Citation: Wen Li, Feng Wang, Yaocheng Shi, Lei Yu. Polyaniline-supported tungsten-catalyzed oxidative deoximation reaction with high catalyst turnover number[J]. Chinese Chemical Letters, ;2023, 34(1): 107505. doi: 10.1016/j.cclet.2022.05.019 shu

Polyaniline-supported tungsten-catalyzed oxidative deoximation reaction with high catalyst turnover number

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

ycshi@yzu.edu.cn

yulei@yzu.edu.cn

Received Date: 17 March 2022
Revised Date: 6 May 2022
Accepted Date: 10 May 2022
Available Online: 13 May 2022

Figures(1)

Polyaniline-supported tungsten (W@PANI) was easily prepared by immersing polyaniline (PANI) in the aqueous solution of Na₂WO₄. It was found to be an efficient catalyst for oxidative deoximation reaction, the very important transformation for pharmaceutical industry. Besides the green features, the method employed very few of catalytic tungsten (0.048 mol% vs. oxime substrates), resulting in the high turnover numbers (TONs) of the catalyst (ca. 10³ mol/mol) and the low metal residues in product (< 0.1 ppm). The reaction is applicable for a variety of substrates, including those containing heterocycles, which are key intermediates in medicine synthesis. It has also been successfully magnified to kilogram scale production to afford the desired carbonyl products smoothly.
- Deoximation,
- Carbonyl,
- Tungsten,
- Free radical reaction,
- Oxidation
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