Citation: Ang Li, Mengke Huang, Die Hu, Zhaodi Tang, Jianhang Xu, Yang Li, Xiaowei Zhang, Xiao Chen, Ge Wang. Polydopamine-coated metal-organic framework-based composite phase change materials for photothermal conversion and storage[J]. Chinese Chemical Letters, ;2023, 34(8): 107916. doi: 10.1016/j.cclet.2022.107916 shu

Polydopamine-coated metal-organic framework-based composite phase change materials for photothermal conversion and storage

Ang Li ^{a, 1,*,} ,
Mengke Huang ^{b, 1} ,
Die Hu ^b ,
Zhaodi Tang ^b ,
Jianhang Xu ^b ,
Yang Li ^c ,
Xiaowei Zhang ^c ,
Xiao Chen ^{c, d, *,} ,
Ge Wang ^{b, e, *,}

a.
School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China
b.
Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
c.
Institute of Advanced Materials, Beijing Normal University, Beijing 100875, China
d.
Key Laboratory of Low-grade Energy Utilization Technologies and Systems (Chongqing University), Ministry of Education of China, Chongqing University, Chongqing 400044, China
e.
Shunde Graduate School, University of Science and Technology Beijing, Shunde 528399, China

angli@usts.edu.cn

xiaochen@bnu.edu.cn

gewang@ustb.edu.cn

Received Date: 29 August 2022
Revised Date: 8 October 2022
Accepted Date: 17 October 2022
Available Online: 19 October 2022

Figures(4)

The liquid leakage and weak solar absorption capacity of organic phase change materials (PCMs) seriously hinder the efficient utilization of solar energy and thermal energy storage. To address these issues, we prepared nanoporous metal organic framework (Ni-MOF) for the vacuum infiltration of paraffin wax (PW), followed by the coating of solar-absorbing functional polydopamine (PDA) on the surface of PW@MOF for photothermal conversion and storage. As an efficient photon harvester, PDA coating endows PW@MOF/PDA composite PCMs with excellent photothermal conversion and storage properties due to the robust broadband solar absorption capability in the UV–vis region. Resultantly, our prepared PW@MOF/PDA composite PCMs exhibit a high photothermal conversion and storage efficiency of 91.2%, while that of PW@MOF composite PCMs is only zero. In addition, PW@MOF/PDA composite PCMs also exhibit excellent thermal stability, shape stability, energy storage stability, and photothermal conversion stability. More importantly, this coating strategy is universal by integrating different MOFs and solar absorbers, showing the potential to accelerate the major breakthroughs of high-efficiency MOF-based photothermal composite PCMs in solar energy utilization.
- Phase change materials,
- Metal organic frameworks,
- Photothermal conversion,
- Thermal energy storage,
- Photon harvester
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