Citation: Shunlong Pan, Xi Nie, Xinrui Guo, Hao Hu, Biming Liu, Yongjun Zhang. Enhanced removal of phosphonates from aqueous solution using PMS/UV/hydrated zirconium oxide process[J]. Chinese Chemical Letters, ;2023, 34(4): 107620. doi: 10.1016/j.cclet.2022.06.043 shu

Enhanced removal of phosphonates from aqueous solution using PMS/UV/hydrated zirconium oxide process

Shunlong Pan ^{a, b} ,
Xi Nie ^a ,
Xinrui Guo ^a ,
Hao Hu ^a ,
Biming Liu ^{c, *,} ,
Yongjun Zhang ^a

a.
School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 210009, China
b.
College of Environment, Hohai University, Nanjing 210098, China
c.
State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China

bimingliu@tsinghua.edu.cn

Received Date: 5 January 2022
Revised Date: 7 April 2022
Accepted Date: 18 June 2022
Available Online: 22 June 2022

Figures(5)

Traditional treatment processes cannot completely remove phosphonates in circulating cooling water by one-step method. Herein, we designed peroxymonosulfate/UV irradiation/hydrated zirconium oxide (PMS/UV/HZO) coupling process to enhance the phosphonates removal. In particular, nitrilotris-methylenephosphonic acid (NTMP) removal efficiency by PMS/UV/HZO process was much higher than that of PMS/UV process, UV/HZO process and other processes in comparison experiments. Specifically, almost 97.2% NTMP in water was degraded, and the total phosphorous (TP) reduced from 9.3 mg/L to 0.26 mg/L at pH 7 within 180 min. TP removal efficiency still reached above 90% after 5 cycles adsorption-desorption of HZO. Moreover, Cl¯, NO₃¯ and SO₄²¯ ions all had negligible effect on NTMP removal. During the process, NTMP was first destroyed to form phosphates and other intermediates by the reactive oxygen species (ROS), then phosphates were in situ immobilized via HZO adsorption. Sulfate radical (SO₄^•−) has been confirmed to be the major ROS in the reaction system by quenching experiment and electron paramagnetic resonance (EPR) characterization. And the excellent selective adsorption capacity of HZO for phosphate produced was attributed to the strong inner-sphere coordination between H₂PO₄¯/HPO₄²¯ and Zr-OH on the surface of HZO. These results suggest that PMS/UV/HZO process is a promising technique for enhanced phosphonates decontamination.
- Phosphonates,
- Peroxymonosulfate,
- UV,
- ROS,
- Adsorption
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