Citation: Bin Liu, Minxian Zhang, Jingling Yang, Mingshan Zhu. Efficient ozone decomposition over bifunctional Co₃Mn-layered double hydroxide with strong electronic interaction[J]. Chinese Chemical Letters, ;2022, 33(10): 4679-4682. doi: 10.1016/j.cclet.2022.01.025 shu

Efficient ozone decomposition over bifunctional Co₃Mn-layered double hydroxide with strong electronic interaction

Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou 511443, China

yangjl@jnu.edu.cn

Received Date: 6 September 2021
Revised Date: 8 November 2021
Accepted Date: 11 January 2022
Available Online: 16 January 2022

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Ground-level ozone is one of the primary pollutants detrimental to human health and ecosystems. Catalytic ozone decomposition still suffers from low efficiency and unsatisfactory stability. In this work, we report a manganese-based layered double hydroxide catalyst (Co₃Mn-LDH), which exhibited a superior ozone decomposition performance with the efficiency of 100% and stability over 7 h under a GHSV of 2,000,000 mL g^-1h^-1 and relative humidity of 15%. Even when the relative humidity increased to 50%, the ozone decomposition also reached 86%, which significantly exceeds as-synthesized MnO₂ and commercial MnO₂ in performance. The catalytic mechanism was studied by H₂-TPR, FT-IR and XPS. The excellent performance of Co₃Mn-LDH can be attributed to its abundant surface hydroxyl groups that ensured the preferentially surface enrichment of ozone, as well as the cyclic dynamic replenishment of electrons between multivalent Co²⁺/Co³⁺, Mn²⁺/Mn³⁺/Mn⁴⁺ and oxygen species that endowed the stable ozone decomposition. This work offers new insights into the design of efficient catalysts for ozone pollution control.
- Co₃Mn-layered double hydroxide,
- Ozone removal,
- Hydroxyl groups,
- Bifunctional catalysis,
- Heterogeneous catalysis
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Efficient ozone decomposition over bifunctional Co3Mn-layered double hydroxide with strong electronic interaction

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通讯作者: 陈斌, bchen63@163.com

Efficient ozone decomposition over bifunctional Co₃Mn-layered double hydroxide with strong electronic interaction