Citation: Pengyuan Qiu, Jianwei Wang, Zhangqian Liang, Yanjun Xue, Yanli Zhou, Xiaoli Zhang, Hongzhi Cui, Guiqing Cheng, Jian Tian. The metallic 1T-WS₂ as cocatalysts for promoting photocatalytic N₂ fixation performance of Bi₅O₇Br nanosheets[J]. Chinese Chemical Letters, ;2021, 32(11): 3501-3504. doi: 10.1016/j.cclet.2021.03.077 shu

The metallic 1T-WS₂ as cocatalysts for promoting photocatalytic N₂ fixation performance of Bi₅O₇Br nanosheets

Pengyuan Qiu ^a ,
Jianwei Wang ^a ,
Zhangqian Liang ^a ,
Yanjun Xue ^a ,
Yanli Zhou ^b ,
Xiaoli Zhang ^c ,
Hongzhi Cui ^{a, *,} ,
Guiqing Cheng ^{a, *,} ,
Jian Tian ^{a, *,}

a.
School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China
b.
School of Environmental and Material Engineering, Yantai University, Yantai 264005, China
c.
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

cuihongzhi1965@163.com

chengguiqing@sdust.edu.cn

jiantian@sdust.edu.cn

Received Date: 23 February 2021
Revised Date: 26 March 2021
Accepted Date: 29 March 2021
Available Online: 31 March 2021

Figures(4)

Recently, widespread attention has been devoted to the typical layered BiOCl or BiOBr because of the suitable nanostructure and band structure. However, owing to the fast carrier recombination, the photocatalytic performance of BiOX materials is not so satisfactory. Loading 1T phase WS₂ nanosheets (NSs) onto Bi₅O₇Br NSs can improve the photocatalytic N₂ fixation activity. Among these, the obtained 1T-WS₂@Bi₅O₇Br composites with optimum 5% 1T-WS₂ NSs display a significantly improved photocatalytic N₂ fixation rate (8.43 mmol L^-1h^-1g^-1), 2.51 times higher than pure Bi₅O₇Br (3.36 mmol L^-1h^-1g^-1). And the outstanding stability of 1T-WS₂@Bi₅O₇Br-5 composites is also achieved. Exactly, the photoexcited electrons from Bi₅O₇Br NSs are quickly transferred to conductive 1T phase WS₂ as electron acceptors, which can promote the separation of carriers. In addition, 1T-WS₂ NSs can provide abundant active sites on the basal and edge planes, which can promote the efficiency of photocatalytic N₂ fixation. This work offers a novel solution to improve the photocatalytic performance of Bi₅O₇Br NSs.
- Photocatalytic N₂ fixation,
- Bi₅O₇Br,
- 1T phase WS₂,
- Electron-hole pairs,
- Photocatalytic performance
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The metallic 1T-WS2 as cocatalysts for promoting photocatalytic N2 fixation performance of Bi5O7Br nanosheets

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The metallic 1T-WS₂ as cocatalysts for promoting photocatalytic N₂ fixation performance of Bi₅O₇Br nanosheets