Citation: Zhen Wang, Jun-Yu Li, Tao Huang, Huai-Ming Li, Teng Zhang. A Cu-based metal-organic framework with two types of connecting nodes as catalyst for oxygen activation[J]. Chinese Chemical Letters, ;2023, 34(6): 107635. doi: 10.1016/j.cclet.2022.06.058 shu

A Cu-based metal-organic framework with two types of connecting nodes as catalyst for oxygen activation

Zhen Wang ^{a, b} ,
Jun-Yu Li ^{a, b} ,
Tao Huang ^a ,
Huai-Ming Li ^a ,
Teng Zhang ^{a, b, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

zhangteng@fjirsm.ac.cn

Received Date: 19 April 2022
Revised Date: 15 June 2022
Accepted Date: 21 June 2022
Available Online: 25 June 2022

Figures(2)

Using a ditopic organic linker 4-(1H-pyrazol-4-yl)benzoic acid (H₂pba), FICN-6, a metal-organic framework containing both Cu₂(O₂CR)₄ and Cu₃(OH)(pyz)₃(O₂CR) secondary building units (SBUs), was synthesized. FICN-6 adopts in an unusual intercatenated structure with SBUs from two distinct networks connecting to each other. Presence of Cu₃ clusters makes FICN-6 a good heterogeneous catalyst for oxygen activation and aerobic oxidative C-C coupling of organic boronic acids.
- Copper,
- Metal-organic framework,
- Oxidative C-C coupling,
- Oxygen activation,
- Boronic acids
1. [1]
  D.E. Torres Pazmino, M. Winkler, A. Glieder, M.W. Fraaije, J. Biotechnol. 146 (2010) 9-24. doi: 10.1016/j.jbiotec.2010.01.021
2. [2]
  X. Huang, J.T. Groves, Chem. Rev. 118 (2018) 2491-2553. doi: 10.1021/acs.chemrev.7b00373
3. [3]
  A.J. Jasniewski, , Chem. Rev. 118 (2018) 2554-2592. doi: 10.1021/acs.chemrev.7b00457
4. [4]
  M. Guo, T. Corona, K. Ray, W. Nam, ACS Cent. Sci. 5 (2019) 13-28. doi: 10.1021/acscentsci.8b00698
5. [5]
  M. Huang, W. Xiang, C. Wang, et al., Chin. Chem. Lett. 31 (2020) 2769-2773. doi: 10.1016/j.cclet.2020.06.040
6. [6]
  W.J. van Berkel, N.M. Kamerbeek, M.W. Fraaije, J. Biotechnol. 124 (2006) 670-689. doi: 10.1016/j.jbiotec.2006.03.044
7. [7]
  E.I. Solomon, D.E. Heppner, E.M. Johnston, et al., Chem. Rev. 114 (2014) 3659-3853. doi: 10.1021/cr400327t
8. [8]
  P.V. Iyer, L. Ananthanarayan, Process Biochem. 43 (2008) 1019-1032. doi: 10.1016/j.procbio.2008.06.004
9. [9]
  Y. Lin, J. Ren, X. Qu, Acc. Chem. Res. 47 (2014) 1097-1105. doi: 10.1021/ar400250z
10. [10]
  J. Wu, X. Wang, Q. Wang, et al., Chem. Soc. Rev. 48 (2019) 1004-1076. doi: 10.1039/c8cs00457a
11. [11]
  H. Wei, E. Wang, Chem. Soc. Rev. 42 (2013) 6060-6093. doi: 10.1039/c3cs35486e
12. [12]
  F. Schwizer, Y. Okamoto, T. Heinisch, et al., Chem. Rev. 118 (2018) 142-231. doi: 10.1021/acs.chemrev.7b00014
13. [13]
  M. Liang, X. Yan, Acc. Chem. Res. 52 (2019) 2190-2200. doi: 10.1021/acs.accounts.9b00140
14. [14]
  W. Yang, X. Yang, L. Zhu, et al., Coord. Chem. Rev. 448 (2021) 214170. doi: 10.1016/j.ccr.2021.214170
15. [15]
  H. Wang, K. Wan, X. Shi, Adv. Mater. 31 (2019) e1805368. doi: 10.1002/adma.201805368
16. [16]
