Citation: Xiaomei Yan, Jiangbo Xu, Ting Zhang, Chen Si, Jiachen Jiao, Jie Li, Qiuxia Han. Designing polyoxometalate-based metal-organic framework for oxidation of styrene and cycloaddition of CO₂ with epoxides[J]. Chinese Chemical Letters, ;2023, 34(7): 107851. doi: 10.1016/j.cclet.2022.107851 shu

Designing polyoxometalate-based metal-organic framework for oxidation of styrene and cycloaddition of CO₂ with epoxides

Xiaomei Yan ^a ,
Jiangbo Xu ^a ,
Ting Zhang ^a ,
Chen Si ^a ,
Jiachen Jiao ^a ,
Jie Li ^b ,
Qiuxia Han ^{a, *,}

a.
Henan Key Laboratory of Polyoxometalate Chemistry, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
b.
School of Chemistry & Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, China

hdhqx@henu.edu.cn

Received Date: 28 July 2022
Revised Date: 22 August 2022
Accepted Date: 22 September 2022
Available Online: 27 September 2022

Figures(5)

A photoactive polyoxometalate-based metal−organic framework (POMOF), NiW-DPNDI, was synthesized by combination of Ni(Ⅱ) ions, [ZnW₁₂O₄₀]^6‒ anions, and N, N'-bis(4-pyridylmethyl)naphthalene diimide (DPNDI) molecules into one single framework. NiW-DPNDI displays a three-dimensional structure by the strong anion⋯π interactions between the trapped [ZnW₁₂O₄₀]^6‒ anions and the electron-deficient naphthalenic ring centroids and the π−π stacking interactions between DPNDI moieties. NiW-DPNDI displayed a highly efficient hole-electron separation and ordered electron transfer under irradiation, thus ensuing its excellent photocatalysis in oxidation of styrene to produce benzaldehyde. In addition, it gave a high efficiency for styrene oxide under thermocatalytic conditions. Because the carbonic anhydrase (CA)-mimicking Ni sites and the negative electron-enriched [ZnW₁₂O₄₀]^6‒ anions are well aligned in the pores, it can promote the cycloaddition of CO₂ with epoxides under mild conditions.
- Polyoxometalate,
- Metal-organic framework,
- Photocatalysis,
- Oxidation of styrene,
- Cycloaddition
1. [1]
  C.W.M. Murphy, G.B. Davis, J.L. Rayner, et al., J. Hazard. Mater. 430 (2022) 128482. doi: 10.1016/j.jhazmat.2022.128482
2. [2]
  Y. Sun, M.Y. Gao, Y. Sun, et al., Inorg. Chem. 60 (2021) 13955–13959. doi: 10.1021/acs.inorgchem.1c02179
3. [3]
  Q. Lan, S. Jin, B. Yang, et al., Trans. Tianjin Univ. 28 (2022) 214–225. doi: 10.1007/s12209-022-00324-z
4. [4]
  Z. Wu, S. Guo, L.H. Kong, et al., Chin. J. Catal. 42 (2021) 1790–1797. doi: 10.1016/S1872-2067(21)63820-2
5. [5]
  Y. Song, Y. Peng, S. Yao, et al., Chin. Chem. Lett. 33 (2022) 1047–1050. doi: 10.1016/j.cclet.2021.08.045
6. [6]
  J. Liu, H. Wang, R. Ye, P. Jian, L. Wang, J. Colloid Interface Sci. 585 (2021) 61–71. doi: 10.5121/csit.2021.111406
7. [7]
  Y. Zhang, H. Wang, S. Li, et al., Mol. Catal. 515 (2021) 111940. doi: 10.1016/j.mcat.2021.111940
8. [8]
  K.O. Sulaiman, V. Sudheeshkumar, R.W.J. Scott, RSC Adv. 9 (2019) 28019–28027. doi: 10.1039/c9ra05566e
9. [9]
  Y. Jiang, Z. Xiong, J. Huang, et al., Chin. Chem. Lett. 33 (2022) 415–423. doi: 10.1016/j.cclet.2021.06.058
10. [10]
  Y. Nosaka, A.Y. Nosaka, Chem. Rev. 117 (2017) 11302–11336. doi: 10.1021/acs.chemrev.7b00161
11. [11]
  X. Kan, J.C. Wang, Z. Chen, et al., J. Am. Chem. Soc. 144 (2022) 6681–6686. doi: 10.1021/jacs.2c01186
12. [12]
