Citation: An-An Zhang, Rui Wang, Hai-Bo Huang, Tian-Fu Liu, Rong Cao. Post-modification of metal-organic framework for improved CO₂ photoreduction efficiency[J]. Chinese Chemical Letters, ;2023, 34(3): 107311. doi: 10.1016/j.cclet.2022.03.034 shu

Post-modification of metal-organic framework for improved CO₂ photoreduction efficiency

An-An Zhang ^{a, b, 1} ,
Rui Wang ^{a, b, 1} ,
Hai-Bo Huang ^b ,
Tian-Fu Liu ^{b, c} ,
Rong Cao ^{a, b, c, *,}

a.
Department of Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350002, China

rcao@fjirsm.ac.cn

Received Date: 5 January 2022
Revised Date: 30 January 2022
Accepted Date: 10 March 2022
Available Online: 13 March 2022

Figures(4)

Utilizing metal-organic frameworks (MOFs) to design photocatalysts for CO₂ reduction catalysts is an excellent idea but currently restricted by the relatively low activity. Enhancing CO₂ affinity and tuning the oxidation state of metal clusters in MOFs might be a solution to improve the catalytic performance. Herein, the Cl-bridge atoms in the metal clusters of a cobalt MOF were easily exchanged with OH⁻, which simultaneously oxidized a portion of Co(Ⅱ) to Co(Ⅲ) and resulted in a much enhanced photocatalytic activity for CO₂ reduction. In contrast, the original framework does not exhibit such superior activity. Comprehensive characterizations on their physicochemical properties revealed that the introduction of hydroxyl group not only greatly increases the CO₂ affinity but also alters the oxidation state of metal clusters, resulting in significantly improved photocatalytic activities for CO₂ reduction. This work provides important insight into the design of efficient photocatalysts.
- Metal-organic framework,
- Post-modification,
- Hydroxyl group,
- Ion exchange,
- CO₂ photoreduction
1. [1]
  R. Li, W. Zhang, K. Zhou, Adv. Mater. 30 (2018) 1705512. doi: 10.1002/adma.201705512
2. [2]
  A. Dhakshinamoorthy, A.M. Asiri, H. Garcia, Angew. Chem. Int. Ed. 55 (2016) 5414–5445. doi: 10.1002/anie.201505581
3. [3]
  Z.B. Fang, T.T. Liu, J. Liu, et al., J. Am. Chem. Soc. 142 (2020) 12515–12523. doi: 10.1021/jacs.0c05530
4. [4]
  H.Q. Xu, J. Hu, D. Wang, et al., J. Am. Chem. Soc. 137 (2015) 13440–13443. doi: 10.1021/jacs.5b08773
5. [5]
  S.C. Roy, O.K. Varghese, M. Paulose, C.A. Grimes, ACS Nano 4 (2010) 1259–1278. doi: 10.1021/nn9015423
6. [6]
  X. Chang, T. Wang, J. Gong, Energy Environ. Sci. 9 (2016) 2177–2196. doi: 10.1039/C6EE00383D
7. [7]
  Y. Lee, S. Kim, J.K. Kang, S.M. Cohen, Chem. Commun. 51 (2015) 5735–5738. doi: 10.1039/C5CC00686D
8. [8]
  H. Fei, M.D. Sampson, Y. Lee, C.P. Kubiak, S.M. Cohen, Inorg. Chem. 54 (2015) 6821–6828. doi: 10.1021/acs.inorgchem.5b00752
9. [9]
