Citation: Huan Liu, Longfeng Hu, Razium A. Soomro, Bin Xu. Organic salt-derived phosphorus-doped mesoporous carbon for high performance supercapacitors[J]. Chinese Chemical Letters, ;2023, 34(8): 108004. doi: 10.1016/j.cclet.2022.108004 shu

Organic salt-derived phosphorus-doped mesoporous carbon for high performance supercapacitors

Huan Liu ^{a, b, 1} ,
Longfeng Hu ^{b, 1} ,
Razium A. Soomro ^b ,
Bin Xu ^{b, *,}

a.
College of Materials Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
b.
State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China

xubin@mail.buct.edu.cn

Received Date: 24 October 2022
Revised Date: 6 November 2022
Accepted Date: 13 November 2022
Available Online: 22 November 2022

Figures(4)

Phosphorus-doped mesoporous carbons (PMCs) were prepared using a self-doping and self-templating approach via direct pyrolysis of sodium phytate (C₆H₁₇NaO₂₄P₆). The one-pot method allows simultaneous carbonization and P doping, eliminating the need for pre-synthesis or post-activation treatment. The C₆H₁₇NaO₂₄P₆ is the source of both carbon and phosphorus, and the nano-Na₄P₂O₇ particles produced during pyrolysis act as hard templates for the honeycomb mesoporous structure with high specific surface area (884–827 m²/g), large mesopore volume ratio (67%–75%) and rich phosphorus content (0.53–2.34 at%). As electrodes of supercapacitors in 6 mol/L KOH, the PMCs showed outstanding performance with a high capacitance of 202 F/g and excellent rate performance of 148 F/g at 30 A/g. In addition, the PMCs-based symmetrical supercapacitors can operate in an expanded working voltage of 0–1.6 V in 3 mol/L H₂SO₄ aqueous electrolytes with high-density energy of 11.8 Wh/kg.
- Supercapacitors,
- Mesoporous carbon,
- Phosphorus doping,
- Expanded voltage window,
- Heteroatoms doping
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