  H. Wang, S. Jiang, W. Shao, et al., J. Am. Chem. Soc. 140 (2018) 3474–3480. doi: 10.1021/jacs.8b00719
13. [13]
  X. Ma, H. Hao, W. Sheng, F. Huang, X. Lang, J. Mater. Chem. A 9 (2021) 2214–2222. doi: 10.1039/d0ta10757c
14. [14]
  M. Huang, W. Xiang, C. Wang, et al., Chin. Chem. Lett. 31 (2020) 2769–2773. doi: 10.1016/j.cclet.2020.06.040
15. [15]
  X. Xiao, M. Lu, J. Nan, et al., Appl. Catal. B 218 (2017) 398–408. doi: 10.1016/j.apcatb.2017.06.074
16. [16]
  H. Li, S. Yao, H.L. Wu, et al., Appl. Catal. B 224 (2018) 46–52. doi: 10.1117/12.2296446
17. [17]
  M.T.C. Martins-Costa, J.M. Anglada, J.S. Francisco, M.F. Ruiz-López, Chem. Sci. 13 (2022) 2624–2631. doi: 10.1039/d1sc06866k
18. [18]
  Q. Wang, Q. Chen, G. Jiang, et al., Chin. Chem. Lett. 30 (2019) 1965–1968. doi: 10.1016/j.cclet.2019.08.037
19. [19]
  Q. Chen, G.S. Luo, Y.J. Wang, Green Chem. 23 (2021) 7074–7083. doi: 10.1039/d1gc01887f
20. [20]
  J. Amaro-Gahete, M.V. Pavliuk, H. Tian, et al., Coord. Chem. Rev. 448 (2021) 214172. doi: 10.1016/j.ccr.2021.214172
21. [21]
  Y. Liu, R. Lv, S. Sun, et al., Chin. Chem. Lett. 33 (2022) 807–811. doi: 10.1016/j.cclet.2021.06.087
22. [22]
  N. Zhang, L. Hong, A. Geng, et al., Chin. Chem. Lett. 29 (2018) 1409–1412. doi: 10.1016/j.cclet.2017.12.003
23. [23]
  Z. Xi, K. Wei, Q. Wang, et al., J. Am. Chem. Soc. 143 (2021) 2660–2664. doi: 10.1021/jacs.0c12605
24. [24]
  M. Tan, M. Takeuchi, A. Takai, Chem. Sci. 13 (2022) 4413–4423. doi: 10.1039/d2sc00035k
25. [25]
  S.K. Keshri, T. Ishizuka, T. Kojima, Y. Matsushita, M. Takeuchi, J. Am. Chem. Soc. 143 (2021) 3238–3244. doi: 10.1021/jacs.0c13389
26. [26]
  Q. Liu, Q. Zhang, W. Shi, et al., Nat. Chem. 14 (2022) 433–440. doi: 10.1038/s41557-022-00889-1
27. [27]
  D. Hu, X. Song, S. Wu, et al., Chin. J. Catal. 42 (2021) 356–366. doi: 10.1016/S1872-2067(20)63665-8
28. [28]
  S. Xing, J. Li, G. Niu, et al., Mol. Catal. 458 (2018) 83–88. doi: 10.1016/j.mcat.2018.08.011
29. [29]
  Y. Dong, Q. Han, Q. Hu, et al., Appl. Catal. B 293 (2021) 120214. doi: 10.1016/j.apcatb.2021.120214
30. [30]
  G. Hu, W. Chang, S. An, B. Qi, Y.F. Song, Chin. Chem. Lett. 33 (2022) 3968–3972. doi: 10.1016/j.cclet.2021.11.006
31. [31]
  L.Q. Wei, B.H. Ye, Inorg. Chem. 58 (2019) 4385–4393. doi: 10.1021/acs.inorgchem.8b03525
32. [32]
  J. Li, J. jiao, J. Chang, M. Li, Q. Han, Inorg. Chem. 60 (2021) 10022–10029. doi: 10.1021/acs.inorgchem.1c01311
33. [33]
  J. Liang, R.P. Chen, X.Y. Wang, et al., Chem. Sci. 8 (2017) 1570–1575. doi: 10.1039/C6SC04357G
34. [34]
  R. López, R. Gómez, J. Sol-Gel Sci. Technol. 61 (2012) 1–7. doi: 10.1007/s10971-011-2582-9
35. [35]
  X.H. Li, M. Antonietti, Chem. Soc. Rev. 42 (2013) 6593. doi: 10.1039/c3cs60067j
36. [36]
  J. Duan, L. Chen, H. Ji, et al., Chin. Chem. Lett. 33 (2022) 3172–3176. doi: 10.1016/j.cclet.2021.11.072
37. [37]
  J. Wang, Z. Wu, H. Shen, G. Wang, Polym. Chem. 8 (2017) 7044–7053. doi: 10.1039/C7PY01683B
1. [1]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
2. [2]
  Chunhui Zhang , Jie Wang , Jieyang Zhan , Runmin Yang , Guanggang Gao , Jiayuan Zhang , Linlin Fan , Mengqi Wang , Hong Liu . Highly sensitive hydrazine detection through a novel Raman scattering quenching mechanism enabled by a crystalline and noble metal–free polyoxometalate substrate. Chinese Chemical Letters, 2025, 36(3): 109719-. doi: 10.1016/j.cclet.2024.109719