  O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, et al., Nature 423 (2003) 705-714. doi: 10.1038/nature01650
17. [17]
  H.C. Zhou, J.R. Long, O.M. Yaghi, Chem. Rev. 112 (2012) 673-674. doi: 10.1021/cr300014x
18. [18]
  R.J. Wei, H.G. Zhou, Z.Y. Zhang, et al., CCS Chem. 3 (2021) 2045-2053. doi: 10.31635/ccschem.020.202000401
19. [19]
  T.C. Zhuo, Y. Song, G.L. Zhuang, et al., J. Am. Chem. Soc. 143 (2021) 6114-6122. doi: 10.1021/jacs.0c13048
20. [20]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi, Science 341 (2013) 1230444. doi: 10.1126/science.1230444
21. [21]
  W.Y. Gao, R. Cai, T. Pham, et al., Chem. Mater. 27 (2015) 2144-2151. doi: 10.1021/acs.chemmater.5b00084
22. [22]
  X.J. Hu, Z.X. Li, H. Xue, et al., CCS Chem. 2 (2020) 616-622. doi: 10.31635/ccschem.019.201900040
23. [23]
  X. Niu, X. Li, Z. Lyu, et al., Chem. Commun. 56 (2020) 11338-11353. doi: 10.1039/d0cc04890a
24. [24]
  D. Wang, D. Jana, Y. Zhao, Acc. Chem. Res. 53 (2020) 1389-1400. doi: 10.1021/acs.accounts.0c00268
25. [25]
  I. Nath, J. Chakraborty, F. Verpoort, Chem. Soc. Rev. 45 (2016) 4127-4170. doi: 10.1039/C6CS00047A
26. [26]
  J. Baek, B. Rungtaweevoranit, X. Pei, et al., J. Am. Chem. Soc. 140 (2018) 18208-18216. doi: 10.1021/jacs.8b11525
27. [27]
  M. Li, J. Chen, W. Wu, et al., J. Am. Chem. Soc. 142 (2020) 15569-15574. doi: 10.1021/jacs.0c07273
28. [28]
  X. Feng, Y. Song, J.S. Chen, et al., J. Am. Chem. Soc. 143 (2021) 1107-1118. doi: 10.1021/jacs.0c11920
29. [29]
  Y. Tu, H. Li, T. Tu, Q. Zhang, CCS Chem. 4 (2022) 872-879. doi: 10.31635/ccschem.021.202000759
30. [30]
  D. Feng, Z.Y. Gu, J.R. Li, et al., Angew. Chem. Int. Ed. 51 (2012) 10307-10310. doi: 10.1002/anie.201204475
31. [31]
  Y. Matoba, T. Kumagai, A. Yamamoto, et al., J. Biol. Chem. 281 (2006) 8981-8990. doi: 10.1074/jbc.M509785200
32. [32]
  C.A. Ramsden, P.A. Riley, Bioorg. Med. Chem. 22 (2014) 2388-2395. doi: 10.1016/j.bmc.2014.02.048
33. [33]
  S. Kulandaivel, C.H. Lin, Y.C. Yeh, Chem. Commun. 58 (2022) 569-572. doi: 10.1039/d1cc05908d
34. [34]
  C. Serre, F. Millange, C. Thouvenot, et al., J. Am. Chem. Soc. 124 (2002) 13519-13526. doi: 10.1021/ja0276974
35. [35]
  G. Ferey, C. Serre, Chem. Soc. Rev. 38 (2009) 1380-1399. doi: 10.1039/b804302g
36. [36]
  O. Baudoin, M. Cesario, D. Guenard, F. Gueritte, J. Org. Chem. 67 (2002) 1199-1207. doi: 10.1021/jo0160726
37. [37]
  G.P. McGlacken, L.M. Bateman, Chem. Soc. Rev. 38 (2009) 2447-2464. doi: 10.1039/b805701j
38. [38]
  F.S. Han, Chem. Soc. Rev. 42 (2013) 5270-5298. doi: 10.1039/c3cs35521g
39. [39]
  S. Fu, S. Yao, S. Guo, et al., J. Am. Chem. Soc. 143 (2021) 20792-20801. doi: 10.1021/jacs.1c08908
40. [40]
  J. Hassan, M. Sevignon, C. Gozzi, et al., Chem. Rev. 102 (2002) 1359-1470. doi: 10.1021/cr000664r
41. [41]
  E. Sperotto, G.P. van Klink, G. van Koten, J.G. de Vries, Dalton Trans. 39 (2010) 10338-10351. doi: 10.1039/c0dt00674b
