Citation: Jiajing Wang, Xiaotian Guo, Qingling Jing, Wenting Li, Tingting Chen, Rongmei Zhu, Huan Pang. Rational design of self-sacrificial template derived quasi-Cu-MOF composite as anodes for high-performance lithium-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(6): 107675. doi: 10.1016/j.cclet.2022.07.018 shu

Rational design of self-sacrificial template derived quasi-Cu-MOF composite as anodes for high-performance lithium-ion batteries

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225000, China

panghuan@yzu.edu.cn

Received Date: 22 May 2022
Revised Date: 2 July 2022
Accepted Date: 12 July 2022
Available Online: 19 July 2022

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MOF-based composites have aroused widespread concern due to their controllable morphology and pore characteristics. Nevertheless, the poor conductivity and volume expansion hinder its practical application in LIBs. Herein a classical structure HKUST-1, as the precursor, was used to fabricate quasi-Cu-MOF composite through a facile thermal decomposition strategy. The results showed that quasi-Cu-MOF composite had superior reversible specific capacity (627.5 mAh/g at 100 mA/g) and outstanding cycle stability (514.6 mAh/g at 500 mA/g after 400 cycles) as anodes for LIBs. The results demonstrated that the low-temperature calcination strategy played a significant role in morphology retaining during cycling and the derived copper framework play a crucial part in conductivity improvement. This work is helpful to the design of high-performance electrodes with advanced three-dimensional hierarchical structures.
- Quasi-MOF,
- Conductivity,
- Porous structure,
- Anode,
- Lithium-ion batteries
1. [1]
  Y.S. Wei, M. Zhang, R. Zou, Q. Xu, Chem. Rev. 120 (2020) 12089-12174. doi: 10.1021/acs.chemrev.9b00757
2. [2]
  X. Han, S. Wang, Y. Xu, et al., Energy Environ. Sci. 14 (2021) 5044-5056. doi: 10.1039/d1ee01494c
3. [3]
  L. Wang, T. Liu, T. Wu, J. Lu, Exploration 1 (2021) 20210130. doi: 10.1002/EXP.20210130
4. [4]
  S. Chuhadiya, Himanshu, D. Suthar, S.L. Patel, M.S. Dhaka, Coord. Chem. Rev. 446 (2021) 214115. doi: 10.1016/j.ccr.2021.214115
5. [5]
  M. Liu, N. Li, S. Cao, et al., Adv. Mater. 34 (2022) 2107421. doi: 10.1002/adma.202107421
6. [6]
  Y. Gong, B. Shao, J. Mei, et al., Nano Res. 15 (2022) 551-556. doi: 10.1007/s12274-021-3519-4
7. [7]
  G. Cai, P. Yan, L. Zhang, H.C. Zhou, H.L. Jiang, Chem. Rev. 121 (2021) 12278-12326. doi: 10.1021/acs.chemrev.1c00243
8. [8]
  W. Dai, C. Kouvatas, W. Tai, et al., J. Am. Chem. Soc. 143 (2021) 1993-2004. doi: 10.1021/jacs.0c11784
9. [9]
  M.D. Allendorf, V. Stavila, M. Witman, C.K. Brozek, C.H. Hendon, J. Am. Chem. Soc. 143 (2021) 6705-6723. doi: 10.1021/jacs.0c10777
10. [10]
  Y. Chu, S. Xiong, Chin. Chem. Lett. 33 (2022) 486-490. doi: 10.1016/j.cclet.2021.06.074
11. [11]
  M. Xu, D. Li, K. Sun, et al., Angew. Chem. Int. Ed. 60 (2021) 16372-16376. doi: 10.1002/anie.202104219
12. [12]
  Y. Bai, C. Liu, T. Chen, et al., Angew. Chem. Int. Ed. 60 (2021) 25318-25322. doi: 10.1002/anie.202112381
13. [13]
  Q. Zhao, X. Chen, W. Hou, et al., SusMat 2 (2022) 104-112. doi: 10.1002/sus2.43
14. [14]
  H. Yang, W. Cui, Y. Han, B. Wang, Chin. Chem. Lett. 29 (2018) 842-844. doi: 10.1016/j.cclet.2017.09.024
15. [15]
