Peng Wang , Xueying Ren , Xiao-Hong Yi . Recovering Ag⁺ with nano-MOF-303 to form Ag/AgCl/MOF-303 photocatalyst: The role of stored Cl⁻ ions. Chinese Chemical Letters, 2025, 36(2): 110035-. doi: 10.1016/j.cclet.2024.110035
19. [19]
  Yinglan Yu , Sajid Hussain , Jianping Qi , Lei Luo , Xuemei Zhang . Mechanisms and applications: Cargos transport to basolateral membranes in polarized epithelial cells. Chinese Chemical Letters, 2024, 35(12): 109673-. doi: 10.1016/j.cclet.2024.109673
20. [20]
  Kai Ye , Zhicheng Ye , Chuantao Wang , Zhilai Luo , Cheng Lian , Chunyan Bao . Artificial signal transduction triggered by molecular photoisomerization in lipid membranes. Chinese Chemical Letters, 2025, 36(4): 110033-. doi: 10.1016/j.cclet.2024.110033

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(532)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142