Citation: Chaochao Wei, Xinrong Liu, Chuang Yu, Shaoqing Chen, Shuai Chen, Shijie Cheng, Jia Xie. Revealing performance of 78Li₂S-22P₂S₅ glass ceramic based solid-state batteries at different operating temperatures[J]. Chinese Chemical Letters, ;2023, 34(7): 107859. doi: 10.1016/j.cclet.2022.107859 shu

Revealing performance of 78Li₂S-22P₂S₅ glass ceramic based solid-state batteries at different operating temperatures

Chaochao Wei ^{a, b, 1} ,
Xinrong Liu ^{a, 1} ,
Chuang Yu ^{a, *,} ,
Shaoqing Chen ^c ,
Shuai Chen ^a ,
Shijie Cheng ^a ,
Jia Xie ^{a, *,}

a.
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
c.
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China

cyu2020@hust.edu.cn

xiejia@hust.edu.cn

Received Date: 30 July 2022
Revised Date: 18 August 2022
Accepted Date: 26 September 2022
Available Online: 1 October 2022

Figures(4)

78Li₂S-22P₂S₅ are sulfide electrolytes with high lithium-ion conductivity and wide electrochemical windows in the Li₂S-P₂S₅ system, making them attractive solid electrolytes for ASSLBs. However, the role and potential of 78Li₂S-22P₂S₅ solid electrolytes over a wide temperature range are still not fully understood. Therefore, we constructed solid-state batteries with NCM622 as the positive electrode and 78Li₂S-22P₂S₅ glass-ceramics as the electrolyte to investigate in depth the differences in battery performance over a wide temperature range and their intrinsic mechanisms. The in-situ impedance and relaxation time distribution (DRT) demonstrated the electrochemical stability of the electrolyte over a wide temperature range, while the in-situ stacking pressure observed a large volume change during cycling at 60 ℃, leading to local solid-solid contact failure and poor cycling stability. This study provides insight into the advantages and problems of 78Li₂S-22P₂S₅ in the wide temperature range as well as a basis for the construction of ASSLBs with high energy density and long cycle life.
- 78Li₂S-22P₂S₅ electrolytes,
- Li-ion conductivity,
- Operating temperature,
- Battery performance,
- Volume changes,
- Interfacial resistance
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Revealing performance of 78Li2S-22P2S5 glass ceramic based solid-state batteries at different operating temperatures

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Revealing performance of 78Li₂S-22P₂S₅ glass ceramic based solid-state batteries at different operating temperatures