Citation: Su-Xian Yuan, Ke Su, You-Xiang Feng, Min Zhang, Tong-Bu Lu. Lattice-matched in-situ construction of 2D/2D T-SrTiO₃/CsPbBr₃ heterostructure for efficient photocatalysis of CO₂ reduction[J]. Chinese Chemical Letters, ;2023, 34(4): 107682. doi: 10.1016/j.cclet.2022.07.025 shu

Lattice-matched in-situ construction of 2D/2D T-SrTiO₃/CsPbBr₃ heterostructure for efficient photocatalysis of CO₂ reduction

MOE International Joint Laboratory of Materials Microstructure, Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

zm2016@email.tjut.edu.cn

Received Date: 20 April 2022
Revised Date: 23 June 2022
Accepted Date: 14 July 2022
Available Online: 16 July 2022

Figures(4)

The elaborate regulation of heterostructure interface to accelerate the interfacial charge separation is one of practicable approaches to improve the photocatalytic CO₂ reduction performance of halide perovskite (HP) materials. Herein, we report an in-situ growth strategy for the construction of 2D CsPbBr₃ based heterostructure with perovskite oxide (SrTiO₃) nanosheet as substrate (CsPbBr₃/SrTiO₃). Lattice matching and matchable energy band structures between CsPbBr₃ and SrTiO₃ endow CsPbBr₃/SrTiO₃ heterostructure with an efficient interfacial charge separation. Moreover, the interfacial charge transfer rate can be further accelerated by etching SrTiO₃ with NH₄F to form flat surface capped with Ti−O bonds. The resultant 2D/2D T-SrTiO₃/CsPbBr₃ heterostructure exhibits an impressive photocatalytic activity for CO₂ conversion with a CO yield of 120.2 ± 4.9 µmol g⁻¹ h⁻¹ at the light intensity of 100 mW/cm² and water as electron source, which is about 10 and 7 times higher than those of the pristine SrTiO₃ and CsPbBr₃ nanosheets, surpassing the reported halide perovskite-based photocatalysts under the same conditions.
- Charge transfer,
- CO₂ reduction,
- Heterostructure,
- Perovskite,
- Photocatalysis
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Lattice-matched in-situ construction of 2D/2D T-SrTiO3/CsPbBr3 heterostructure for efficient photocatalysis of CO2 reduction

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通讯作者: 陈斌, bchen63@163.com

Lattice-matched in-situ construction of 2D/2D T-SrTiO₃/CsPbBr₃ heterostructure for efficient photocatalysis of CO₂ reduction