Citation: Ruixue Mo, Dongqiang Han, Zeng Ren, Dazhuang Yang, Fei Wang, Caolong Li. Hollow Fe₂O₃/Co₃O₄ microcubes derived from metal-organic framework for enhanced sensing performance towards acetone[J]. Chinese Chemical Letters, ;2021, 32(11): 3619-3622. doi: 10.1016/j.cclet.2021.06.062 shu

Hollow Fe₂O₃/Co₃O₄ microcubes derived from metal-organic framework for enhanced sensing performance towards acetone

Ruixue Mo ^{a, 1} ,
Dongqiang Han ^{b, 1} ,
Zeng Ren ^c ,
Dazhuang Yang ^a ,
Fei Wang ^{a, *,} ,
Caolong Li ^{a, *,}

a.
Key Laboratory of Biomedical Functional Materials, College of Science, China Pharmaceutical University, Nanjing 211198, China
b.
Department of Physics, College of Science, China Pharmaceutical University, Nanjing 211198, China
c.
Institute of Tibetan Medicine, University of Tibetan Medicine, Lhasa 850000, China

feiwang@cpu.edu.cn

licl@cpu.edu.cn

Received Date: 30 April 2021
Revised Date: 5 June 2021
Accepted Date: 23 June 2021
Available Online: 11 July 2021

Figures(7)

