Citation: Yunpeng Wu, Deyang Yu, Yi Feng, Leiyun Han, Xilong Liu, Xudong Zhao, Xiaoyang Liu. Facilely synthesized N-doped graphene sheets and its ferromagnetic origin[J]. Chinese Chemical Letters, ;2021, 32(12): 3841-3846. doi: 10.1016/j.cclet.2021.04.054 shu

Facilely synthesized N-doped graphene sheets and its ferromagnetic origin

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

xdzhao@jlu.edu.cn

liuxy@jlu.edu.cn

Received Date: 11 April 2021
Revised Date: 28 April 2021
Accepted Date: 29 April 2021
Available Online: 8 May 2021

Figures(4)

Inducing ferromagnetism into graphene is vital today because it has a wide range of applications such as spintronics devices and magnetic memory devices. In this paper, we will report a new method to synthesize ferromagnetic graphene by nitrogen doping. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy were utilized to testify the N-doped material and further discuss the N-doped process. The superconducting quantum interference device (SQUID) was put in and used to analyze the magnetic properties of the N-doped graphene sheets. It shows that the material exhibits ferromagnetism at both 3 K and 300 K and the ferromagnetic saturation moment is 0.412 emu/g and 0.051 emu/g, respectively. The mechanism of the origin of the ferromagnetism in N-doped graphene sheets will also be discussed in this paper. It shows that, when the amount graphitic N reached the threshold, the origin of the ferromagnetism will change from defects induced by nitrogen atoms to the transition in energy band caused by graphitic N.
- Graphene,
- Nitrogen doping,
- Ferromagnetism,
- Magnetic coupling interaction,
- Defect
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