Citation: Shuang Zhao, Jinjin Yang, Yifeng Han, Meixia Wu, Man-Rong Li. Modulation of ionic arrangement in polar magnet by chemical pressure[J]. Chinese Chemical Letters, ;2023, 34(3): 107355. doi: 10.1016/j.cclet.2022.03.078 shu

Modulation of ionic arrangement in polar magnet by chemical pressure

Shuang Zhao ^a ,
Jinjin Yang ^a ,
Yifeng Han ^{a, *,} ,
Meixia Wu ^b ,
Man-Rong Li ^{a, *,}

a.
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-sen University, Guangzhou 510006, China
b.
Institute of Semiconductors, Guangdong Academy of Sciences, Guangzhou 510650, China

hanyf26@mail.sysu.edu.cn

limanrong@mail.sysu.edu.cn

Received Date: 23 February 2022
Revised Date: 13 March 2022
Accepted Date: 18 March 2022
Available Online: 21 March 2022

Figures(4)

The similarity of local structure-connection pattern and volumetrically compressive strain between host and guest phases can be used to stabilize heteroid metastable matter and tune the local structure and properties. Here a series of metastable ABO₃ (A = Mn; B = Mn_0.5Mo_0.5, Mn_1/3Ta_2/3, and Mn_0.5Ta_0.5) were trapped in LiTaO₃ to form solid-solutions, where the difference of solid solubility limit reveals the barrier of size effect on chemical pressure. All samples show antiferromagnetic characters, in which the (LiTaO₃)_1--[Mn(Mn_0.5Mo_0.5)O₃] series exhibit more complex magnetic and dielectric behaviors with the increasing of metastable guest phase, stemming from the complex interactive mechanism between Mn²⁺ and Mo⁶⁺. The cell parameter variation of (LiTaO₃)_1--[Mn(Mn_0.5Ta_0.5)O₃] shows a more regularly changing tendency, on account of the smallest size barrier. These findings show that chemical pressure can effectively stimulate the physical pressure to intercept and modulate a metastable phase at atomic-scale by compressibility effect between like structures at ambient pressure.
- Chemical pressure,
- Trapping metastable-phase,
- Cationic arrangement,
- Antiferromagnetism,
- Dielectricity
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