Citation: Yanjie Wang, Cheng Tang, Min Su, Yixiong Ji, Lei Xie, Qi Yang, Aijun Du, Yong Zhou, Jun Yang. Highly sensitive, humidity-tolerant and flexible NO₂ sensors based on nanoplate Bi₂Se₃ film[J]. Chinese Chemical Letters, ;2023, 34(8): 107981. doi: 10.1016/j.cclet.2022.107981 shu

Highly sensitive, humidity-tolerant and flexible NO₂ sensors based on nanoplate Bi₂Se₃ film

Yanjie Wang ^a ,
Cheng Tang ^b ,
Min Su ^c ,
Yixiong Ji ^c ,
Lei Xie ^a ,
Qi Yang ^c ,
Aijun Du ^b ,
Yong Zhou ^{a, *,} ,
Jun Yang ^{c, *,}

a.
Key Laboratory of Optoelectronic Technology and System of Ministry of Education, College of Optoelectronic Engineering, Chongqing University, Chongqing 400044, China
b.
School of Chemistry and Physics, Centre of Materials Science, Queensland University of Technology, Brisbane 4001, Australia
c.
Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China

zhyf@cqu.edu.cn

jyang@cigit.ac.cn

Received Date: 24 June 2022
Revised Date: 1 August 2022
Accepted Date: 2 November 2022
Available Online: 5 November 2022

Figures(4)

Recently, two-dimension (2D) materials have fueled considerable interest in the field of gas sensing to cope urgent demands at specific scenarios. Unfortunately, the susceptibility to ambient humidity, and/or fragile operation stability always frustrate their further practicability. To overcome these drawbacks, we proposed one novel flexible gas sensor based on bismuth selenide (Bi₂Se₃) nanoplates for sensitive NO₂ detection at room temperature. The as-prepared Bi₂Se₃ sensor exhibited favorable sensing performance, including remarkable NO₂ selectivity, high response of 120% and fast response time of 81 s toward 5 ppm NO₂, an ultralow detection limit of 100 ppb, and nice stability. Besides, the excellent humidity tolerance and mechanical flexibility endowed Bi₂Se₃ sensors with admirable reliability under harsh working conditions. The first-principles calculation further revealed the insights of extraordinary NO₂ selectivity and the underlying gas-sensing mechanism.
- Flexible NO₂ sensor,
- Bi₂Se₃ nanoplates,
- Humidity tolerance,
- Room-temperature operation,
- First-principles calculation
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Highly sensitive, humidity-tolerant and flexible NO2 sensors based on nanoplate Bi2Se3 film

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Highly sensitive, humidity-tolerant and flexible NO₂ sensors based on nanoplate Bi₂Se₃ film