Citation: Shan-Shan Jia, Wen-Shi Xu, Yong Chen, Yu Liu. Pyrrole/macrocycle/MOF supramolecular co-assembly for flexible solid state supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(9): 2773-2776. doi: 10.1016/j.cclet.2021.03.002 shu

Pyrrole/macrocycle/MOF supramolecular co-assembly for flexible solid state supercapacitors

College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

chenyong@nankai.edu.cn

yuliu@nankai.edu.cn

Received Date: 6 January 2021
Revised Date: 24 February 2021
Accepted Date: 1 March 2021
Available Online: 3 March 2021

Figures(7)

Supramolecular assemblies constructed through the encapsulation of conductive polymers (CPs) by macrocyclic molecules have attracted increasing interest in the fields of supramolecular chemistry and electrochemistry. In this work, an effective strategy was reported to improve the stability and conductivity of CPs by electrochemically constructing different supramolecular assemblies composed of macrocycles and CPs. Typically, we uploaded zinc-based MOF (ZIF-8) onto carbon nanotube film (CNTF) and further electrically deposited macrocycles and CPs to gain the flexible conductive electrodes. Herein, five different supramolecular macrocycles, including α-cyclodextrin (α-CD), sulfato-β-cyclodextrin (SCD), sulfonatocalix[4]arene (SC[4]), cucurbit[6]uril (CB[6]) and cucurbit[7]uril (CB[7]) were utilized and the electrochemical performances of the assembly electrodes increased in an order of α-CD < SCD < SC[4] < CB[6] < CB[7], significantly improving the areal capacitance up to 1533 mF/cm². This strategy may provide a new way for the application of macrocyclic supramolecules in electrochemical systems.
- Supramolecular assemblies,
- Macrocycle,
- Conductive polymers,
- Electrochemical performance,
- Cationic radical
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沈阳化工大学材料科学与工程学院沈阳 110142