Citation: Jihong Zhang, Yuchen Wang, Hongjuan Wang, Dichang Zhong, Tongbu Lu. Enhancing photocatalytic performance of metal-organic frameworks for CO₂ reduction by a bimetallic strategy[J]. Chinese Chemical Letters, ;2022, 33(4): 2065-2068. doi: 10.1016/j.cclet.2021.09.035 shu

Enhancing photocatalytic performance of metal-organic frameworks for CO₂ reduction by a bimetallic strategy

MOE International Joint Laboratory of Materials Microstructure, Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

hongjuanwang@tjut.edu.cn

dczhong@email.tjut.edu.cn

Received Date: 10 July 2021
Revised Date: 19 August 2021
Accepted Date: 7 September 2021
Available Online: 13 September 2021

Figures(4)

Metal-organic frameworks (MOFs) as a type of crystalline heterogeneous catalysts have shown potential application in photocatalytic CO₂ reduction. However, MOF catalysts with high efficiency and selectivity are still in pursuit. Herein, by a bimetallic strategy, the catalytic performance of a Co-MOF for photocatalytic CO₂ reduction was enhanced. Specifically, the Co-MOF based on 4, 5-dicarboxylic acid (H₃IDC) and 4, 4ʹ-bipydine (4, 4ʹ-bpy) can catalyze CO₂ reduction to CO, with high efficiency but relatively low selectivity. After replacement of 2/3 Co(Ⅱ) with Ni(Ⅱ) within Co-MOF, the resulted isostructural Co₁Ni₂-MOF not only retains high efficiency for photocatalytic CO₂ reduction, but also shows enhanced CO selectivity. The CO evolution rate reaches 1160 µmol g⁻¹ h⁻¹ and the CO selectivity reaches as high as 94.6%. The enhanced photocatalytic CO₂ reduction performance is supported by theoretical calculation results. This case demonstrates that bimetallic strategy is an effective mean to optimize the catalytic performance of MOF catalysts for photochemical CO₂ reduction.
- Metal-organic framework,
- Photocatalytic CO₂ reduction,
- Bimetallic strategy,
- CO₂–to–CO conversion,
- Photocatalysis,
- Dinuclear metal synergistic catalysis
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Enhancing photocatalytic performance of metal-organic frameworks for CO2 reduction by a bimetallic strategy

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通讯作者: 陈斌, bchen63@163.com

Enhancing photocatalytic performance of metal-organic frameworks for CO₂ reduction by a bimetallic strategy