Citation: Jianting Li, Jiaquan Li, Hongji Liu, Li Zhang, Yang Lu, Zhengzheng Zhou. Structural landscape investigations on bendable plastic crystals of isonicotinamide polymorphs[J]. Chinese Chemical Letters, ;2022, 33(8): 4069-4073. doi: 10.1016/j.cclet.2022.03.090 shu

Structural landscape investigations on bendable plastic crystals of isonicotinamide polymorphs

Jianting Li ^a ,
Jiaquan Li ^a ,
Hongji Liu ^a ,
Li Zhang ^{b, *,} ,
Yang Lu ^b ,
Zhengzheng Zhou ^{a, *,}

a.
NMPA Key Laboratory for Safety Evaluation of Cosmetics, Guangdong Provincial Key Laboratory of Tropical Disease Research, Department of Hygiene Inspection & Quarantine Science, School of Public Health, Southern Medical University, Guangzhou 510515, China
b.
Beijing City Key Laboratory of Polymorphic Drugs, Institute of Materia Medica, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100050, China

zhangl@imm.ac.cn

zhouzz418@smu.edu.cn

Received Date: 27 December 2021
Revised Date: 21 March 2022
Accepted Date: 21 March 2022
Available Online: 25 March 2022

Figures(5)

Three polymorphs (forms Ⅰ, Ⅱ and Ⅴ) of isonicotinamide (INA) were mechanically flexible and exhibited one-dimensional (1D) plasticity. Anisotropic intermolecular interactions contribute to the plasticity of single crystals: weak dispersive interactions between slip planes such as 1D columns in forms Ⅰ and Ⅱ or 2D layers in form Ⅴ were stabilized by strong hydrogen bonds, allowing the layer or column's surface to glide smoothly without hindrance. The disparity of intermolecular interactions on plastic properties of INA polymorphic crystals was confirmed by energy framework analysis, nanoindentation tests and micro-Raman spectroscopy. The crystal which exhibits plastic property provides a promising application in pharmaceuticals and material sciences.
- Isonicotinamide,
- Polymorph,
- Plasticity,
- Slip plane,
- Bending crystal
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