Citation: Peng Liu, Bingqing Li, Jianli Zhang, Hongfu Jiang, Zhong Su, Chao Lai. Self-swelling derived frameworks with rigidity and flexibility enabling high-reversible silicon anodes[J]. Chinese Chemical Letters, ;2023, 34(8): 107946. doi: 10.1016/j.cclet.2022.107946 shu

Self-swelling derived frameworks with rigidity and flexibility enabling high-reversible silicon anodes

Peng Liu ^a ,
Bingqing Li ^a ,
Jianli Zhang ^b ,
Hongfu Jiang ^b ,
Zhong Su ^{a, *,} ,
Chao Lai ^{a, *,}

a.
School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou 221116, China
b.
Jiangsu Xinhua Semiconductor Material Technology Co., Ltd., Xuzhou 221116, China

suzhongjs@163.com

laichao@jsnu.edu.cn

Received Date: 8 September 2022
Revised Date: 10 October 2022
Accepted Date: 24 October 2022
Available Online: 29 October 2022

Figures(5)

Silicon is recognized as the most advantageous next-generation anode material for LIBs in terms of its extremely high theoretical capacity and appropriate operating voltage. However, the application of Si anode is limited by huge volume expansion emerging with cycling, which in turn induces the collapse of the electrode structure, resulting in rapid capacity decay. Here, we report a strategy using self-swelling artificial laponite to prepare a laponite/MXene/CNT composite framework with both rigidity and flexibility, which can excellently address these challenges of Si anode. The self-swelling artificial laponite participates in the construction of hierarchical and porous structures, providing sufficient buffer space to mitigate the volume expansion of the Li_xSi alloying reaction. Meanwhile, tough and tightly cross-linked silicate nanosheets can improve the mechanical strength of the framework for strong structural stability. More importantly, the negative charge between the layers of artificial laponite can effectively promote fast Li-ion transport in the electrode. This free-standing silicon anode enables the preparation of high areal capacity electrodes to further enhance the energy density of LIBs and a higher reversible capacity of 2381.8 mAh/g at 0.1 C after 50 cycles with an initial coulombic of 85.6%. This work provides a simple and practical fabrication strategy for developing high-performance Si-based batteries, which can speed up their commercialization.
- Self-swelling derived framework,
- High mass loading,
- High areal capacity,
- Si anodes,
- Free-binder
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沈阳化工大学材料科学与工程学院沈阳 110142