3. [3]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
4. [4]
  Jiaqi Ma , Lan Li , Yiming Zhang , Jinjie Qian , Xusheng Wang . Covalent organic frameworks: Synthesis, structures, characterizations and progress of photocatalytic reduction of CO2. Chinese Journal of Structural Chemistry, 2024, 43(12): 100466-100466. doi: 10.1016/j.cjsc.2024.100466
5. [5]
  Xiaohui Fu , Yanping Zhang , Juan Liao , Zhen-Hua Wang , Yong You , Jian-Qiang Zhao , Mingqiang Zhou , Wei-Cheng Yuan . Palladium-catalyzed enantioselective decarboxylation of vinyl cyclic carbamates: Generation of amide-based aza-1,3-dipoles and application to asymmetric 1,3-dipolar cycloaddition. Chinese Chemical Letters, 2024, 35(12): 109688-. doi: 10.1016/j.cclet.2024.109688
6. [6]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
7. [7]
  Jia-Cheng Hou , Wei Cai , Hong-Tao Ji , Li-Juan Ou , Wei-Min He . Recent advances in semi-heterogenous photocatalysis in organic synthesis. Chinese Chemical Letters, 2025, 36(2): 110469-. doi: 10.1016/j.cclet.2024.110469
8. [8]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
9. [9]
  Bowen Li , Ting Wang , Ming Xu , Yuqi Wang , Zhaoxing Li , Mei Liu , Wenjing Zhang , Ming Feng . Structuring MoO₃-polyoxometalate hybrid superstructures to boost electrocatalytic hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(2): 110467-. doi: 10.1016/j.cclet.2024.110467
10. [10]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
11. [11]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
12. [12]
  Ning Zhang , Mengjie Qin , Jiawen Zhu , Xuejing Lou , Xiao Tian , Wende Ma , Youmei Wang , Minghua Lu , Zongwei Cai . Thickness-controllable synthesis of metal-organic framework based hollow nanoflowers with magnetic core via liquid phase epitaxy for phosphopeptides enrichment. Chinese Chemical Letters, 2025, 36(4): 110177-. doi: 10.1016/j.cclet.2024.110177
13. [13]
  Rongxin Zhu , Shengsheng Yu , Xuanzong Yang , Ruyu Zhu , Hui Liu , Kaikai Niu , Lingbao Xing . Construction of pyrene-based hydrogen-bonded organic frameworks as photocatalysts for photooxidation of styrene in water. Chinese Chemical Letters, 2024, 35(10): 109539-. doi: 10.1016/j.cclet.2024.109539
14. [14]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
15. [15]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
16. [16]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
17. [17]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
18. [18]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
19. [19]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
20. [20]
  Jiangqi Ning , Junhan Huang , Yuhang Liu , Yanlei Chen , Qing Niu , Qingqing Lin , Yajun He , Zheyuan Liu , Yan Yu , Liuyi Li . Alkyl-linked TiO2@COF heterostructure facilitating photocatalytic CO2 reduction by targeted electron transport. Chinese Journal of Structural Chemistry, 2024, 43(12): 100453-100453. doi: 10.1016/j.cjsc.2024.100453

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1049)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Designing polyoxometalate-based metal-organic framework for oxidation of styrene and cycloaddition of CO2 with epoxides

Metrics

通讯作者: 陈斌, bchen63@163.com

Designing polyoxometalate-based metal-organic framework for oxidation of styrene and cycloaddition of CO₂ with epoxides