  K.G. Laurier, F. Vermoortele, R. Ameloot, et al., J. Am. Chem. Soc. 135 (2013) 14488–14491. doi: 10.1021/ja405086e
10. [10]
  B. An, Z. Li, Y. Song, et al., Nat. Catal. 2 (2019) 709–717. doi: 10.1038/s41929-019-0308-5
11. [11]
  D. Wang, R. Huang, W. Liu, D. Sun, Z. Li, ACS Catal. 4 (2014) 4254–4260. doi: 10.1021/cs501169t
12. [12]
  G. Huang, Y. Wang, T. Liu, Chin. Chem. Lett. 30 (2019) 2309–2312. doi: 10.1016/j.cclet.2019.04.030
13. [13]
  T. Li, B. -. T. Liu, Z. -. B. Fang, et al., J. Mater. Chem. A 9 (2021) 4687–4691. doi: 10.1039/D1TA00100K
14. [14]
  X.J. Hu, Z.X. Li, H. Xue, et al., CCS Chem. 2 (2020) 616–622. doi: 10.31635/ccschem.019.201900040
15. [15]
  A.A. Zhang, X. Cheng, X. He, et al., Research 2021 (2021) 9874273.
16. [16]
  L. Li, J.D. Yi, Z.B. Fang, et al., Chem. Mater. 31 (2019) 7584–7589. doi: 10.1021/acs.chemmater.9b02375
17. [17]
  B.T. Liu, X.H. Pan, D.Y. Nie, et al., Adv. Mater. 32 (2020) e2005912. doi: 10.1002/adma.202005912
18. [18]
  X.F. Lu, P.Q. Liao, J.W. Wang, et al., J. Am. Chem. Soc. 138 (2016) 8336–8339. doi: 10.1021/jacs.6b03125
19. [19]
  Z. Li, A.W. Peters, A.E. Platero-Prats, et al., J. Am. Chem. Soc. 139 (2017) 15251–15258. doi: 10.1021/jacs.7b09365
20. [20]
  J.Y. Liang, W.N. Lipscomb, J. Am. Chem. Soc. 108 (1986) 5051–5058. doi: 10.1021/ja00277a001
21. [21]
  C. Kormann, D.W. Bahnemann, M.R. Hoffmann, Environ. Sci. Technol. 22 (1988) 798–806. doi: 10.1021/es00172a009
22. [22]
  S. Merouani, O. Hamdaoui, F. Saoudi, M. Chiha, J. Hazard. Mater. 178 (2010) 1007–1014. doi: 10.1016/j.jhazmat.2010.02.039
23. [23]
  Y.X. Ye, C. Wen, J. Pan, et al., Appl. Catal. B 285 (2021) 119726. doi: 10.1016/j.apcatb.2020.119726
24. [24]
  Y. Xu, J. Mo, Q. Liu, X. Wang, S. Ding, Catal. Sci. Technol. 10 (2020) 2040–2046. doi: 10.1039/C9CY02202C
25. [25]
  G. Ye, P. Luo, Y. Zhao, et al., Chemosphere 253 (2020) 126767. doi: 10.1016/j.chemosphere.2020.126767
26. [26]
  Y.N. Gong, W. Zhong, Y. Li, et al., J. Am. Chem. Soc. 142 (2020) 16723–16731. doi: 10.1021/jacs.0c07206
27. [27]
  C.A. Kent, J.J. Concepcion, C.J. Dares, et al., J. Am. Chem. Soc. 135 (2013) 8432–8435. doi: 10.1021/ja400616a
28. [28]
  D. -. C. Liu, H.J. Wang, T. Ouyang, et al., ACS Appl. Energy Mater. 1 (2018) 2452–2459. doi: 10.1021/acsaem.8b00673
29. [29]
  S.L. Chan, T.L. Lam, C. Yang, S.C. Yan, N.M. Cheng, Chem. Commun. 51 (2015) 7799–7801. doi: 10.1039/C5CC00566C
30. [30]
  Y. Liu, W. Wang, J. Electrochem. Soc. 159 (2012) D375–D381. doi: 10.1149/2.094206jes
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Post-modification of metal-organic framework for improved CO2 photoreduction efficiency

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通讯作者: 陈斌, bchen63@163.com

Post-modification of metal-organic framework for improved CO₂ photoreduction efficiency