Citation: Haoyuan Lv, Hongbo Guo, Kai Guo, Haitao Lei, Wei Zhang, Haoquan Zheng, Zuozhong Liang, Rui Cao. Substituent position effect of Co porphyrin on oxygen electrocatalysis[J]. Chinese Chemical Letters, ;2021, 32(9): 2841-2845. doi: 10.1016/j.cclet.2021.02.032 shu

Substituent position effect of Co porphyrin on oxygen electrocatalysis

Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

liangzuozhong@snnu.edu.cn

ruicao@snnu.edu.cn

Received Date: 29 December 2020
Revised Date: 7 February 2021
Accepted Date: 17 February 2021
Available Online: 19 February 2021

Figures(4)

Substituent effect of metal porphyrin molecular catalysts plays a crucial role in determining the catalytic activity of oxygen electrocatalysis. Herein, substituent position effect of Co porphyrins on oxygen electrocatalysis, including the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER), was investigated. Two Co porphyrins, namely 2, 4, 6-OMe-CoP and 3, 4, 5-OMe-CoP, were selected as the research objects. The ORR and OER performance was evaluated by drop-coating molecular catalysts on carbon nanotubes (CNTs). The resulted 3, 4, 5-OMe-CoP/CNT exhibited high bifunctional electrocatalytic activities and better long-term stability for both ORR and OER than 2, 4, 6-OMe-CoP/CNT. Furthermore, when applied in the Zn-air battery, 3, 4, 5-OMe-CoP/CNT exhibited comparable performance to that with precious metal-based materials. The enhanced catalytic activity may be attributed to the improved charge transfer rate, mass transfer and hydrophilicity. This work provides an effective strategy to further enhance catalytic activity by introducing substituent position effect, which is of great importance for developing more efficient energy-related electrocatalysts.
- Oxygen electrocatalysis,
- Oxygen reduction reaction,
- Oxygen evolution reaction,
- Co porphyrin,
- Substituent effect
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