Citation: Xu Yu, Zhixin Zhao, Chengang Pei. Surface oxidized iron-nickel nanorods anchoring on graphene architectures for oxygen evolution reaction[J]. Chinese Chemical Letters, ;2021, 32(11): 3579-3583. doi: 10.1016/j.cclet.2021.03.040 shu

Surface oxidized iron-nickel nanorods anchoring on graphene architectures for oxygen evolution reaction

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225000, China

yxypz15@yzu.edu.cn

Received Date: 17 February 2021
Revised Date: 9 March 2021
Accepted Date: 15 March 2021
Available Online: 17 March 2021

Figures(4)

Surface oxidized iron-nickel nanorods coupling with reduced graphene architectures (FeNi-O-rGA) are successfully constructed via hydrothermal, freeze-drying, and thermal activation approaches. The hierarchical structure can provide lots of pathways for fast ion diffusion and charge transfer, and expose abundant catalytic sites. Meanwhile, the activity of FeNi-O-rGA is boosted by the optimized metal-oxygen bond strength in FeNi₃ alloys. Partial oxidized FeNi nanorods are strongly coupled with rGA by the formation of metal-O-C bonds, which can impede the aggregation of FeNi₃ alloys and increase the utilization of active sites. The special structure and partially oxidized FeNi nanorods for FeNi-O-rGA can result in excellent OER activity and catalytic stability. Only 215 mV of overpotential is required to drive the current density of 10 mA/cm² as well as the Tafel slope of 50.9 mV/dec in 1 mol/L KOH. The change of surface chemistry of FeNi-O-rGA is confirmed by XPS after the OER test, which indicates the highly catalytic stability of FeNi-O-rGA due to the formation of intermediate metal oxyhydroxide.
- Architectures,
- Graphene oxides,
- FeNi nanorods,
- Metallic oxide,
- Oxygen evolution reaction
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