Citation: Ya-Nan Yang, Lei Qiao, Zhong-Ming Sun. [Cd(Sn₉)₂]⁶⁻ and [Cd(Ni@Sn₉)₂]⁶⁻: Reactivity and coordination chemistry of empty and Ni-centered [Sn₉]⁴⁻ Zintl ions[J]. Chinese Chemical Letters, ;2023, 34(1): 107207. doi: 10.1016/j.cclet.2022.02.013 shu

[Cd(Sn₉)₂]⁶⁻ and [Cd(Ni@Sn₉)₂]⁶⁻: Reactivity and coordination chemistry of empty and Ni-centered [Sn₉]⁴⁻ Zintl ions

State Key Laboratory of Elemento-Organic Chemistry, Tianjin Key Lab of Rare Earth Materials and Applications, School of Material Science and Engineering, Nankai University, Tianjin 300350, China

1120180362@mail.nankai.edu.cn

sunlab@nankai.edu.cn

Received Date: 10 January 2022
Revised Date: 4 February 2022
Accepted Date: 8 February 2022
Available Online: 11 February 2022

Figures(3)

To investigate the reactivity of homoatomic clusters [E₉]⁴⁻ (E = Si-Pb) and intermetalloid clusters [M@E₉]⁻, the reactions of the Zintl anions [Sn₉]⁴⁻ and [Ni@Sn₉]⁴⁻ with the CdMes₂ (Mes = Mesitylene) in the presence of 2.2.2-crypt were carried out. Two new compounds [K(2.2.2-crypt)]₆[(Sn₉)Cd(Sn₉)]·en (1) and [K(2.2.2-crypt)]₆[(Ni@Sn₉)Cd(Ni@Sn₉)]·en (2) were afforded. Both 1 and 2 were characterized by single-crystal X-ray diffraction, energy dispersive X-ray (EDX), and electrospray ionization mass spectrometry (ESI-MS), and can be viewed as two [Sn₉]⁴⁻ or [Ni@Sn₉]⁴⁻ subunits bridged by Cd ion in an η³: η³ coordination mode. Quantum chemical calculations reveal the relationships between the geometries and electronic structures of clusters 2a, [Ni₃Ge₁₈]⁴⁻ and [Cu₄@Sn₁₈]⁴⁻. Further electron localization technique (AdNDP method) was performed to explain chemical bonding patterns of 1a.
- Heterometallic complexes,
- Sn cluster,
- Zintl anions,
- DFT calculation,
- Electronic structure
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[Cd(Sn9)2]6− and [Cd(Ni@Sn9)2]6−: Reactivity and coordination chemistry of empty and Ni-centered [Sn9]4− Zintl ions

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通讯作者: 陈斌, bchen63@163.com

[Cd(Sn₉)₂]⁶⁻ and [Cd(Ni@Sn₉)₂]⁶⁻: Reactivity and coordination chemistry of empty and Ni-centered [Sn₉]⁴⁻ Zintl ions