Citation: Qingxin Zhang, Yabo Wang, Yanzhi Wang, Shujiao Yang, Xuan Wu, Bin Lv, Ni Wang, Yimei Gao, Xiaoran Xu, Haitao Lei, Rui Cao. Electropolymerization of cobalt porphyrins and corroles for the oxygen evolution reaction[J]. Chinese Chemical Letters, ;2021, 32(12): 3807-3810. doi: 10.1016/j.cclet.2021.04.048 shu

Electropolymerization of cobalt porphyrins and corroles for the oxygen evolution reaction

Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

leiht2017@snnu.edu.cn

ruicao@snnu.edu.cn

Received Date: 16 March 2021
Revised Date: 22 April 2021
Accepted Date: 25 April 2021
Available Online: 1 May 2021

Figures(4)

Developing large-scale electrocatalysts using molecular complexes for the oxygen evolution reaction (OER) is of great importance. Herein, four cobalt porphyrins and corroles are deposited on electrode substrates using a simple and fast electropolymerization method. Our results showed that Co-1-P@CC, formed by electropolymerizing Co tetrakis(p-N-pyrrolylphenyl)porphyrin (Co-1-P) on carbon cloth (CC), is the most active OER catalyst in the examined Co porphyrins and corroles in alkaline aqueous solutions by displaying an onset overpotential of 380 mV. Long-term electrolysis tests confirmed the stability of these electropolymerized films by functioning as OER electrocatalysts.
- Cobalt corroles,
- Cobalt porphyrins,
- Electropolymerization,
- Molecular electrocatalysis,
- Oxygen evolution
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