Citation: Yu-Han Lu, Zhuo-Tao Zhang, Hong-Yu Wu, Min-Hang Zhou, Hai-Yang Song, Hong-Tao Ji, Jun Jiang, Jin-Yang Chen, Wei-Min He. TBAI/H₂O-cooperative electrocatalytic decarboxylation coupling-annulation of quinoxalin-2(1H)-ones with N-arylglycines[J]. Chinese Chemical Letters, ;2023, 34(7): 108036. doi: 10.1016/j.cclet.2022.108036 shu

TBAI/H₂O-cooperative electrocatalytic decarboxylation coupling-annulation of quinoxalin-2(1H)-ones with N-arylglycines

a.
Hengyang Medical School, University of South China, Hengyang 421001, China
b.
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China

weiminhe@usc.edu.cn

Received Date: 27 September 2022
Revised Date: 30 November 2022
Accepted Date: 1 December 2022
Available Online: 5 December 2022

Figures(7)

The first example of TBAI/H₂O cooperative electrocatalytic coupling-annulation of quinoxalin-2(1H)-ones with N-arylglycines was developed. A broad range of tetrahydroimidazo[1,5-a]quinoxalin-4(5H)-ones were obtained in good to excellent yields with exclusive chemoselectivities and excellent regioselectivities. The H-hydrogen bond served as a key factor for the electrocatalytic production of aminomethyl radical at lower oxidative potential.
- Green chemistry,
- Electrochemistry,
- Aminomethyl radical,
- Annulation reaction
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TBAI/H2O-cooperative electrocatalytic decarboxylation coupling-annulation of quinoxalin-2(1H)-ones with N-arylglycines

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通讯作者: 陈斌, bchen63@163.com

TBAI/H₂O-cooperative electrocatalytic decarboxylation coupling-annulation of quinoxalin-2(1H)-ones with N-arylglycines