Citation: Xue Wang, Meiwei Huang, Zhaoben Su, Libo Qian, Yong Guo, Qing-Yun Chen, Chengying Wu, Tao lv, Qin Su, Qing Shen, Jie Ma. Surface activity of a series of fluoroether betaine amphoteric surfactants: Oxygen roles[J]. Chinese Chemical Letters, ;2023, 34(3): 107961. doi: 10.1016/j.cclet.2022.107961 shu

Surface activity of a series of fluoroether betaine amphoteric surfactants: Oxygen roles

Xue Wang ^{a, b} ,
Meiwei Huang ^{b, *,} ,
Zhaoben Su ^b ,
Libo Qian ^b ,
Yong Guo ^b ,
Qing-Yun Chen ^{b, *,} ,
Chengying Wu ^c ,
Tao lv ^c ,
Qin Su ^d ,
Qing Shen ^d ,
Jie Ma ^a

a.
School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China
b.
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
c.
Sanming Hexafluo Chemicals Company, Ltd., Fluorinated New Material Industry Park, Sanming 365200, China
d.
Shanghai Huayi 3F New Materials Co., Ltd., Shanghai 200241, China

^☆

hmw@sioc.ac.cn

chenqy@sioc.ac.cn

Received Date: 24 August 2022
Revised Date: 22 October 2022
Accepted Date: 26 October 2022
Available Online: 28 October 2022

Figures(6)

As PFOS, PFOA and their derivatives were banned according to the Stockholm Convention for their potential bioaccumulation and toxicity, people attempted to substitute the legacy fluorosurfactants with short-chain ones. Although short-chain alternatives can alleviate bioaccumulation, surface activity was compromised. Fluorine industry kept seeking for effective solution. In this work, we prepared and investigated a series of fluoroether betaine surfactants for their surface activity and spreading property. The role of oxygen on surface activity was discussed. We found that insertion of oxygen atoms into fluorinated chain could increase hydrophobicity and thus enhance surface activity. The contribution of one oxygen is approximately half of that of a difluoromethylene group by experience. Moreover, introducing oxygen diversified the structure to fill in the gap of surface activity between short and long fluorosurfactants. In summary, this work provided basic knowledge for molecular design.
- Environmental chemistry,
- Surfactant,
- Fluorine,
- Oxygen,
- Sustainable chemistry
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