  Y. Wang, H. Jin, Q. Ma, et al., Angew. Chem. Int. Ed. 59 (2020) 4365-4369. doi: 10.1002/anie.201915807
16. [16]
  J. Zhai, Q. Kang, Q. Liu, et al., J. Colloid Interface Sci. 608 (2022) 1942-1950. doi: 10.1016/j.jcis.2021.10.096
17. [17]
  M. Bagheri, A. Melillo, B. Ferrer, M.Y. Masoomi, H. Garcia, ACS Appl. Mater. Interfaces 14 (2022) 978-989. doi: 10.1021/acsami.1c19862
18. [18]
  Y.Y. Hu, R.X. Han, L. Mei, et al., Mater. Today Energy 19 (2021) 100608. doi: 10.1016/j.mtener.2020.100608
19. [19]
  M. Bagheri, M.Y. Masoomi, E. Domínguez, H. García, ACS Sustain. Chem. Eng. 9 (2021) 10611-10619. doi: 10.1021/acssuschemeng.1c02851
20. [20]
  J. Zhang, Y. Wang, H. Wang, D. Zhong, T. Lu, Chin. Chem. Lett. 33 (2022) 2065-2068. doi: 10.1016/j.cclet.2021.09.035
21. [21]
  N. Tsumori, L. Chen, Q. Wang, et al., Chem 4 (2018) 845-856. doi: 10.1016/j.chempr.2018.03.009
22. [22]
  M. Bagheri, A. Melillo, B. Ferrer, M.Y. Masoomi, H. Garcia, Chemistry 27 (2021) 14273-14281. doi: 10.1002/chem.202102405
23. [23]
  M. Bagheri, M.Y. Masoomi, A. Forneli, H. García, J. Phys. Chem. C 126 (2021) 683-692.
24. [24]
  Y. Wu, Y. Li, J. Gao, Q. Zhang, SusMat 1 (2021) 66-87. doi: 10.1002/sus2.3
25. [25]
  W.G. Cui, Y.T. Li, H. Zhang, et al., Appl. Catal. B 278 (2020) 119262. doi: 10.1016/j.apcatb.2020.119262
26. [26]
  L. Ai, N. Li, M. Chen, H. Jiang, J. Jiang, J. Mater. Chem. A 9 (2021) 16479-16488. doi: 10.1039/d1ta02995a
27. [27]
  Y. Shen, L. Bao, F. Sun, T. Hu, Mater. Chem. Front. 3 (2019) 2363-2373. doi: 10.1039/c9qm00277d
28. [28]
  L. Fan, F. Zhao, Z. Huang, et al., Appl. Catal. A 572 (2019) 34-43. doi: 10.1016/j.apcata.2018.12.021
29. [29]
  T. Wang, H. Zhu, Q. Zeng, D. Liu, Adv. Mater. Interfaces 6 (2019) 1900423. doi: 10.1002/admi.201900423
30. [30]
  K. Wang, C. Wu, F. Wang, N. Jing, G. Jiang, ACS Sustain. Chem. Eng. 7 (2019) 18582-18592. doi: 10.1021/acssuschemeng.9b04813
31. [31]
  H. Xia, N. Li, W. Huang, Y. Song, Y. Jiang, ACS Appl. Mater. Interfaces 13 (2021) 22240-22253. doi: 10.1021/acsami.1c04680
32. [32]
  C. Arul, K. Moulaee, N. Donato, et al., Sens. Actuator B 329 (2021) 129053. doi: 10.1016/j.snb.2020.129053
33. [33]
  G. Zheng, Z. Xing, X. Gao, et al., Appl. Surf. Sci. 559 (2021) 149701. doi: 10.1016/j.apsusc.2021.149701
34. [34]
  L. Zhu, Z. Yao, T. Liu, et al., Chem. Commun. 56 (2020) 5847-5850. doi: 10.1039/D0CC01599G
35. [35]
  W. Liu, Z. Zhang, Y. Zhang, et al., Nano Micro Lett. 13 (2021) 61. doi: 10.1007/s40820-021-00590-x
36. [36]
  L. Zhu, Z. Yao, T. Liu, et al., Chem. Commun. 56 (2020) 5847-5850. doi: 10.1039/D0CC01599G
37. [37]
  X. Cai, Z. Xie, M. Pang, J. Lin, Cryst. Growth Des. 19 (2019) 556-561. doi: 10.1021/acs.cgd.8b01695
38. [38]
  S. Shang, Z. Tao, C. Yang, et al., Chem. Eng. J. 393 (2020) 124666. doi: 10.1016/j.cej.2020.124666
39. [39]
  D.H. Nam, O.S. Bushuyev, J. Li, et al., J. Am. Chem. Soc. 140 (2018) 11378-11386. doi: 10.1021/jacs.8b06407
40. [40]
  H. Qing, R. Wang, Z. Chen, et al., J. Colloid Interface Sci. 566 (2020) 1-10. doi: 10.1016/j.jcis.2020.01.068
41. [41]
  A. Rendón-Calle, Q.H. Low, S.H.L. Hong, et al., Appl. Catal. B 285 (2021) 119776. doi: 10.1016/j.apcatb.2020.119776
42. [42]
  Z. Li, D. Wang, W. Wei, et al., Solid State Sci. 108 (2020) 106375. doi: 10.1016/j.solidstatesciences.2020.106375
43. [43]
