Citation: Qiu-Hui Zheng, Chuang Chen, Si-Min Cao, Meng-Ting Peng, Bao-Xia Dong, Yun-Lei Teng. Well-dispersed porous Fe–N–C catalyst towards the high-selective and high-efficiency conversion of CO₂ to CO[J]. Chinese Chemical Letters, ;2023, 34(1): 107273. doi: 10.1016/j.cclet.2022.02.078 shu

Well-dispersed porous Fe–N–C catalyst towards the high-selective and high-efficiency conversion of CO₂ to CO

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

bxdong@yzu.edu.cn

ylteng@yzu.edu.cn

Received Date: 29 December 2021
Revised Date: 25 January 2022
Accepted Date: 27 February 2022
Available Online: 3 March 2022

Figures(4)

In this study, through direct pyrolysis of a nitrogen-rich metal-organic framework of Fe-BTT at different temperatures and followed by acid treatment, we prepared a series of Fe–N–C_T (T = 800–1000 ℃) composite catalysts with uniform cubic morphology and homogeneously distributed active sites. Acid leaching leads to the removal of excess Fe NPs and the exposure of more pyridinic N and porphyrin-like Fe–N_x sites and creates a higher specific surface area. Structural and electrochemical performance test results showed that Fe–N–C₉₀₀ catalyst exhibited the highest selectivity for CO product at –1.2 V vs. Ag/AgCl, with 496 mV of overpotential and 86.8% of Faraday efficiency, as well as excellent long-term stability, due to the good inheritance from rich-N Fe–BTT precursor.
- Electrochemical CO₂ reduction,
- Fe–N–C,
- Metal-organic framework,
- High-temperature pyrolysis,
- Acid leaching
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沈阳化工大学材料科学与工程学院沈阳 110142

Well-dispersed porous Fe–N–C catalyst towards the high-selective and high-efficiency conversion of CO2 to CO

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通讯作者: 陈斌, bchen63@163.com

Well-dispersed porous Fe–N–C catalyst towards the high-selective and high-efficiency conversion of CO₂ to CO