Citation: Tianren Li, Yueyu Song, Jingjing Jiang, Mingyu Li, Yuhan Ma, Shuangshi Dong. NiCo₂O₄/BiOCl/Bi₂₄O₃₁Br₁₀ ternary Z-scheme heterojunction enhance peroxymonosulfate activation under visible light: Catalyst synthesis and reaction mechanism[J]. Chinese Chemical Letters, ;2023, 34(3): 107503. doi: 10.1016/j.cclet.2022.05.017 shu

NiCo₂O₄/BiOCl/Bi₂₄O₃₁Br₁₀ ternary Z-scheme heterojunction enhance peroxymonosulfate activation under visible light: Catalyst synthesis and reaction mechanism

Tianren Li ^{a, b, 1} ,
Yueyu Song ^{a, b, 1} ,
Jingjing Jiang ^{a, b} ,
Mingyu Li ^{a, b} ,
Yuhan Ma ^{a, b} ,
Shuangshi Dong ^{a, b, *,}

a.
Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130026, China
b.
Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130026, China

dongshuangshi@gmail.com

Received Date: 27 February 2022
Revised Date: 22 April 2022
Accepted Date: 10 May 2022
Available Online: 13 May 2022

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The Z-scheme heterostructure for photocatalyst can effectively prolong the lifetime of photogenerated carriers and retain a higher conduction/valence band position, promoting the synergistic coupling of photocatalysis and peroxymonosulfate (PMS) activation. In order to fully utilize the luminous energy and realize the efficient activation of PMS, this work achieved successful construction of NiCo₂O₄/BiOCl/Bi₂₄O₃₁Br₁₀ ternary Z-scheme heterojunction by simultaneously synthesizing BiOCl and NiCo₂O₄ with NiCl₂ and CoCl₂ as the precursors. The intercalated BiOCl could serve as a carrier migration ladder to further achieve the spatial separation of electron-hole pairs, so that the oxidation and reduction processes separately occurred in different regions. Compared with the reported catalysts, the as-prepared composites exhibited the enhanced removal efficiency for tetracycline hydrochloride (TCH) in the visible light/PMS system, with a degradation efficiency of 85.30% in 2 min, and possessed good stability. Z-scheme heterojunction was shown to be beneficial for maximizing the superiority of photo-assisted Fenton-like reaction system. The experimental and characterization results confirmed that both non-radicals (¹O₂) and radicals (SO₅^•− and SO₄^•−) were involved in the reaction process and the SO₅^•− generated by the oxidation of PMS played a crucial role in the TCH degradation. The possible reaction mechanism was finally proposed. This study provided new insight into the Z-scheme heterostructure to promote the photo-assisted Fenton-like reaction.
- Peroxymonosulfate activation,
- Photo-assisted Fenton-like reaction,
- Z-scheme heterojunction,
- Reaction mechanism,
- Reactive oxygen species
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NiCo2O4/BiOCl/Bi24O31Br10 ternary Z-scheme heterojunction enhance peroxymonosulfate activation under visible light: Catalyst synthesis and reaction mechanism

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通讯作者: 陈斌, bchen63@163.com

NiCo₂O₄/BiOCl/Bi₂₄O₃₁Br₁₀ ternary Z-scheme heterojunction enhance peroxymonosulfate activation under visible light: Catalyst synthesis and reaction mechanism