Citation: Shurong Li, Zhenzhang Weng, Linpeng Jiang, Rongjia Wei, Haifeng Su, Lasheng Long, Lansun Zheng, Xiangjian Kong. A series of heterometallic 3d-4f polyoxometalates as single-molecule magnets[J]. Chinese Chemical Letters, ;2023, 34(3): 107251. doi: 10.1016/j.cclet.2022.02.056 shu

A series of heterometallic 3d-4f polyoxometalates as single-molecule magnets

a.
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
b.
College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, China

xjkong@xmu.edu.cn

Received Date: 26 January 2022
Revised Date: 16 February 2022
Accepted Date: 21 February 2022
Available Online: 24 February 2022

Figures(4)

Three sandwich-like [Ln₂Fe₂(B-α-FeW₉O₃₄)₂]¹⁰⁻ clusters (Ln₂Fe₄, Ln = Dy (1), Ho (2), and Y (3)) were obtained by reacting Na₉[B-α-SbW₉O₃₃], Ln₂O₃, FeCl₃·6H₂O and KH₂PO₄. The [B-α-FeW₉O₃₄]¹¹⁻ units were formed via the in situ conversion of lacunary polyoxometalates (POM) [B-α-SbW₉O₃₃]⁹⁻ and the Ln³⁺ ions were generated from the slow dissolution of Ln₂O₃, both of which play important roles in the synthesis of Ln₂Fe₄. Ln₂Fe₄ is the first 3d-4f cluster assembled from d-metal heteroatom-containing POM. The Dy₂Fe₄ cluster exhibits single-molecule magnet properties with an 80 K energy barrier in an optimal DC field. Cyclic voltammetry tests and controlled-potential coulometry experiments show that the polyoxometalate Fe heteroatom in clusters 1–3 is also electrochemically active.
- Polyoxometalates,
- 3d-4f,
- Cluster,
- Lanthanide,
- Single-molecule magnet
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