  R. Yun, B. Zhang, F. Zhan, et al., Inorg. Chem. 60 (2021) 12906-12911. doi: 10.1021/acs.inorgchem.1c01284
44. [44]
  J. Yan, H. Wang, B. Jin, M. Zeng, R. Peng, J. Solid State Chem. 297 (2021) 122060. doi: 10.1016/j.jssc.2021.122060
45. [45]
  R. Wei, Y. Dong, Y. Zhang, et al., J. Colloid Interface Sci. 582 (2021) 236-245. doi: 10.1016/j.jcis.2020.08.044
46. [46]
  P. Hu, A. Yuan, C. Meng, H. Chen, H. Zhou, ChemElectroChem 7 (2020) 4003-4009. doi: 10.1002/celc.202001017
47. [47]
  J. Yan, Y. Cui, M. Xie, et al., Angew. Chem. Int. Ed. 60 (2021) 24467-24472. doi: 10.1002/anie.202110373
48. [48]
  X. Lou, X. Hu, S. Xiang, et al., New J. Chem. 44 (2020) 17899-17905. doi: 10.1039/d0nj04061d
49. [49]
  S. Maiti, A. Pramanik, U. Manju, S. Mahanty, Microporous Mesoporous Mater. 226 (2016) 353-359. doi: 10.1016/j.micromeso.2016.02.011
50. [50]
  Q. Gan, H. He, K. Zhao, Z. He, S. Liu, J. Colloid Interface Sci. 530 (2018) 127-136. doi: 10.1016/j.jcis.2018.06.057
51. [51]
  T. Gong, X. Lou, E.Q. Gao, B. Hu, ACS Appl. Mater. Interfaces 9 (2017) 21839-21847. doi: 10.1021/acsami.7b05889
52. [52]
  J. Qiu, M. Yu, Z. Zhang, X. Cai, G. Guo, J. Alloys Compd. 775 (2019) 366-371. doi: 10.1016/j.jallcom.2018.10.129
53. [53]
  Y.G. Weng, Z.H. Ren, Z.R. Zhang, et al., Inorg. Chem. 60 (2021) 17074-17082. doi: 10.1021/acs.inorgchem.1c02304
54. [54]
  D. Ge, J. Peng, G. Qu, et al., New J. Chem. 40 (2016) 9238-9244. doi: 10.1039/C6NJ02568D
55. [55]
  X. Zhang, H. Liu, L. Jiang, Adv. Mater. 31 (2019) e1804508. doi: 10.1002/adma.201804508
56. [56]
  Q. Zhang, Q. Gao, W. Qian, et al., Mater. Today Energy 13 (2019) 93-99. doi: 10.1016/j.mtener.2019.05.006
57. [57]
  L. Du, Q. Wu, L. Yang, et al., Nano Energy 57 (2019) 34-40. doi: 10.1016/j.nanoen.2018.12.019
58. [58]
  Q. Cheng, S. Han, K. Mao, et al., Nano Energy 52 (2018) 485-493. doi: 10.1016/j.nanoen.2018.08.005
59. [59]
  S. Wu, G. Fu, W. Lv, et al., Small 14 (2018) 1702667. doi: 10.1002/smll.201702667
60. [60]
  L. Jiao, J. Zhu, Y. Zhang, et al., J. Am. Chem. Soc. 143 (2021) 19417-19424. doi: 10.1021/jacs.1c08050
61. [61]
  L. Fan, X. Guo, W. Li, X. Hang, H. Pang, Chin. Chem. Lett. 34 (2023) 107447. doi: 10.1016/j.cclet.2022.04.045
62. [62]
  K. Amin, J. Zhang, H. Zhou, et al., Sustain. Energy Fuels 4 (2020) 4179-4185. doi: 10.1039/d0se00610f
63. [63]
  W. Zhao, L. Gao, L. Yue, et al., J. Mater. Chem. A 9 (2021) 6402-6412. doi: 10.1039/d1ta00497b
64. [64]
  H. Li, T. Wei, S. Huang, et al., New J. Chem. 45 (2021) 12168-12177. doi: 10.1039/d1nj01385h
65. [65]
  J. Kim, W. Jang, J.H. Kim, C. Yang, Compos. B. Eng. 222 (2021) 109083. doi: 10.1016/j.compositesb.2021.109083
66. [66]
  N. Li, Y. Liu, X. Ji, et al., Chin. Chem. Lett. 32 (2021) 3787-3792. doi: 10.1016/j.cclet.2021.04.029
67. [67]
  X. Jiao, Y. Liu, T. Li, et al., ACS Appl. Mater. Interfaces 11 (2019) 30858-30864. doi: 10.1021/acsami.9b08915
68. [68]
  Q. Feng, T. Li, Y. Miao, et al., J. Colloid Interface Sci. 608 (2022) 227-238. doi: 10.1016/j.jcis.2021.09.147
69. [69]
  X. Shi, J. Yu, Q. Liu, et al., Sustain. Mater. Technol. 28 (2021) e00275.
70. [70]
  W. Xu, W. Li, H. Wen, et al., Appl. Catal. B 286 (2021) 119946. doi: 10.1016/j.apcatb.2021.119946
71. [71]
  X. Li, H. Liu, X. Jia, et al., Sci. Total Environ. 621 (2018) 1533-1541. doi: 10.1016/j.scitotenv.2017.10.075
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