Citation: Siyi Xu, Yue Han, Cheng Zhou, Jianxi Li, Liguo Shen, Hongjun Lin. A biobased flame retardant towards improvement of flame retardancy and mechanical property of ethylene vinyl acetate[J]. Chinese Chemical Letters, ;2023, 34(1): 107202. doi: 10.1016/j.cclet.2022.02.008 shu

A biobased flame retardant towards improvement of flame retardancy and mechanical property of ethylene vinyl acetate

Siyi Xu ^{a, b, c} ,
Yue Han ^{a, b, c} ,
Cheng Zhou ^{b, c} ,
Jianxi Li ^{b, c} ,
Liguo Shen ^{a, *,} ,
Hongjun Lin ^{a, *,}

a.
College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004, China
b.
National Energy Life Evaluation and Management Technology Lab of Nuclear Power and Nonmetal Materials, Suzhou 215400, China
c.
CGN-DELTA (Taicang) Testing Technology Co., Ltd., Suzhou 215400, China

lgshen@zjnu.cn

hjlin@zjnu.cn

Received Date: 26 November 2021
Revised Date: 30 December 2021
Accepted Date: 3 February 2022
Available Online: 6 February 2022

Figures(4)

A new biobased flame retardant (MHPA) with remarkable compatibility was synthesized via a facile and low-cost neutralization reaction of magnesium hydroxide (MH) and phytic acid (PA). By blending the prepared MHPA into ethylene vinyl acetate (EVA), the fire retardancy, smoke suppression and mechanical properties of the composites were significantly improved. When 50 wt% of MH was added into EVA matrix, the value of limiting oxygen index (LOI) reached 26.1%. Whereas, when 10 wt% MH in the EVA composites (with initial 50 wt% MH) was replaced by MHPA, the resulted EVA composites had a LOI value of 30.8%, indicating high efficiency of addition of MHPA to improve flame retardancy. Moreover, the heat release rate (HRR) and total smoke production (TSP) of the EVA composites reduced by 54.4% and 27.6%, respectively, suggesting that incorporation of MHPA could effectively hinder rapid degradation of EVA composites during burning process. The fire-retardant mechanism may reside in that the MHPA combined with MH can present the excellent carbonization and expansion effects. This study illustrates that the biobased MHPA has a broad application prospect to develop flame-retardant EVA composites.
- Flame retardant,
- Smoke suppression,
- Mechanical properties,
- Magnesium hydroxide,
- Phytic acid
1. [1]
  H.H. Chu, W.H. Huang, K.S. Chuang, B.H. Shen, Int. J. Adhes. Adhes. 99 (2020) 102586 doi: 10.1016/j.ijadhadh.2020.102586
2. [2]
  M. Sabet, A. Hassan, C.T. Ratnam, Polym. Degrad. Stabil. 97 (2012) 1432–1437 doi: 10.1016/j.polymdegradstab.2012.05.010
3. [3]
  S. Ramarad, C.T. Ratnam, M. Khalid, A.L. Chuah, S. Hanson, Radiat. Phys. Chem. 130 (2017) 362–370 doi: 10.1016/j.radphyschem.2016.09.023
4. [4]
  S.P. Tambe, S.K. Singh, M. Patri, D. Kumar, Prog. Org. Coat. 62 (2008) 382–386 doi: 10.1016/j.porgcoat.2008.02.006
5. [5]
  M.C. Carvalho de Oliveira, A.S. Alves Cardoso Diniz, M.M. Viana, V. d. F. Cunha Lins, Renewable Sustainable Energy Rev. 81 (2018) 2299–2317 doi: 10.1016/j.rser.2017.06.039
6. [6]
  F.E. Ngohang, G. Fontaine, L. Gay, S. Bourbigot, Polym. Degrad. Stab. 115 (2015) 89–109 doi: 10.1016/j.polymdegradstab.2015.03.002
7. [7]
  L. Shen, C. Shao, R. Li, et al., Polym. Bull. 76 (2019) 2399–2410 doi: 10.1007/s00289-018-2500-1
8. [8]
  G. Yu, Y. Liu, J. Li, Polym. Adv. Technol. 29 (2018) 1804–1814 doi: 10.1002/pat.4287
9. [9]
  J.M. Allgood, T. Jimah, C.M. McClaskey, et al., Environ. Res. 153 (2017) 55–62 doi: 10.1016/j.envres.2016.11.010
10. [10]
  Y. Gao, J. Wu, Q. Wang, C.A. Wilkie, D. O'Hare, J. Mater. Chem. A 2 (2014) 10996–11016 doi: 10.1039/c4ta01030b
11. [11]
  F. Laoutid, L. Bonnaud, M. Alexandre, J.M. Lopez-Cuesta, P. Dubois, Mat. Sci. Eng. R: Rep. 63 (2009) 100–125 doi: 10.1016/j.mser.2008.09.002
