Citation: Zehui Xie, Yang Zhou, Canhui Ling, Xinlin Zhu, Zhao Fang, Xiaolong Fu, Wuwei Yan, Yong Yang. "Series and parallel" design of ether linkage and imidazolium cation synergistically regulated four-armed polymerized ionic liquid for all-solid-state polymer electrolyte[J]. Chinese Chemical Letters, ;2022, 33(3): 1407-1411. doi: 10.1016/j.cclet.2021.08.031 shu

"Series and parallel" design of ether linkage and imidazolium cation synergistically regulated four-armed polymerized ionic liquid for all-solid-state polymer electrolyte

Zehui Xie ^a ,
Yang Zhou ^{a, b} ,
Canhui Ling ^a ,
Xinlin Zhu ^a ,
Zhao Fang ^a ,
Xiaolong Fu ^c ,
Wuwei Yan ^d ,
Yong Yang ^{a, *,}

a.
Key Laboratory of Soft Chemistry and Functional Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
b.
The Green Aerotechnics Research Institute of Chongqing Jiaotong University, Chongqing 401120, China
c.
Xi'an Modern Chemistry Research Institute, Xi'an 710065, China
d.
Shenzhen BTR Nanotechnology Company, Ltd., Shenzhen 518106, China

yychem@njust.edu.cn

Received Date: 8 June 2021
Revised Date: 10 July 2021
Accepted Date: 7 August 2021
Available Online: 12 August 2021

Figures(4)

Developing all-solid-state polymer electrolytes (SPEs) with high electrochemical performances and stability is of great importance for exploiting of high energy density and safe batteries. Herein, ether linkage and imidazolium ionic liquid (ILs) are incorporated into the multi-armed polymer backbone though the series and parallel way. The parallel polymeric ionic liquid (P-P (PEGMA-IM)) maximizes the synergistic effect of ILs and ether linkage, which endowed the material with low crystallinity and high flame retardancy. The P-P (PEGMA-IM) based P-SPE presents a high ionic conductivity of 0.489 mS/cm at 60 ℃, an excellent lithium-ion transference number of 0.46 and a wide electrochemical window of 4.87 V. The assembled lithium metal battery using P-SPE can deliver a capacity of 151 mAh/g at 0.2 C, and the capacity retention ratio reaches 82% with a columbic efficiency beyond 99%. The overpotential of P-SPE based symmetric battery is 0.08 V, and there is no apparent magnifying even after 130 h cycling. This new design provides a new avenue for exploitation of advanced SPEs for the next-generation batteries.
- Series and parallel,
- Polymer electrolyte,
- All-solid-state,
- Lithium metal battery,
- Four-armed
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