Citation: Hongyu Ma, Yong Liu, Rui Xiong, Jianhong Wei. Hetero-structured ZnIn₂S₄-NiO@MOF photo-catalysts for efficient hydrogen evolution[J]. Chinese Chemical Letters, ;2022, 33(2): 1042-1046. doi: 10.1016/j.cclet.2021.08.048 shu

Hetero-structured ZnIn₂S₄-NiO@MOF photo-catalysts for efficient hydrogen evolution

Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, and School of Physics and Technology, Wuhan University, Wuhan 430072, China

jhwei@whu.edu.cn

Received Date: 10 July 2021
Revised Date: 7 August 2021
Accepted Date: 11 August 2021
Available Online: 16 August 2021

Figures(4)

To obtain a high-performance heterogeneous photo-catalyst, herein, the hetero-structured ZnIn₂S₄-NiO@MOF (ZNM) nano-sheets are designed and prepared by partial pyrolysis of nickel-based MOFs (Ni-MOF) combined with the low-temperature solvo-thermal method. The results indicate that the NiO nanoparticles, produced by partial pyrolysis of the Ni-MOF, have a high density of the surface active sites with limited aggregation, which act as a co-catalyst to capture photo-induced charge carriers. In addition, the morphology and structure of Ni-MOF nano-sheets were preserved in ZNM, which is beneficial to the reduction of the conduction barrier for the photo generated electron-hole pairs. With the synergetic advantages of co-catalyst and unique two-dimensional hetero-structure, ZNM nano-sheets exhibited significantly improved activity for photo-catalytic hydrogen production.
- Metal-organic frameworks,
- ZnIn₂S₄-NiO@MOF,
- Hetero-structured,
- Photo-catalyst,
- Hydrogen production
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Hetero-structured ZnIn2S4-NiO@MOF photo-catalysts for efficient hydrogen evolution

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通讯作者: 陈斌, bchen63@163.com

Hetero-structured ZnIn₂S₄-NiO@MOF photo-catalysts for efficient hydrogen evolution