Citation: Kangting Zheng, Bingxue Niu, Cunmeng Lin, Yizhen Song, Pengtao Ma, Jingping Wang, Jingyang Niu. DL-Serine covalently modified multinuclear lanthanide-implanted arsenotungstates with fast photochromism[J]. Chinese Chemical Letters, ;2023, 34(2): 107238. doi: 10.1016/j.cclet.2022.02.043 shu

DL-Serine covalently modified multinuclear lanthanide-implanted arsenotungstates with fast photochromism

Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

mpt@henu.edu.cn

jyniu@henu.edu.cn

Received Date: 30 December 2021
Revised Date: 8 February 2022
Accepted Date: 17 February 2022
Available Online: 20 February 2022

Figures(4)

A series of DL-serine covalently modified multinuclear lanthanide implanted arsenotungstates K₂[{Ln(H₂O)₇}₂{As₄W₄₄O₁₃₇(OH)₁₈(H₂O)₂(DL-Ser)₂}{Ln₂(H₂O)₅(DL-Ser)}₂]·65H₂O (DL-Ser = DL-serine, Ln = La (1), Ce (2), Pr (3)) are obtained. Crystal structure analysis shows that these compounds are isomorphic and contain the basic [{As₄W₄₄O₁₃₇(OH)₁₈(H₂O)₂(DL-Ser)₂}{Ln₂(H₂O)₅(DL-Ser)}₂]^8– polyoxoanion constituted by two {As₂W₁₉O₅₉(OH)₈(H₂O)}^6‒ subunits, a [W₆O₂₃(OH)₂(DL-Ser)₂]^14‒ fragment, and two embedded [Ln₂(H₂O)₅(DL-Ser)]⁵⁺ groups, which further build into one dimensional linear chainlike structure via two peripheral Ln³⁺ ions. Most remarkably, these compounds exhibit rapid photochromic behaviors, which changed color quickly from white (1), yellow (2), green (3) to blue (1), brown (2) and glaucous (3) in ten minutes under UV irradiation, and that the colors gradually recovered in the dark for approximately 22 h.
- Polyoxometalate,
- Arsenotungstate,
- Carboxylate covalently modified,
- Lanthanide,
- Photochromism
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