42. [42]
  J.P. Corbet, G. Mignani, Chem. Rev. 106 (2006) 2651-2710. doi: 10.1021/cr0505268
43. [43]
  O. Vechorkin, V. Proust, X. Hu, J. Am. Chem. Soc. 131 (2009) 9756-9766. doi: 10.1021/ja9027378
44. [44]
  C. Adamo, C. Amatore, I. Ciofini, et al., J. Am. Chem. Soc. 128 (2006) 6829-6836. doi: 10.1021/ja0569959
45. [45]
  L. Zhou, Q.X. Xu, H.F. Jiang, Chin. Chem. Lett. 18 (2007) 1043-1046. doi: 10.1016/j.cclet.2007.06.023
46. [46]
  X. Xu, S. Gao, W. Chen, et al., ChemistrySelect 3 (2018) 8863-8866. doi: 10.1002/slct.201801714
47. [47]
  C. Gonzalez-Arellano, A. Corma, M. Iglesias, F. Sanchez, Chem. Commun. (2005) 1990-1992.
48. [48]
  P.N. Eyimegwu, J.A. Lartey, J.H. Kim, ACS Appl. Nano Mater. 2 (2019) 6057-6066. doi: 10.1021/acsanm.9b01594
49. [49]
  T. Vogler, A. Studer, Adv. Syn. Catal. 350 (2008) 1963-1967. doi: 10.1002/adsc.200800300
50. [50]
  D. Tyagi, C. Binnani, R.K. Rai, et al., Inorg. Chem. 55 (2016) 6332-6343. doi: 10.1021/acs.inorgchem.6b01115
51. [51]
  A.S. Demir, O. Reis, M. Emrullahoglu, J. Org. Chem. 68 (2003) 10130-10134. doi: 10.1021/jo034680a
52. [52]
  G. Cheng, M. Luo, Eur. J. Org. Chem. (2011) 2519-2523. doi: 10.1002/ejoc.201001729
53. [53]
  B. Kaboudin, Y. Abedi, T. Yokomatsu, Eur. J. Org. Chem. (2011) 6656-6662. doi: 10.1002/ejoc.201100994
54. [54]
  Q. Liu, Y. Song, Y. Ma, et al., J. Am. Chem. Soc. 141 (2019) 488-496. doi: 10.1021/jacs.8b11230
1. [1]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
2. [2]
  Wen-Jing Li , Jun-Bo Wang , Yu-Heng Liu , Mo Zhang , Zhan-Hui Zhang . Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids. Chinese Chemical Letters, 2025, 36(3): 110001-. doi: 10.1016/j.cclet.2024.110001
3. [3]
  Shengtao Jiang , Mengjiao Xie , Limin Jin , Yifan Ren , Wentian Zheng , Siping Ji , Yanbiao Liu . New insights into electrocatalytic singlet oxygen generation for effective and selective water decontamination. Chinese Chemical Letters, 2025, 36(5): 110293-. doi: 10.1016/j.cclet.2024.110293
4. [4]
  Liangfeng Yang , Liang Zeng , Yanping Zhu , Qiuan Wang , Jinheng Li . Copper-catalyzed photoredox 1,4-amidocyanation of 1,3-enynes with N-amidopyridin-1-ium salts and TMSCN: Facile access to α-amido allenyl nitriles. Chinese Chemical Letters, 2024, 35(11): 109685-. doi: 10.1016/j.cclet.2024.109685
5. [5]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
6. [6]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
7. [7]
  Ning Zhang , Mengjie Qin , Jiawen Zhu , Xuejing Lou , Xiao Tian , Wende Ma , Youmei Wang , Minghua Lu , Zongwei Cai . Thickness-controllable synthesis of metal-organic framework based hollow nanoflowers with magnetic core via liquid phase epitaxy for phosphopeptides enrichment. Chinese Chemical Letters, 2025, 36(4): 110177-. doi: 10.1016/j.cclet.2024.110177
8. [8]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
9. [9]
