Citation: Wei Xiao, Jie Wu. Narasaka reaction: Desilylative acylation of 1-alkenylsilanes with acid anhydrides[J]. Chinese Chemical Letters, ;2021, 32(9): 2751-2755. doi: 10.1016/j.cclet.2021.03.033 shu

Narasaka reaction: Desilylative acylation of 1-alkenylsilanes with acid anhydrides

Wei Xiao ^a ,
Jie Wu ^{a, b, c, *,}

a.
School of Pharmaceutical and Materials Engineering & Institute for Advanced Studies, Taizhou University, Taizhou 318000, China
b.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
c.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China

jie_wu@fudan.edu.cn

Received Date: 1 February 2021
Revised Date: 11 March 2021
Accepted Date: 12 March 2021
Available Online: 15 March 2021

Figures(11)

Recent advances in the desilylative acylation of 1-alkenylsilanes with acid anhydrides under transition metal catalysis are summarized. This catalytic desilylative acylation of 1-alkenylsilanes provides an efficient route to α, β-unsaturated ketones by using rhodium or iridium as the catalyst. Moreover, various one pot sequence reactions have been developed, which can synthesize α, β-unsaturated ketones from simple starting materials in an economic way. Additionally, this approach is applied to the asymmetric synthesis of atropisomers possessing silanol groups with excellent enantioselectivity.
- Acid anhydride,
- 1-Alkenylsilane,
- Desilylative acylation,
- Transition metal catalysis,
- α, β-Unsaturated ketone
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