12. [12]
  L. Ye, Q. Wu, B. Qu, Polym. Degrad. Stab. 94 (2009) 751–756 doi: 10.1016/j.polymdegradstab.2009.02.010
13. [13]
  F. Lou, K. Wu, Q. Wang, et al., Polymers-Basel 11 (2019) 125 doi: 10.3390/polym11010125
14. [14]
  Y. Liu, L. Shen, Z. Huang, et al., J. Membr. Sci. 641 (2022) 119925 doi: 10.1016/j.memsci.2021.119925
15. [15]
  X. Wu, L. Wang, C. Wu, G. Wang, P. Jiang, J. Appl. Polym. Sci. 126 (2012) 1917–1928 doi: 10.1002/app.36884
16. [16]
  T. Liu, F. Wang, G. Li, et al., J. Appl. Polym. Sci. 138 (2021) 49607 doi: 10.1002/app.49607
17. [17]
  L. Liu, M. Xu, Y. Hu, et al., J. Appl. Polym. Sci. 136 (2019) 47129 doi: 10.1002/app.47129
18. [18]
  X.W. Cheng, J.P. Guan, R.C. Tang, K.Q. Liu, J. Cleaner Prod. 124 (2016) 114–119 doi: 10.1016/j.jclepro.2016.02.113
19. [19]
  W. Zhu, S. Hao, M. Yang, B. Cheng, J. Zhang, Cellulose (2020) 1–12
20. [20]
  Z. Zheng, S. Liu, B. Wang, et al., Polym. Compos. 36 (2015) 1606–1619 doi: 10.1002/pc.23069
21. [21]
  Y.Y. Gao, C. Deng, Y.Y. Du, S.C. Huang, Y.Z. Wang, Polym. Degrad. Stab. 161 (2019) 298–308 doi: 10.1016/j.polymdegradstab.2019.02.005
22. [22]
  J. Zhang, Z. Li, L. Zhang, Y. Yang, D.Y. Wang, ACS Sustain. Chem. Eng. 8 (2020) 994–1003 doi: 10.1021/acssuschemeng.9b05658
23. [23]
  L. Wang, J. Zhan, L. Song, Y. Hu, R.K.K. Yuen, J. Appl. Polym. Sci. 131 (2014) 40112
24. [24]
  M. Wu, Y. Chen, H. Lin, et al., Water Res. 181 (2020) 115932 doi: 10.1016/j.watres.2020.115932
25. [25]
  S. Xu, J. Li, Q. Ye, L. Shen, H. Lin, J. Colloid Interface Sci. 589 (2021) 525–531 doi: 10.1016/j.jcis.2021.01.026
26. [26]
  K. Shang, W. Liao, Y.Z. Wang, Chin. Chem. Lett. 29 (2018) 433–436 doi: 10.1016/j.cclet.2017.08.017
27. [27]
  Y. Long, G. Yu, L. Dong, et al., Water Res. 189 (2020) 116665-116665
28. [28]
  T. Sun, Y. Liu, L. Shen, et al., J. Colloid Interface Sci. 570 (2020) 273–285 doi: 10.1016/j.jcis.2020.03.008
29. [29]
  Y. Xu, Y. Xiao, W. Zhang, et al., J. Membr. Sci. 618 (2021) 118726 doi: 10.1016/j.memsci.2020.118726
30. [30]
  Q. Zeng, Y. Liu, L. Shen, et al., J. Colloid Interface Sci. 582 (2021) 291–300 doi: 10.1016/j.jcis.2020.08.023
31. [31]
  Z. Huang, J. Liu, Y. Liu, et al., J. Membr. Sci. 623 (2021) 119080 doi: 10.1016/j.memsci.2021.119080
32. [32]
  D. Yao, G. Yin, Q. Bi, et al., Polymers-Basel 12 (2020) 2107 doi: 10.3390/polym12092107
33. [33]
  S. Xu, Q. Gao, C. Zhou, et al., Mater. Chem. Phys. 274 (2021) 125182 doi: 10.1016/j.matchemphys.2021.125182
34. [34]
  W.X. Li, H.J. Zhang, X.P. Hu, et al., J. Hazard. Mater. 398 (2020) 123001 doi: 10.1016/j.jhazmat.2020.123001
35. [35]
  B. Chen, H. Xie, L. Shen, et al., J. Membr. Sci. 640 (2021) 119820 doi: 10.1016/j.memsci.2021.119820
36. [36]
  W. Meng, W. Wu, W. Zhang, et al., Poly. Int. 68 (2019) 1759–1766 doi: 10.1002/pi.5885
37. [37]
  B. Wang, X. Qian, Y. Shi, et al., Compos. Part B: Eng. 69 (2015) 22–30 doi: 10.1016/j.compositesb.2014.09.015
38. [38]
  Y.Y. Yen, H.T. Wang, W.J. Guo, Polym. Degrad. Stab. 97 (2012) 863–869 doi: 10.1016/j.polymdegradstab.2012.03.043
39. [39]
  Z. Huang, Q. Zeng, Y. Liu, et al., J. Membr. Sci. 640 (2021) 119854 doi: 10.1016/j.memsci.2021.119854
40. [40]
  Y. Wang, X. Yang, H. Peng, et al., ACS Appl. Mater. Interfaces 8 (2016) 9925–9935 doi: 10.1021/acsami.6b00998
41. [41]
  L.F. Fang, B.K. Zhu, L.P. Zhu, H. Matsuyama, S. Zhao, J. Membr. Sci. 524 (2017) 235–244 doi: 10.1016/j.memsci.2016.11.026
42. [42]
  Y. Liu, Q. Yu, Z. Fang, Y. Zhang, Polym. Polym. Compos. 23 (2015) 345–350 doi: 10.1177/096739111502300507
43. [43]
  F. Zhang, W. Sun, Y. Wang, B. Liu, J. Appl. Polym. Sci. 132 (2015) 42148
44. [44]
  W. Guo, S. Nie, E.N. Kalali, et al., Compos. Part B: Eng. 176 (2019) 107261 doi: 10.1016/j.compositesb.2019.107261