In this work, hollow Fe₂O₃/Co₃O₄ microcubes have been successfully synthesized through a hydrothermal method followed by an annealing process using metal-organic framework of Prussian blue as a soft template. The morphologies, microstructures, surface area and element compositions have been carefully characterized by a series of techniques. Meanwhile, compared with that of pure Fe₂O₃ and Co₃O₄, the gas sensor based on the hollow microcubes exhibits enhanced sensing performances towards acetone, e.g., a higher response of 21.2 and a shorter response time of 5 s towards 20 ppm acetone at a relatively low working temperature of 200 ℃. Moreover, the hollow microcubes-based gas sensor still shows perfect long-term stability, excellent repeatability and the ability of sub-ppm level detection, which provides a possibility for its application in real life. The enhanced gas sensing performances can be attributed to the hollow structure with a high surface area and the formed p-n heterojunctions within the microcubes.
- Acetone,
- Fe₂O₃,
- Co₃O₄,
- Metal-organic frameworks,
- Heterojunctions,
- Gas sensor
1. [1]
  D. Zhang, Z. Yang, Z. Wu, G. Dong, Sens. Actuator. B283 (2019) 42-51 doi: 10.1016/j.snb.2018.11.133
2. [2]
  D. Han, M. Zhao, J. Alloys Compd. 815 (2020) 152406 doi: 10.1016/j.jallcom.2019.152406
3. [3]
  Y. Zhang, C. Jia, Q. Kong, et al., ACS Appl. Mater. Interfaces12 (2020) 26161-26169 doi: 10.1021/acsami.0c04580
4. [4]
  L. Deng, L. Bao, J. Xu, D. Wang, X. Wang, Chin. Chem. Lett. 31 (2020) 2041-2044 doi: 10.1016/j.cclet.2020.04.033
5. [5]
  S. Liang, J. Li, F. Wang, et al., Sens. Actuator. B238 (2017) 923-927 doi: 10.1016/j.snb.2016.06.144
6. [6]
  Q. Jia, H. Ji, Y. Zhang, et al., J. Hazard Mater. 276 (2014) 262-270 doi: 10.1016/j.jhazmat.2014.05.044
7. [7]
  X. Kou, N. Xie, F. Chen, et al., Sens. Actuator. B256 (2018) 861-869 doi: 10.1016/j.snb.2017.10.011
8. [8]
  F. Wang, H. Li, Z. Yuan, et al., RSC Adv. 6 (2016) 79343-79349 doi: 10.1039/C6RA13876D
9. [9]
  X.H. Jia, C.D. Cheng, S.P. Feng, et al., Appl. Surf. Sci. 481 (2019) 1001-1010 doi: 10.1016/j.apsusc.2019.03.198
10. [10]
  S. He, C. Yan, X.Z. Chen, et al., Appl. Catal. B276 (2020) 119138 doi: 10.1016/j.apcatb.2020.119138
11. [11]
  Z. Li, J.Y. Hu, Y.G. Xiao, et al., Anal. Chim. Acta1146 (2021) 174-183 doi: 10.1016/j.aca.2020.11.021
12. [12]
  Z.M. Xu, X.M. Deng, Y. Chen, et al., Sol. RRL5 (2021) 2000416 doi: 10.1002/solr.202000416
13. [13]
  H. Wang, X. Wang, R.M. Kong, L. Xia, F. Qu, Chin. Chem. Lett. 32 (2021) 198-202 doi: 10.1016/j.cclet.2020.10.017
14. [14]
  P.Y. Gao, R. Liu, H.H. Huang, X. Jia, H.B. Pan, RSC Adv. 6 (2016) 94699-94705 doi: 10.1039/C6RA21567J
15. [15]
  Y.Y. Yin, N. Zhang, J. Han, et al., Sens. Actuator. B297 (2019) 126738 doi: 10.1016/j.snb.2019.126738
16. [16]
  K. Tian, X.X. Wang, Z.Y. Yu, H.Y. Li, X. Guo, ACS Appl. Mater. Interfaces9 (2017) 29669-29676 doi: 10.1021/acsami.7b07069
17. [17]
  W.Y. Li, L.N. Xu, J. Chen, Adv. Funct. Mater. 15 (2005) 851-857 doi: 10.1002/adfm.200400429
18. [18]
  T.T. Zhou, T. Zhang, J.A. Deng, et al., Sens. Actuator. B242 (2017) 369-377 doi: 10.1016/j.snb.2016.11.067
19. [19]
  J. Cao, N. Zhang, S. Wang, H. Zhang, J. Colloid Interface Sci. 577 (2020) 19-28 doi: 10.1016/j.jcis.2020.05.028
20. [20]
  F. Yang, K.B. Xu, J.Q. Hu, J. Alloys Compd. 729 (2017) 1172-1176 doi: 10.1016/j.jallcom.2017.09.259
21. [21]
  X.J. Wei, Y.H. Li, H.R. Peng, et al., Chem. Eng. J. 355 (2019) 336-340 doi: 10.1016/j.cej.2018.08.009
22. [22]
  X.R. Qiao, C. Ma, X. Chang, et al., Sens. Actuator. B327 (2021) 128926 doi: 10.1016/j.snb.2020.128926
23. [23]
  M.M. Alam, H.B. Balkhoyor, A.M. Asiri, et al., Surf. Interfaces20 (2020) 100607 doi: 10.1016/j.surfin.2020.100607
24. [24]
  Y. Xiang, Y. Zhu, J. Lu, et al., Solid State Sci. 93 (2019) 79-86 doi: 10.1016/j.solidstatesciences.2019.05.008
25. [25]
  F.H. Zhang, H.Q. Yang, X.L. Xie, et al., Sens. Actuator. B141 (2009) 381-389 doi: 10.1016/j.snb.2009.06.049
26. [26]
  Y.J. Kwon, H.G. Na, S.Y. Kang, et al., Sens. Actuator. B239 (2017) 180-192 doi: 10.1016/j.snb.2016.07.177
27. [27]
  F. Qu, J. Liu, Y. Wang, et al., Sens. Actuator. B199 (2014) 346-353 doi: 10.1016/j.snb.2014.04.003
28. [28]
  C. Li, Z. Chen, W. Yuan, Q.H. Xu, C.M. Li, Nanoscale11 (2019) 1111-1122 doi: 10.1039/c8nr07041e
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
3. [3]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
4. [4]
  Fahui Xiang , Lu Li , Zhen Yuan , Wuji Wei , Xiaoqing Zheng , Shimin Chen , Yisi Yang , Liangji Chen , Zizhu Yao , Jianwei Fu , Zhangjing Zhang , Shengchang Xiang . Enhanced C₂H₂/CO₂ separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition. Chinese Chemical Letters, 2025, 36(3): 109672-. doi: 10.1016/j.cclet.2024.109672
5. [5]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
6. [6]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
7. [7]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
8. [8]
  Xi Feng , Ding-Yi Hu , Zi-Jun Liang , Mu-Yang Zhou , Zhi-Shuo Wang , Wen-Yu Su , Rui-Biao Lin , Dong-Dong Zhou , Jie-Peng Zhang . A metal azolate framework with small aperture for highly efficient ternary benzene/cyclohexene/cyclohexane separation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100540-100540. doi: 10.1016/j.cjsc.2025.100540
9. [9]
  Yu Deng , Yan Liu , Yonghui Deng , Jinsheng Cheng , Yidong Zou , Wei Luo . In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series. Chinese Chemical Letters, 2024, 35(7): 108898-. doi: 10.1016/j.cclet.2023.108898
10. [10]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
11. [11]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
12. [12]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
13. [13]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
14. [14]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
15. [15]
  Wenbiao Zhang , Bolong Yang , Zhonghua Xiang . Atomically dispersed Cu-based metal-organic framework directly for alkaline polymer electrolyte fuel cells. Chinese Chemical Letters, 2025, 36(2): 109630-. doi: 10.1016/j.cclet.2024.109630
16. [16]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
17. [17]
  Sixiao Liu , Tianyi Wang , Lei Zhang , Chengyin Wang , Huan Pang . Cerium-based metal-organic framework-modified natural mineral vermiculite for photocatalytic nitrogen fixation under visible-light irradiation. Chinese Chemical Letters, 2025, 36(3): 110058-. doi: 10.1016/j.cclet.2024.110058
18. [18]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
19. [19]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
20. [20]
  Zhi Wang , Lingpeng Yan , Yelin Hao , Jingxia Zheng , Yongzhen Yang , Xuguang Liu . Highly efficient and photothermally stable CDs@ZIF-8 for laser illumination. Chinese Chemical Letters, 2024, 35(10): 109430-. doi: 10.1016/j.cclet.2023.109430

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(834)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hollow Fe2O3/Co3O4 microcubes derived from metal-organic framework for enhanced sensing performance towards acetone

Metrics

通讯作者: 陈斌, bchen63@163.com

Hollow Fe₂O₃/Co₃O₄ microcubes derived from metal-organic framework for enhanced sensing performance towards acetone