  Jiayu Xu , Meng Li , Baoxia Dong , Ligang Feng . Fully fluorinated hybrid zeolite imidazole/Prussian blue analogs with combined advantages for efficient oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(6): 108798-. doi: 10.1016/j.cclet.2023.108798
10. [10]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
11. [11]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
12. [12]
  Gangsheng Li , Xiang Yuan , Fu Liu , Zhihua Liu , Xujie Wang , Yuanyuan Liu , Yanmin Chen , Tingting Wang , Yanan Yang , Peicheng Zhang . Three-step synthesis of flavanostilbenes with a 2-cyclohepten-1-one core by Cu-mediated [5 + 2] cycloaddition/decarboxylation cascade. Chinese Chemical Letters, 2025, 36(2): 109880-. doi: 10.1016/j.cclet.2024.109880
13. [13]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
14. [14]
  Ying Gao , Rong Zhou , Qiwen Wang , Shaolong Qi , Yuanyuan Lv , Shuang Liu , Jie Shen , Guocan Yu . Natural killer cell membrane doped supramolecular nanoplatform with immuno-modulatory functions for immuno-enhanced tumor phototherapy. Chinese Chemical Letters, 2024, 35(10): 109521-. doi: 10.1016/j.cclet.2024.109521
15. [15]
  Lei Zhu , Hai-Ruo Li , Yi-Ning Mao , Ruiying Liu , Bo Zhang , Jing Chen , Wengui Xu , Libo Zhang , Cheng-Peng Li . A four-fold interpenetrated MOF for efficient perrhenate/pertechnetate removal from alkaline nuclear effluents. Chinese Chemical Letters, 2024, 35(12): 109921-. doi: 10.1016/j.cclet.2024.109921
16. [16]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
17. [17]
  Zhefei Hu , Jingwen Liao , Jiawen Zhou , Lulu Zhao , Yanjuan Liu , Yuefei Zhang , Wei Chen , Sheng Tang . A new green approach to synthesizing MIP-202@porous silica microspheres for positional isomer/enantiomer/hydrophilic separation. Chinese Chemical Letters, 2025, 36(1): 109985-. doi: 10.1016/j.cclet.2024.109985
18. [18]
  Yao-Yu Ma , Wen-Juan Shi , Gang-Ding Wang , Xin Liu , Lei Hou , Yao-Yu Wang . Enhancing ethane/ethylene separation performance through the amino-functionalization of ethane-selective MOF. Chinese Chemical Letters, 2025, 36(3): 109729-. doi: 10.1016/j.cclet.2024.109729
19. [19]
  Quanquan Li , Chenzhu Zhao , Shanshan Jia , Qiang Chen , Xusheng Li , Mengyao She , Hua Liu , Ping Liu , Yaoyu Wang , Jianli Li . Design and fabrication of Cu^I/Cu^II-MOF-incorporated hydrogel photocatalysts for synergy removal of Cr(VI) and congo red. Chinese Chemical Letters, 2025, 36(5): 109936-. doi: 10.1016/j.cclet.2024.109936
20. [20]
  Hua Liu , Jian Zhao , Qi Li , Xiang-Yu Zhang , Zhi-Wei Zheng , Kun Huang , Da-Bin Qin , Bin Zhao . Indium-captured zirconium-porphyrin frameworks displaying rare multi-selectivity for catalytic transfer hydrogenation of aldehydes and ketones. Chinese Chemical Letters, 2025, 36(6): 110593-. doi: 10.1016/j.cclet.2024.110593

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(524)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142