45. [45]
  R. Chen, Z. Luo, X. Yu, et al., Carbohyd. Polym. 245 (2020) 116530 doi: 10.1016/j.carbpol.2020.116530
46. [46]
  N. Zhang, J. Zhang, H. Yan, et al., J. Hazard. Mater. 373 (2019) 856–865 doi: 10.1016/j.jhazmat.2019.04.016
47. [47]
  X. Hu, X. Zhu, Z. Sun, Constr. Build. Mater. 256 (2020) 119445 doi: 10.1016/j.conbuildmat.2020.119445
48. [48]
  D. Wang, Y. Wang, T. Li, et al., ACS Sustain. Chem. Eng. 8 (2020) 10265–10274 doi: 10.1021/acssuschemeng.0c03277
49. [49]
  Y. Pan, Z. Luo, B. Wang, J. Appl. Polym. Sci. 138 (2021) 49813 doi: 10.1002/app.49813
1. [1]
  Mengchen Liu , Yufei Zhang , Yi Xiao , Yang Wei , Meichen Bi , Huaide Jiang , Yan Yu , Shenghong Zhong . High stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensors. Chinese Journal of Structural Chemistry, 2025, 44(3): 100518-100518. doi: 10.1016/j.cjsc.2025.100518
2. [2]
  Chengyi Xiao , Xiaoli Sun , Chen Zhang , Weiwei Li . An In-Depth Analysis of the Scientific Connotations, Testing Methods, and Applications of Free Volume in Polymer Physics. University Chemistry, 2025, 40(4): 33-45. doi: 10.12461/PKU.DXHX202403069
3. [3]
  Dongmei Yao , Junsheng Zheng , Liming Jin , Xiaomin Meng , Zize Zhan , Runlin Fan , Cong Feng , Pingwen Ming . Effect of surface oxidation on the interfacial and mechanical properties in graphite/epoxy composites composite bipolar plates. Chinese Chemical Letters, 2024, 35(11): 109382-. doi: 10.1016/j.cclet.2023.109382
4. [4]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
5. [5]
  Wenhao Yan , Shuaiya Xue , Xuerui Zhao , Wei Zhang , Jian Li . Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy. Chinese Chemical Letters, 2024, 35(4): 109224-. doi: 10.1016/j.cclet.2023.109224
6. [6]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
7. [7]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
10. [10]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
11. [11]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
12. [12]
  Runjing Xu , Xin Gao , Ya Chen , Xiaodong Chen , Lifeng Cui . Research status and prospect of rechargeable magnesium ion batteries cathode materials. Chinese Chemical Letters, 2024, 35(11): 109852-. doi: 10.1016/j.cclet.2024.109852
13. [13]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
14. [14]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
15. [15]
  Yingfen Li , Zhiqi Wang , Yunhai Zhao , Dajun Luo , Xueliang Zhang , Jun Zhao , Zhenghua Su , Shuo Chen , Guangxing Liang . Potassium doping for grain boundary passivation and defect suppression enables highly-efficient kesterite solar cells. Chinese Chemical Letters, 2024, 35(11): 109468-. doi: 10.1016/j.cclet.2023.109468
16. [16]
  Shuai Li , Liuting Zhang , Fuying Wu , Yiqun Jiang , Xuebin Yu . Efficient catalysis of FeNiCu-based multi-site alloys on magnesium-hydride for solid-state hydrogen storage. Chinese Chemical Letters, 2025, 36(1): 109566-. doi: 10.1016/j.cclet.2024.109566
17. [17]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
18. [18]
  Yuchen Wang , Zhenhao Xu , Kai Yan . Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules. Chinese Journal of Structural Chemistry, 2025, 44(1): 100418-100418. doi: 10.1016/j.cjsc.2024.100418
19. [19]
  Lu Qi , Zhaoyang Chen , Xiaoyu Luan , Zhiqiang Zheng , Yurui Xue , Yuliang Li . Atomically dispersed Mn enhanced catalytic performance for overall water splitting on graphdiyne-coated copper hydroxide nanowire. Chinese Journal of Structural Chemistry, 2024, 43(1): 100197-100197. doi: 10.1016/j.cjsc.2023.100197
20. [20]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448

Get Citation

PDF

XML

Metrics

PDF Downloads(23)
Abstract views(739)
HTML views(116)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142