Citation: Yu Tan, Jinjun He, Bo Wang, Cheng Chao Li, Taihong Wang. Tuning the layer structure of molybdenum trioxide towards high-performance aqueous zinc-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(4): 107410. doi: 10.1016/j.cclet.2022.04.008 shu

Tuning the layer structure of molybdenum trioxide towards high-performance aqueous zinc-ion batteries

Yu Tan ^{a, e} ,
Jinjun He ^c ,
Bo Wang ^b ,
Cheng Chao Li ^{b, *,} ,
Taihong Wang ^{a, d, *,}

a.
College of Materials Science and Engineering, Hunan University, Changsha 410082, China
b.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
c.
School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
d.
Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen 518055, China
e.
College of Chemistry and Materials Science, Hunan Agriculture University, Changsha 410128, China

licc@gdut.edu.cn

wangth@sustech.edu.cn

Received Date: 7 March 2022
Revised Date: 28 March 2022
Accepted Date: 6 April 2022
Available Online: 11 April 2022

Figures(5)

Aqueous zinc-ion batteries (ZIBs) have attracted significant attentions because of low cost and high reliability. However, conventional ZIBs are severely limited by the development of high energy density cathode materials with reversible Zn²⁺ insertion/extraction. Herein, a conducting polymer intercalated MoO₃ (PMO) with extensively extended interlayer spacing is developed as a high-performance ZIBs cathode material. The interlayer spacing of PMO is prominently increased which results in an improved Zn²⁺ mobility during charge and discharge process. More significantly, the electrochemical results reveals that the intercalation of PANI facilitates the charge storage and reinforces the layered structure of MoO₃, leading to a high capacity and good cycling stability. DFT calculation further reveals the intercalation of PANI into MoO₃ significantly lower Zn²⁺ diffusion barrier. Benefit from these advantages, the ZIBs based on PMO electrode delivers a considerable capacity of 157 mAh/g at 0.5 A/g and ameliorative stability with 63.4% capacity retention after 1000 cycles.
- Molybdenum trioxide,
- Cathode,
- Zinc ion batteries,
- Polyaniline intercalation,
- Layered structure
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